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In order to develop the valve rocker arm material for the new type engine, we investigated various materials whose chemical compositions were selected using 30% chromium cast iron, which had shown good results in screening evaluation tests, as the basis. High chromium cast irons are well known for their abrasive wear resistance, but it has been very difficult to apply them for use as rocker arm material because their machinability is very poor, and because it is difficult for them to have a regular microstructure. In this paper, both the manufacturing method for the rocker arm which decreases the disadvantages that high chromium cast iron have and the rocker arm material best suited for this method are described.

The automobile industry currently faces many challenges which may greatly impact on its foundry operations. One of these challenges, consumers'' demand for greater fuel efficiency, can be met by reducing the weight of castings used in automobiles, and minimizing engineering tolerances. In answer to this particular demand, engine foundries have begun to either produce cylinder blocks or other castings with aluminum rather than cast iron. However, if a reduction in weight (thin wall and near-net shaping) can be realized with cast iron, there would be numerous merits from the perspective of cost and compactness and there would be much more flexibility in automotive parts design.

This paper describes the application of a life prediction method for stainless steel exhaust manifolds. Examination of the exhaust manifold cracks indicated that many of the failures could be attributed to out-of-phase thermal fatigue due to compressive strains that occur at high temperatures. Therefore, the plastic strain range was used as the crack initiation criteria. In addition, the comparison of the calculated thermal fatigue stress-strain hysteresis to the experimental hysteresis made it clear that it was essential to use the stress-strain data that was obtained through tensile and compression testing by keeping the test specimens at the maximum temperature of the thermal fatigue test mode. A finite element crack prediction method was developed using the aforementioned material data and good results were obtained.

At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.

In an evaluation of crashworthiness for the cars made of aluminum alloys, the evaluation considering fracture phenomenon comes to be needed because conventional aluminum alloys have low fracture strain (10-20%). In case of the development of a B-Pillar made by die cast, if crack occurrence, furthermore, separation of a part can be estimated by using CAE in crashworthiness evaluations, we can reduce the number of prototype makings and the cost of development using expensive dies. Therefore, we performed crashworthiness evaluations by CAE using some sort of a damage & fracture material model. It is known as “Orthotropic damage & fracture model”.

This paper describes a new 2.4-liter 16-valve in-line four-cylinder engine, 2TZ-FE, which has been mounted horizontally on a new minivan, the TOYOTA PREVIA. This engine has the TOYOTA original compact 4-valve DOHC system (scissors gear mechanism), and TOYOTA's newest technologies, such as 75 deg. slant cylinder and Separated accessory Drive System. The compact configuration reduces the height of this engine to only 44Omm (17.3-inches). Engine location is under the flat floor on the midship rear-wheel-drive vehicle and allows the PREVIA to have a spacious cabin with walkthrough. Its high performance, 103kW at 500Orpm and 209Nm at 4000rpm, has been achieved through updated technologies, such as: Knock Controll System (KCS), well studied intake system and exhaust manifold which is made of stainless steel double pipe. At the same time, high reliability and quietness have been achieved for the 2TZ-FE by TOYOTA's updated technologies.

It has been reported that engine oils containing magnesium detergents gel under special conditions. The authors have previously reported on the mechanism by which magnesium detergents form needle crystals, which is the main cause of the gelation[1]. For this article, the authors conducted tests in actual vehicles using several types of engine oils containing magnesium detergents, including oils for which gelation problems have been reported in the market. The gelation was reproduced, and the test oils were ranked by their propensity to gel. In addition, a laboratory test method was used in which water and CO2 were mixed into engine oil under controlled conditions, then left stored in a bottle for twenty days, after which the kinematic viscosity and the quantity of insolubles of the mixture were measured. The study demonstrated the correlation between the laboratory test method and the actual vehicle tests.

Roadway departure mitigation systems for helping to avoid and/or mitigate roadway departure collisions have been introduced by several vehicle manufactures in recent years. To support the development and performance evaluation of the roadway departure mitigation systems, a set of commonly seen roadside surrogate objects need to be developed. These objects include grass, curbs, metal guardrail, concrete divider, and traffic barrel/cones. This paper describes how to determine the representative color of these roadside surrogates. 24,762 locations with Google street view images were selected for the color determination of roadside objects. To mitigate the effect of the brightness to the color determination, the images not in good weather, not in bright daylight and under shade were manually eliminated. Then, the RGB values of the roadside objects in the remaining images were extracted.

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).

Recently, use of aluminum engine parts has increased for fuel economy and power improvements. Aluminum cylinder heads, for example, are currently used in most engines. But, only low performance engine coolants are available for prevention of heat-transfer corrosion of aluminum cylinder heads. The authors have studied a laboratory test method that is able to accurately evaluate the performance of engine coolants for prevention of aluminum cylinder head corrosion. And we have developed the new test method by changing the test specimen temperature higher and the engine coolant temperature lower than the ASTM D4340 test. The new test has been confirmed engine bench test. We evaluated further the performance of many engine coolants of the world for prevention of aluminum cylinder head corrosion using the new test. We have known that there were a lot of poor performance engine coolants in the world.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.

Replacing the metal car roof with conventional solar modules results in the increase of total car weight and change of center of mass, which is not preferable for car designing. Therefore, weight reduction is required for solar modules to be equipped on vehicles. Exchanging glass to plastic for the cover plate of solar module is one of the major approaches to reduce weight; however, load bearing property, impact resistance, thermal deformation, and weatherability become new challenges. In this paper a new solar module structure that weighs as light as conventional steel car roofs, resolving these challenges is proposed.

The effects of lubricant oil and fuel properties on low speed pre-ignition (LSPI) occurrence in boosted S.I. engines were experimentally evaluated with multi-cylinder engine and de-correlated oil and fuel matrices. Further, the auto-ignitability of fuel spray droplets and evaporated homogeneous fuel/oil mixtures were evaluated in a combustion bomb and pressure differential scanning calorimetry (PDSC) tests to analyze the fundamental ignition process. The work investigated the effect of engine conditions, fuel volatility and various lubricant additives on LSPI occurrence. The results support the validity of aspects of the LSPI mechanism hypothesis based on the phenomenon of droplets of lubricant oil/fuel mixture (caused by adhesion of fuel spray on the liner wall) flying into the chamber and autoigniting before spark ignition.

It may be possible to simplify the structure and control systems of a lithium-ion battery by replacing the conventional liquid electrolyte with a solid electrolyte, resulting in higher energy density. However, power performance is a development issue of batteries using a solid electrolyte. To increase battery power performance, in addition to lithium ionic conductivity within the bulk of the electrolyte, it is also necessary to boost the lithium ionic conductivity at the interface between the electrode active material and the electrolyte, and to boost electron and lithium ionic conductivity within the cathode and anode active material. This research studied the mechanism of resistance reduction by electrode surface modification. Subsequently, this research attempted to improve electron conductivity by simultaneously introducing oxygen vacancies and carrying out nitrogen substitution in the crystalline structure of the Li4Ti5O12 anode active material.

We have tried to improve damping capacity of an aluminum alloy by means of dispersing ceramic particles (low damping SiC and high damping NdNbO4) of different sizes and volume fractions in the aluminum alloy by powder metallurgy. It is shown that the damping capacity is increased in every case accompanying an increase of Young's modulus. It is also shown that the intrinsic damping capacity of dispersed particles does not play a role in improving the damping capacity. The increase of the damping capacity seems to be attributed to dislocations breakaway, interaction of fine particles and dislocations, and relaxation of interface between ceramic particles and aluminum matrix.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

We have taken notice of Zn-Fe alloy electroplating with an eye to developing new corrosion-resistant steel sheets for automotive use with both cosmetic corrosion resistance and perforating corrosion resistance, and as a result of investigations into its paintability and corrosion resistance over the whole range of its compositions, we have come to a conclusion that steel sheets with two-layer Zn-Fe alloy electroplating that consists of a thin upper layer with a 75 to 85% Fe content and a lower layer with a 10 to 20% Fe content is the best choice.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

In an effort to reduce mass, future automotive bodies will feature lower gage steel or lighter weight materials such as aluminum. An unfortunate side effect of lighter weight bodies is a reduction in sound transmission loss (TL). For barrier based systems, as the total system mass (including the sheet metal, decoupler, and barrier) goes down the transmission loss is reduced. If the reduced surface density from the sheet metal is added to the barrier, however, performance can be restored (though, of course, this eliminates the mass savings). In fact, if all of the saved mass from the sheet metal is added to the barrier, the TL performance may be improved over the original system. This is because the optimum performance for a barrier based system is achieved when the sheet metal and the barrier have equal surface densities. That is not the case for standard steel constructions where the surface density of the sheet metal is higher than the barrier.