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This paper describes experiments conducted to determine the regulated emissions, ozone-forming potentials, specific reactivities, and reactivity adjustment factors for eight butane and propane alternative fuel blends run on a light-duty vehicle, emission certified to be a California transitional low emission vehicle (TLEV) and converted to operate on liquefied petroleum gas (LPG). Duplicate EPA FTP emission tests were conducted with each fuel. Hydrocarbon speciation was utilized to determine reactivity-adjusted non-methane organic gases (NMOG) emissions for one test on each fuel. Results showed that all eight fuels could allow the converted vehicle to pass California ultra-low emission vehicle (ULEV) NMOG and oxides of nitrogen (NOx) standards. Six of the eight fuels could allow the vehicle to pass ULEV carbon monoxide (CO) standards. BUTANE has been an important gasoline blending component for many years.

Small engines which are friendly toward the environment are needed all over the world, whether the need is expressed in terms of energy efficiency, useful engine life, health benefits for the user, or emission regulations enacted to protect a population or an ecologically-sensitive area. Progress toward the widespread application of lower-impact small engines is being made through engine design, matching of engine to equipment and task, aftertreatment technology, alternative and reformulated fuels, and improved lubricants. This paper describes three research and development projects, focused on the interrelationships of fuels, lubricants, and emissions in Otto-cycle engines, which were conducted by Southwest Research Institute. All the work reported was funded internally as part of a commitment to advance the state of small engine technology and thus enhance human utility.

A project was conducted by Southwest Research Institute on behalf of the California Air Resources Board and the South Coast Air Quality Management District to demonstrate the technical feasibility of utilizing closed-loop three-way catalyst technology in off-road equipment applications. Five representative engines were selected, and baseline emission-tested using both gasoline and LPG. Emission reduction systems, employing three-way catalyst technology with electronic fuel control, were designed and installed on two of the engines. The engines were then installed in a fork lift and a pump system, and limited durability testing was performed. Results showed that low emission levels, easily meeting CARB's newly adopted large spark-ignited engine emission standards, could be achieved.

A new approach to reclaiming the spoil areas produced by area-type mining operations has been developed. This system uses a machine known as a winch-dozer, consisting of a pair of large back-to-back buckets which are drawn by cable across spoil piles, moving back and forth between a “tailblock” anchor and a “drawworks” winch unit developed as an attachment to a large crawler tractor. The system is expected to reduce the cost of reclamation leveling by 40-50%. The system permits more effective power utilization due to the blade system's light weight, induces caving of spoil banks, and permits moving spoil in both directions of blade travel.

The Texas Department of Transportation (TxDOT) began using an emulsified diesel fuel in July 2002. They initiated a simultaneous study of the effectiveness of this fuel in comparison to 2D on-road diesel fuel, which they use in both their on-road and off-road equipment. The study also incorporated analyses for the fleet operated by the Associated General Contractors (AGC) in the Houston area. Some members of AGC use 2D off-road diesel fuel in their equipment. The study included comparisons of fuel economy and emissions for the emulsified fuel relative to the conventional diesel fuels. Cycles that are known to be representative of the typical operations for TxDOT and AGC equipment were required for use in this study. Four test cycles were developed from data logged on equipment during normal service: 1) the TxDOT Telescoping Boom Excavator Cycle, 2) the AGC Wheeled Loader Cycle, 3) the TxDOT Single-Axle Dump Truck Cycle, and 4) the TxDOT Tandem-Axle Dump Truck Cycle.

Tests were conducted on a variety of commercially available spark plugs to determine the influence of igniter design on initial kernel formation and overall performance. Flame kernel formation was investigated using high-speed schlieren visualization. The flame growth rate was quantified using the area of the burned gas region. The results showed that kernel growth rate was heavily influenced by electrode geometry and configuration. The igniters were also tested in a bomb calorimeter to determine the levels of supplied and delivered energy. The typical ratio of supplied to delivered energy was 20% and igniters with a higher internal resistance delivered more energy and had faster kernel formation rates. The exception was plugs with large amounts of conductive mass near the electrodes, which had very slow kernel formation rates despite relatively high delivered energy levels.

Over twenty prototype hybrid buses and other commercial vehicles are currently being completed and deployed. These vehicles are primarily “series” hybrid vehicles which use electric motors for primary traction while internal combustion engines, or high-speed turbine engines connected to generators, supply some portion of the electric propulsion and battery recharge energy. Hybrid-electric vehicles have an electric energy storage system on board that influences the operation of the heat engine. The storage system design and level affect the vehicle emissions, electricity consumption, and fuel economy. Existing heavy-duty emissions test procedures require that the engine be tested over a transient cycle before it can be used in vehicles (over 26,000 lbs GVW). This paper describes current test procedures for assessing engine and vehicle emissions, and proposes techniques for evaluating engines used with hybrid-electric vehicle propulsion systems.

The 2007 emission standards for both light-duty and heavy-duty diesel vehicles remain a challenge. A level of about 90% NOx conversion is required to meet the standards. Technologies that have the most potential to achieve very high NOx conversion at low temperatures of diesel exhaust are lean NOx traps (LNTs) and Selective Catalytic Reduction (SCR) of NOx using aqueous urea, typically known as Urea SCR. The LNT has the advantage of requiring no new infrastructure, and does not pose any new customer compliance issues. However, Urea SCR has high and durable NOx conversion in a wider temperature window, a lower equivalent fuel penalty, and lower system cost. On a technical basis, Urea SCR has the best chance of meeting the 2007 NOx targets. This paper reviews the results of some demonstration programs for both light-and heavy-duty applications.

Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.

This paper discusses the techniques and diagnostic significance of atomic absorption, atomic emission, and infrared spectrometric analysis of crankcase lubricants, with the use of supplementary data where pertinent. The parameters affecting used oil analytical data are discussed in terms of examples from Army general purpose vehicle test engines. Wear metals in used gear oils are also discussed and examples are given. Analytical methods and their applications are fully described, and the equipment and procedures for infrared spectroscopy and gas chromatography techniques are outlined.

Solid and metallic ash particle number (PN) and particulate matter (PM) mass emission measurements were performed on a heavy-duty (HD) on-highway diesel engine and a compressed natural gas (CNG) engine. Measurements were conducted under transient engine operation that included the FTP, WHTC and RMC. Both engines were calibrated to meet CARB ultra low NOX emission target of 0.02 g/hp-hr, a 90% reduction from current emissions limit. The HD diesel engine final exhaust configuration included a number of aftertreatement sub-systems in addition to a selective catalytic reduction filter (SCRF). The stoichiometric CNG engine final configuration included a closed coupled Three Way Catalyst (ccTWC) and an under floor TWC (ufTWC). The aftertreatment systems for both engines were aged for a full useful life (FUL) of 435,000 miles, prior to emissions testing. PM mass emissions from both engines were comparable and well below the US EPA emissions standard.

Five light-duty vehicles were used to investigate HC, CO, and NOx emissions and fuel economy sensitivity to changes in the length of soak period preceding the EPA Urban Dynamometer Driving Schedule (UDDS). Emission tests were conducted following soak periods 10 minutes to 36 hours in length. Each of the first 8 minutes of the driving cycle was studied separately to observe vehicle warm-up. Several engine and fuel system temperatures were monitored during soak and run periods and example trends are illustrated. The extent to which emission rates and fuel consumption are affected by soak period length is discussed.

This paper describes a research program on exhaust emissions from snowmobile engines, including both emissions characterization and estimation of national emissions impact. Tests were conducted on three popular 2-stroke twins and on one rotary (Wankel) engine. Emissions that were measured included total hydrocarbons, (paraffinic) hydrocarbons by NDIR, CO, CO2, NO (by two methods), NOx, O2, aldehydes, light hydrocarbons, particulate, and smoke. Emissions of SOx were estimated on the basis of fuel consumed, and evaporative hydrocarbons were projected to be negligible for actual snowmobile operation. During emissions tests, intake air temperature was controlled to approximately -7°C (20°F), and room air at approximately 24°C (75°F) was used for engine cooling. Based on test results and the best snowmobile population and usage data available, impact of snowmobile emissions on a national scale was computed to be minimal.

The optical spark plug probe and ionization head gasket probe developed at Sandia Laboratories were applied to one cylinder of a production multicylinder automotive gasoline engine. The purpose of this application is to eventually study combustion phenomena leading to high emissions under cold start and cold idle conditions. As a first step in studying cold start combustion and emissions issues, diagnostic instrumentation was simultaneously applied to a production engine under steady state idle, road load and an intermediate load-speed condition. The preliminary application of such instrumentation is the subject of the present paper. The spark plug probe was redesigned for ease of use in production engines and to provide a more robust design. The two probes were geometrically oriented to obtain radial line-up between the optical windows and ionization probes. Data were taken simultaneously with both probes at the three load-speed conditions mentioned above.

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH₃) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH₃ transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.

This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.

Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH₃ storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH₃ storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH₃ slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.

The process of developing, parameterizing, validating, and maintaining models occurs within a wide variety of tools, and requires significant time and resources. To maximize model utilization, models are often shared between various toolsets and experts. One common example is sharing aircraft engine models with airframers. The functionality of a given model may be utilized and shared with a secondary model, or multiple models may run collaboratively through co-simulation. There are many technical challenges associated with model sharing and co-simulation. For example, data communication between models and tools must be accurate and reliable, and the model usage must be well-documented and perspicuous for a user. This requires clear communication and understanding between computer scientists and engineers. Most often, models are developed by engineers, whereas the tools used to share the models are developed by computer scientists.

Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were a 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NOx+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NOx emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NOx increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines.