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As governmental agencies focus on low levels of the oxides of nitrogen (NOx) emissions compliance, new off-road applications are being reviewed for both regulated and unregulated emissions to understand the technological challenges and requirements for improved emissions performance. The California Air Resources Board (CARB) has declared its intention to pursue more stringent NOX standards for the off-road market. As part of this effort, CARB initiated a program to provide a detailed characterization of emissions meeting the current Tier 4 off-road standards [1]. This work focused on understanding the off-road market, establishing a current technology emissions baseline, and performing initial modeling on potential low NOx solutions. This paper discusses a part of this effort, focuses on the emissions characterization from two non-road engine platforms, and compares the emissions species from different approaches designed to meet Tier 4 emissions regulations.

The 2007 emission standards for both light-duty and heavy-duty diesel vehicles remain a challenge. A level of about 90% NOx conversion is required to meet the standards. Technologies that have the most potential to achieve very high NOx conversion at low temperatures of diesel exhaust are lean NOx traps (LNTs) and Selective Catalytic Reduction (SCR) of NOx using aqueous urea, typically known as Urea SCR. The LNT has the advantage of requiring no new infrastructure, and does not pose any new customer compliance issues. However, Urea SCR has high and durable NOx conversion in a wider temperature window, a lower equivalent fuel penalty, and lower system cost. On a technical basis, Urea SCR has the best chance of meeting the 2007 NOx targets. This paper reviews the results of some demonstration programs for both light-and heavy-duty applications.

Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.

Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.

Since the conception of the internal combustion engine, smoky and ill-smelling exhaust was prevalent. Over the last century, significant improvements have been made in improving combustion and in treating the exhaust to reduce these effects. One group of compounds typically found in exhaust, polycyclic aromatic hydrocarbons (PAH), usually occurs at very low concentrations in diesel engine exhaust. Some of these compounds are considered carcinogenic, and most are considered hazardous air pollutants (HAP). Many methods have been developed for sampling, handling, and analyzing PAH. For this study, an improved method for dilute exhaust sampling was selected for sampling the PAH in diesel engine exhaust. This sampling method was used during transient engine operation both with and without aftertreatment to show the effect of aftertreatment.

The commercial vehicle industry continues to move in the direction of improving brake thermal efficiency while meeting more stringent diesel engine emission requirements. This study focused on demonstrating future emissions by using an exhaust burner upstream of a conventional aftertreatment system. This work highlights system results over the low load cycle (LLC) and many other pertinent cycles (Beverage Cycle, and Stay Hot Cycle, New York Bus Cycle). These efforts complement previous works showing system performance over the Heavy-Duty FTP and World Harmonized Transient Cycle (WHTC). The exhaust burner is used to raise and maintain the Selective Catalytic Reduction (SCR) catalyst at its optimal temperature over these cycles for efficient NOX reduction. This work showed that tailpipe NOX is significantly improved over these cycles with the exhaust burner.

Engine and aftertreatment solutions have been identified to meet the upcoming ultra-low NOX regulations on heavy duty vehicles in the United States and Europe. These standards will require changes to current conventional aftertreatment systems for dealing with low exhaust temperature scenarios while increasing the useful life of the engine and aftertreatment system. Previous studies have shown feasibility of meeting the US EPA and California Air Resource Board (CARB) requirements. This work includes a 15L diesel engine equipped with cylinder deactivation (CDA) and an aftertreatment system that was fully DAAAC aged to 800,000 miles. The aftertreatment system includes an e-heater (electric heater), light-off Selective Catalytic Reduction (LO-SCR) followed by a primary aftertreatment system containing a DPF and SCR.

In 2020, CARB adopted the low NOX omnibus ruling, which provided revisions to on-road heavy duty engine compliance standards and certification practices. As part of the updates to the regulation, CARB has introduced a new in-use vehicle testing process that broadens the operation modes tested and considers the manufacturer’s intended vehicle application. Compared to the previous method, or the Not-to-Exceed approach, cold start and low ambient temperature provisions were included as part of the updates. The inclusion of low temperature operation requires the OEMs to design a robust engine and aftertreatment package that extends NOX conversion performance. The following work discusses the NOX emissions performance impact in a low temperature ambient environment. The engine and aftertreatment system evaluated was designed to comply with CARB’s low NOX regulations. The cycles tested included the CARB Southern NTE cycle and an FTP-LLC protocol.

Typical two-site storage-based SCR plant models in literature consider NH3 stored in the first site to participate in NH3 storage, NOx conversion and second site to only participate in NH3 storage passively. This paper focuses on quantifying the impact of stored NH3 in the second site on the overall NOx conversion for an ultra-low NOx system due to intra site NH3 mass transfer. Accounting for this intra site mass transfer leads to better prediction of SCR out NH3 thus ensuring compliance with NH3 coverage targets and improved dosing characteristics of the controller that is critical to achieving ultra-low NOx standard. The stored NH3 in the second site undergoes mass transfer to the first site during temperature ramps encountered in a transient cycle that leads to increased NOx conversion in conditions where the dosing is switched off. The resultant NH3 coverage fraction prediction is critical in dosing control of SCR.

This work is a part of medium-duty Low NOx technology development project with a focus on evaluating a combination of engine and advanced aftertreatment for 0.02 g/bhp-hr NOx regulation proposed by CARB (California air resource board). In this project, a control oriented chemical kinetics model of SCR (Selective catalytic reduction) was used in the aftertreatment controller that is susceptible to performance degradation due to hydrothermal and chemical aging. This paper focuses on modeling the NOx conversion and NH3 storage characteristics using a controls oriented SCR plant model which is further used for a model-based urea dosing scheme. A set of steady state reactor tests were used to calibrate the SCR performance at degreened, hydrothermal only and hydrothermal + chemical aging conditions and also to determine inhibition factors related to aging. The resultant model is capable of simulating SCR performance deterioration such as a reduction in NOx conversion and NH3 storage.

Commercial vehicles require fast aftertreatment heat-up in order to move the SCR catalyst into the most efficient temperature range to meet upcoming NOX regulations. Today’s diesel aftertreatment systems require on the order of 10 minutes to heat up during a cold FTP cycle. The focus of this paper is to heat up the aftertreatment system as quickly as possible during cold starts and maintain a high temperature during low load, while minimizing fuel consumption. A system solution is demonstrated using a heavy-duty diesel engine with an end-of-life aged aftertreatment system targeted for 2027 emission levels using various levels of controls. The baseline layer of controls includes cylinder deactivation to raise the exhaust temperature more than 100° C in combination with elevated idle speed to increase the mass flowrate through the aftertreatment system. The combination yields higher exhaust enthalpy through the aftertreatment system.

Advanced combustion strategies used to improve efficiency, emissions, and performance in internal combustion engines (IC) alter the chemical composition of engine-out emissions. The characterization of exhaust chemistry from advanced IC engines requires an analytical system capable of measuring a wide range of compounds. For many years, the widely accepted Coordinating Research Council (CRC) Auto/Oil procedure[1,2] has been used to quantify hydrocarbon compounds between C1 and C12 from dilute engine exhaust in Tedlar polyvinyl fluoride (PVF) bags. Hydrocarbons greater than C12+ present the greatest challenge for identification in diesel exhaust. Above C12, PVF bags risk losing the higher molecular weight compounds due to adsorption to the walls of the bag or by condensation of the heavier compounds. This paper describes two specialized exhaust gas sampling and analytical systems capable of analyzing the mid-range (C10 - C24) and the high range (C24+) hydrocarbon in exhaust.

The Tank-Automotive RD&E Center periodically conducts foreign materiel evaluations to assess the current state of the art for ground vehicle technologies. The Propulsion Laboratory is conducting performance evaluations of an opposed-piston two-stroke diesel tank engine produced by the Kharkov Design Bureau in Ukraine. A key factor in the performance of all two-stroke engines is the scavenging process, which determines how well the cylinders are emptied of exhaust and filled with fresh air. The overall air flow rate is not sufficient to determine this, as a significant amount of air may be lost through the exhaust ports during the scavenging process. The inlet tracer gas method was employed to provide the additional data required. With methane as the tracer, it produced reasonable and consistent data over a wide range of engine speeds and loads. The inlet tracer gas method was found to be an effective tool for measuring the scavenging performance of a running two-stroke diesel engine.

Results of engine bench tests on a 1998 heavy-duty diesel engine have confirmed the emissions reduction performance of a U.S. Environmental Protection Agency (EPA) registered platinum/cerium bimetallic fuel borne catalyst (FBC) used with several different catalyzed and uncatalyzed diesel particulate filters (DPF's). Performance was evaluated on both a 450ppm sulfur fuel (No.2 D) and a CARB 50ppm low sulfur diesel (LSD) fuel. Particulate emissions of less than 0.02g/bhp-hr were achieved on several combinations of FBC and uncatalyzed filters on 450ppm sulfur fuel while levels of 0.01g/bhp-hr were achieved for both catalyzed and uncatalyzed filters using the FBC with the low sulfur CARB fuel. Eight-mode steady state testing of one filter and FBC combination with engine timing changes produced a 20% nitrogen oxide (NOx) reduction with particulates (PM) maintained at 0.01g/bhp-hr and no increase in measured fuel consumption.

Semi-volatile organic compounds (SVOC) are a group of compounds in engine exhaust that either form during combustion or are part of the fuel and lubricating oil. Since these compounds occur at very low concentrations in diesel engine exhaust, the methods for sampling, handling, and analyzing these compounds are critical to obtaining good results. An improved dilute exhaust sampling method was used for sampling and analyzing SVOC in engine exhaust, and this method was performed during transient engine operation. A total of 22 different SVOC were measured using a 2012 medium-duty diesel engine. This engine was equipped with a stock diesel oxidation catalyst (DOC), a diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst in series. Exhaust concentrations for SVOC were compared both with and without exhaust aftertreatment. Concentrations for the engine-out SVOC were significantly higher than with the aftertreatment present.

The classical approach to prepare engine exhaust emissions control systems for evaluation and certification is to condition the fresh parts by aging the systems on an engine/dynamometer aging stand. For diesel systems this can be a very lengthy process since the estimated service life of the emissions control systems can be several hundred thousand miles. Thus full useful life aging can take thousands of engine bench aging hours, even at elevated temperatures, making aging a considerable cost and time investment. Compared to gasoline engines, diesel engines operate with very low exhaust gas temperatures. One of the major sources of catalyst deactivation is exposure to high temperature [ 1 ].

This study compared four different candidate fuels which were prepared by blending different components with a typical No. 2 diesel. Two fuels were blended with a synthetic diesel prepared from natural gas condensate, and all candidate fuels were splash blended with a proprietary additive package from International Fuel Technology Inc. (IFT). These fuels were then compared to the No. 2 diesel and to a California Air Resources Board (CARB) equivalent diesel fuel. The comparisons included fuel properties such as sulfur content, aromatics, cetane, lubricity, distillation; emissions; and fuel consumption. Emission testing was conducted on a 1991 Detroit Diesel Series 60. The Environmental Protection Agency (EPA) transient cycle was utilized for emissions, fuel characterization was performed according to ASTM standards, and fuel consumption was calculated by the carbon balance method.

The 2010 emission standards for heavy-duty diesel engines in the U.S. have established a limit for oxides of nitrogen (NOx) emissions of 0.20 g/bhp-hr., a 90% reduction from the previous emission standards. However, it has been projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with the 2010 emission standards, the upcoming National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and ozone will not be achieved in California without further significant reductions in NOx emissions from the heavy-duty vehicle fleet. Given this, there is potential of further reduction in NOx emissions limit standards for heavy duty engines in the US. Recently there have been extensive studies and publications focusing on ultra-low NOx after treatment technologies that help achieve up to 0.02g/bhp-hr. at tailpipe [1].

With the conclusion of the California Air Resources Board (CARB) Stage 1 Ultra-Low NOX (ULN) program, there continues to be a commitment for identifying potential pathways to demonstrate 0.02 g/bhp-hr NOX emissions. The Stage 1 program focused on achieving the ULN levels on the heavy-duty regulatory cycles utilizing a turbo-compound engine which required the integration of novel catalyst technologies and a supplemental heat source. While the aftertreatment configuration provided a potential solution to meet the ULN target, a complicated approach with a greenhouse gas (GHG) penalty was required to overcome challenges from low temperature exhaust. A subsequent Stage 2 program was concerned with the development of a new low load test cycle and evaluating the trade-off between GHG and tailpipe NOX on the Stage 1 ULN solution.

Despite considerable progress over the last several decades, California continues to face some of the most significant air quality problems in the United States. These continued issues highlight the need for further mobile source NOX reductions to help California and other areas meet ambient air quality targets mandated by the U.S. EPA. Beginning in 2014, the California Air Resources Board (CARB) launched a program aimed at demonstrating technologies that could enable heavy-duty on-highway engines to reach tailpipe NOX levels up to 90% below the current standards, which were implemented in 2010. At the same time, mandated improvements to greenhouse gas emissions (GHG) require that these NOX reductions be achieved without sacrificing fuel consumption and increasing GHG emissions.