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Demand for transport energy is growing but this growth is skewed heavily toward commercial transport, such as, heavy road, aviation, marine and rail which uses heavier fuels like diesel and kerosene. This is likely to lead to an abundance and easy availability of lighter fractions like naphtha, which is the product of the initial distillation of crude oil. Naphtha will also require lower energy to produce and hence will have a lower CO₂ impact compared to diesel or gasoline. It would be desirable to develop engine combustion systems that could run on naphtha. Many recent studies have shown that running compression ignition engines on very low Cetane fuels, which are very similar to naphtha in their auto-ignition behavior, offers the prospect of developing very efficient, clean, simple and cheap engine combustion systems. Significant development work would be required before such systems could power practical vehicles.

If fuels that are more resistant to auto-ignition are injected near TDC in compression ignition engines, they ignite much later than diesel fuel and combustion occurs when the fuel and air have had more chance to mix. This helps to reduce NOX and smoke emissions at much lower injection pressures compared to a diesel fuel. However, PPCI (Partially Premixed Compression Ignition) operation also leads to higher CO and HC at low loads and higher heat release rates at high loads. These problems can be significantly alleviated by managing the mixing through injector design (e.g. nozzle size and centreline spray angle) and changing CR (Compression Ratio). This work describes results of running a single-cylinder diesel engine on fuel blends by using three different nozzle design (nozzle size: 0.13 mm and 0.17 mm, centreline spray angle: 153° and 120°) and two different CRs (15.9:1 and 18:1).

Conventional fossil fuels will constitute the majority of automotive fuels for the foreseeable future but will have to adapt to changes in engine technology. Unconventional transport fuels such as biofuels, gas-to-liquid fuels, compressed natural gas, and liquid petroleum gas will also play a role. Hydrogen might be a viable transport fuel if it overcomes barriers in production, transport, storage, and safety and/or if fuel cells become viable. This book opens by considering these issues and then introduces practical transport fuels. A chapter on engine deposits follows, which is an important practical topic about how fuels affect engines that is not usually considered in other books. The next three chapters discuss auto-ignition phenomena in engines. The auto-ignition resistance of fuels is the most important fuel property since it limits the efficiency of spark ignition engines and determines the performance of compression ignition engines.

Extensive tests have been carried out in a single-cylinder Direct Injection Spark Ignition (DISI) engine using up to fifteen different fuels at inlet pressure of up to 3.4 bar abs. to study fuel effects as well as inlet pressure effects on knock. In addition fuel effects on particulate emissions at part-throttle were measured. Fuel anti-knock quality does not correlate with MON and is best described by the Octane Index, OI = RON-KS where S = RON -MON is the sensitivity of the fuel and K is a constant depending on the engine pressure/temperature regime. The RON of the fuels considered was in the range between 95 and 105 and the sensitivity between 8 and 13. K is negative at all the conditions tested, i.e., for a given RON, a higher sensitivity fuel has better anti-knock quality. K decreases with increasing intake pressure and more generally, decreases as Tcomp₁₅, the temperature of the unburned gas at a pressure of 15 bar decreases.

In the context of stringent future emission standards as well as the need to reduce emissions of CO2 on a global scale, the cost of manufacturing engines is increasing. Naphtha has been shown to have beneficial properties for its use as a fuel in the transportation sector. Well to tank CO2 emissions from the production of Naphtha are lower than any other fuel produced in the refinery due to its lower processing requisites. Moreover, under current technology trends the demand for diesel is expected to increase leading to a possible surplus of light fuels in the future. Recent research has demonstrated that significant fuel consumption reduction is possible based on a direct injection gasoline engine system, when a low quality gasoline stream such as Naphtha is used in compression ignition mode. With this fuel, the engine will be at least as efficient and clean as current diesel engines but will be more cost effective (lower injection pressure, HC/CO after-treatment rather than NOx).

In this paper blends of diesel and gasoline (dieseline) fuelled Partially Premixed Compression Ignition (PPCI) combustion and the comparison to conventional diesel combustion is investigated. The tests are carried out using a light duty four cylinder Euro IV diesel engine. The engine condition is maintained at 1800 rpm, 52 Nm (equivalent IMEP around 4.3 bar). Different injection timings and different amounts of EGR are used to achieve the PPCI combustion. The results show that compared to the conventional diesel combustion, the smoke and NOx emissions can be reduced by more than 95% simultaneously with dieseline fuelled PPCI combustion. The particle number total concentration can be reduced by 90% as well as the mean diameter (from 54 nm for conventional diesel to 16 nm for G50 fuelled PPCI). The penalty is a slightly increased noise level and lower indicated efficiency, which is decreased from 40% to 38.5%.