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Addition of nitroalkanes to gasoline is shown to reduce the octane quality. The reduction in the Motor Octane Number (MON) is greater than the reduction in the Research Octane Number (RON). In other words addition of nitroalkanes causes an increase in octane sensitivity. The temperature of the compressed air/fuel mixture in the MON test is higher then in the RON test. Through chemical kinetic modelling, we are able to show how the temperature dependence of the reactions responsible for break-up of the nitroalkane molecule can lead to an increase in octane sensitivity. Results are presented from an Homogenous Charge Compression Ignition (HCCI) engine with a homogeneous charge in which the air intake temperature was varied. When the engine was operated on gasoline-like fuels containing nitroalkanes, it was observed that the combustion phasing was much more sensitive to the air intake temperature. This suggests a possible means of controlling combustion phasing for HCCI.

Lubricant samples were aged on a SI bench engine that was run using ten different gasoline fuels. For each gasoline tested, the oxidative stability of the lubricant and the extent of engine wear was assessed in terms of a number of different parameters. Surprisingly, it was found that fuels containing higher levels of olefin (whether C8 olefin, or a C5/C6 olefin blend, or a catalytically cracked refinery stream) performed directionally better than a reference gasoline with low levels of aromatics and olefins. Fuels with a higher final boiling point and higher aromatic content, appeared to be associated with enhanced levels of sludge formation than the reference gasoline, but did not give rise to enhanced engine wear.