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Mechanisms responsible for enhanced charge reactivity with intake added ozone (O3) were explored in a single-cylinder, optically accessible, research engine configured for low-load advanced compression ignition (ACI) experiments. The influence of O3 concentration (0-40 ppm) on engine performance metrics was evaluated as a function of intake temperature and start of injection for the engine fueled by iso-octane, 1-hexene, or a 5-component gasoline surrogate. For the engine fueled by either the gasoline surrogate or 1-hexene, 25 ppm of added O3 reduced the intake temperature required for stable combustion by 65 and 80°C, respectively. An ultraviolet (UV) light absorption diagnostic was also used to measure crank angle (CA) resolved in-cylinder O3 concentrations for select motored and fired operating conditions. The O3 measurements were compared to results from complementary 0D chemical kinetic simulations that utilized detailed chemistry mechanisms augmented with O3 oxidation chemistry.

Fuel reforming during a Negative Valve Overlap (NVO) period is an effective approach to control Low Temperature Gasoline Combustion (LTGC) ignition. Previous work has shown through experiments that primary reference fuels reform easily and produce several species that drastically affect ignition characteristics. However, our previous research has been unable to accurately predict measured reformate composition at the end of the NVO period using simple single-zone models. In this work, we use a stochastic reactor model (SRM) closed cycle engine simulation to predict reformate composition accounting for in-cylinder temperature and mixture stratification. The SRM model is less computationally intensive than CFD simulations while still allowing the use of large chemical mechanisms to predict intermediate species formation rates.

Negative Valve Overlap (NVO) is a potential control strategy for enabling Low-Temperature Gasoline Combustion (LTGC) at low loads. While the thermal effects of NVO fueling on main combustion are well-understood, the chemical effects of NVO in-cylinder fuel reforming have not been extensively studied. The objective of this work is to examine the effects of fuel molecular structure on NVO fuel reforming using gas sampling and detailed speciation by gas chromatography. Engine gas samples were collected from a single-cylinder research engine at the end of the NVO period using a custom dump-valve apparatus. Six fuel components were studied at two injection timings: (1) iso-octane, (2) n-heptane, (3) ethanol, (4) 1-hexene, (5) cyclohexane, and (6) toluene. All fuel components were studied neat except for toluene - toluene was blended with 18.9% nheptane by liquid volume to increase the fuel reactivity.

In-cylinder reforming of injected fuel during an auxiliary negative valve overlap (NVO) period can be used to optimize main-cycle auto-ignition phasing for low-load Low-Temperature Gasoline Combustion (LTGC), where highly dilute mixtures can lead to poor combustion stability. When mixed with fresh intake charge and fuel, these reformate streams can alter overall charge reactivity characteristics. The central issue remains large parasitic heat losses from the retention and compression of hot exhaust gases along with modest pumping losses that result from mixing hot NVO-period gases with the cooler intake charge. Accurate determination of total cycle energy utilization is complicated by the fact that NVO-period retained fuel energy is consumed during the subsequent main combustion period. For the present study, a full-cycle energy analysis was performed for a single-cylinder research engine undergoing LTGC with varying NVO auxiliary fueling rates and injection timing.

The objective of this research is a detailed investigation of unburned hydrocarbon (UHC) in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the mechanisms that control the formation of UHC via experiments and simulations in a 0.48L signal-cylinder light duty engine operating at 2000 r/min and 5.5 bar IMEP with multiple injections. A multi-gas FTIR along with other gas and smoke emissions instruments are used to measure exhaust UHC species and other emissions. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, analysis of spray trajectory with a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2].

For next-generation engines that operate using low-temperature gasoline combustion (LTGC) modes, a major issue remains poor combustion stability at low-loads. Negative valve overlap (NVO) enables enhanced main combustion control through modified valve timings to retain combustion residuals along with a small fuel injection that partially reacts during the recompression. While the thermal effects of NVO fueling on main combustion are well understood, the chemical effects of NVO reactions are less certain, especially oxygen-deficient reactions where fuel pyrolysis dominates. To better understand NVO period chemistry details, comprehensive speciation of engine samples collected at the end of the NVO cycle was performed by photoionization mass spectroscopy (PIMS) using synchrotron generated vacuum-ultraviolet light.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.