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Technical Paper

The Development of Auto Temp II

1972-02-01
720288
The development of the AUTO TEMP II Temperature Control System used in Chrysler Corp. vehicles is summarized. A description of the design, development, function, and manufacturing aspects of the control system is presented, with emphasis on unique control parameters, reliability, serviceability, and check-out of production assemblies. Auto Temp II was developed by Chrysler in conjunction with Ranco Incorporated. The servo-controlled, closed-loop system, which has a sensitivity of 0.5 F, utilizes a water-flow control valve for temperature control, along with a cold engine lockout. The basic components are: sensor string, servo, and amplifier. All automatic functions involving control of mass flow rate, temperature, and distribution of the air entering the vehicle, are encompassed in one control unit. All components are mechanically linked through the gear train and are responsive to the amplifier through the feedback potentiometer.
Technical Paper

Technical Advantages of Urea SCR for Light-Duty and Heavy-Duty Diesel Vehicle Applications

2004-03-08
2004-01-1292
The 2007 emission standards for both light-duty and heavy-duty diesel vehicles remain a challenge. A level of about 90% NOx conversion is required to meet the standards. Technologies that have the most potential to achieve very high NOx conversion at low temperatures of diesel exhaust are lean NOx traps (LNTs) and Selective Catalytic Reduction (SCR) of NOx using aqueous urea, typically known as Urea SCR. The LNT has the advantage of requiring no new infrastructure, and does not pose any new customer compliance issues. However, Urea SCR has high and durable NOx conversion in a wider temperature window, a lower equivalent fuel penalty, and lower system cost. On a technical basis, Urea SCR has the best chance of meeting the 2007 NOx targets. This paper reviews the results of some demonstration programs for both light-and heavy-duty applications.
Technical Paper

System Level Simulation of H2 ICE after Treatment System

2024-04-09
2024-01-2625
Hydrogen Internal Combustion Engines (H2 ICE) are gaining recognition as a nearly emission-free alternative to traditional ICE engines. However, H2 ICE systems face challenges related to thermal management, N2O emissions, and reduced SCR efficiency in high humidity conditions (15% H2O). This study assesses how hydrogen in the exhaust affects after-treatment system components for H2 ICE engines, such as Selective Catalytic Reduction (SCR), Hydrogen Oxidation Catalyst (HOC), and Ammonia Slip Catalyst (ASC). Steady-state experiments with inlet H2 inlet concentrations of 0.25% to 1% and gas stream moisture levels of up to 15% H2O were conducted to characterize the catalyst response to H2 ICE exhaust. The data was used to calibrate and validate system component models, forming the basis for a system simulation.
Technical Paper

Spectrometric Analysis of Used Oils

1969-02-01
690776
This paper discusses the techniques and diagnostic significance of atomic absorption, atomic emission, and infrared spectrometric analysis of crankcase lubricants, with the use of supplementary data where pertinent. The parameters affecting used oil analytical data are discussed in terms of examples from Army general purpose vehicle test engines. Wear metals in used gear oils are also discussed and examples are given. Analytical methods and their applications are fully described, and the equipment and procedures for infrared spectroscopy and gas chromatography techniques are outlined.
Technical Paper

Solid Particle Number and Ash Emissions from Heavy-Duty Natural Gas and Diesel w/SCRF Engines

2018-04-03
2018-01-0362
Solid and metallic ash particle number (PN) and particulate matter (PM) mass emission measurements were performed on a heavy-duty (HD) on-highway diesel engine and a compressed natural gas (CNG) engine. Measurements were conducted under transient engine operation that included the FTP, WHTC and RMC. Both engines were calibrated to meet CARB ultra low NOX emission target of 0.02 g/hp-hr, a 90% reduction from current emissions limit. The HD diesel engine final exhaust configuration included a number of aftertreatement sub-systems in addition to a selective catalytic reduction filter (SCRF). The stoichiometric CNG engine final configuration included a closed coupled Three Way Catalyst (ccTWC) and an under floor TWC (ufTWC). The aftertreatment systems for both engines were aged for a full useful life (FUL) of 435,000 miles, prior to emissions testing. PM mass emissions from both engines were comparable and well below the US EPA emissions standard.
Video

SCR Deactivation Study for OBD Applications

2012-06-18
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications [1,2,3,4]. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO2 formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH3) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH3 transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Technical Paper

SCR Deactivation Study for OBD Applications

2012-04-16
2012-01-1076
Selective catalytic reduction (SCR) catalysts will be used to reduce oxides of nitrogen (NOx) emissions from internal combustion engines in a number of applications. Southwest Research Institute® (SwRI)® performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and an Fe-zeolite formulation. This work describes NOx timed response to ammonia (NH₃) transients as a function of thermal aging time and temperature. It has been proposed that the response time of NOx emissions to NH₃ transients, effected by changes in diesel emissions fluid (DEF) injection rate, could be used as an on-board diagnostic (OBD) metric. The objective of this study was to evaluate the feasibility and practicality of this OBD approach.
Video

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-06-18
This paper forms the third of a series and presents results obtained during the testing and development phase of a dedicated range extender engine designed for use in a compact class vehicle. The first paper in this series used real world drive logs to identify usage patterns of such vehicles and a driveline model was used to determine the power output requirements of a range extender engine for this application. The second paper presented the results of a design study. Key attributes for the engine were identified, these being minimum package volume, low weight, low cost, and good NVH. A description of the selection process for identifying the appropriate engine technology to satisfy these attributes was given and the resulting design highlights were described. The paper concluded with a presentation of the resulting specification and design highlights of the engine. This paper will present the resulting engine performance characteristics.
Technical Paper

SCR Deactivation Kinetics for Model-Based Control and Accelerated Aging Applications

2012-04-16
2012-01-1077
Selective Catalytic Reduction (SCR) catalysts are used to reduce NOx emissions from internal combustion engines in a variety of applications. Southwest Research Institute (SwRI) performed an Internal Research & Development project to study SCR catalyst thermal deactivation. The study included a V/W/TiO₂ formulation, a Cu-zeolite formulation and a Fe-zeolite formulation. This work describes NH₃ storage capacity measurement data as a function of aging time and temperature. Addressing one objective of the work, these data can be used in model-based control algorithms to calculate the current NH₃ storage capacity of an SCR catalyst operating in the field, based on time and temperature history. The model-based control then uses the calculated value for effective DEF control and prevention of excessive NH₃ slip. Addressing a second objective of the work, accelerated thermal aging of SCR catalysts may be achieved by elevating temperatures above normal operating temperatures.
Technical Paper

Preparation and Testing of an Electric Competition Vehicle

1991-08-01
911684
A Dodge Omni electric car was prepared for competition in an electric “stock car” 2-hour endurance event: the inaugural Solar and Electric 500 Race, April 7, 1991. This entry utilized a series-wound, direct-current 21-hp electric motor controlled by an SCR frequency and pulse width modulator. Two types of lead-acid batteries were evaluated and the final configuration was a set of 16 (6-volt each) deep-cycle units. Preparation involved weight and friction reduction; suspension modification; load, charge and temperature instrumentaltion; and electrical interlock and collision safety systems. Vehicle testing totalled 15 hours of operation. Ranges observed in testing with the final configuration were from 30 to 52 miles for loads of 175 to 90 amperes. These were nearly constant, continuous discharge cycles. The track qualifying speed (64mph) was near the 68 mph record set by the DEMI Honda at the event on the one-mile track.
Technical Paper

Post-Mortem Analysis of DAAAC and Conventionally Aged Aftertreatment Systems

2023-10-31
2023-01-1656
Upcoming regulations from CARB and EPA will require diesel engine manufacturers to validate aftertreatment durability with full useful life aged components. To this end, the Diesel Aftertreatment Accelerated Aging Cycle (DAAAC) protocol was developed to accelerate aftertreatment aging by accounting for hydrothermal aging, sulfur, and oil poisoning deterioration mechanisms. Two aftertreatment systems aged with the DAAAC protocol, one on an engine and the other on a burner system, were directly compared to a reference system that was aged to full useful life using conventional service accumulation. After on-engine emission testing of the fully aged components, DOC and SCR catalyst samples were extracted from the aftertreatment systems to compare the elemental distribution of contaminants between systems. In addition, benchtop reactor testing was conducted to measure differences in catalyst performance.
Technical Paper

Polycyclic Aromatic Hydrocarbons in Diesel Engine Exhaust Both with and without Aftertreatment

2018-09-10
2018-01-1812
Since the conception of the internal combustion engine, smoky and ill-smelling exhaust was prevalent. Over the last century, significant improvements have been made in improving combustion and in treating the exhaust to reduce these effects. One group of compounds typically found in exhaust, polycyclic aromatic hydrocarbons (PAH), usually occurs at very low concentrations in diesel engine exhaust. Some of these compounds are considered carcinogenic, and most are considered hazardous air pollutants (HAP). Many methods have been developed for sampling, handling, and analyzing PAH. For this study, an improved method for dilute exhaust sampling was selected for sampling the PAH in diesel engine exhaust. This sampling method was used during transient engine operation both with and without aftertreatment to show the effect of aftertreatment.
Technical Paper

Performance Evaluation of Advanced Emission Control Technologies for Diesel Heavy-Duty Engines

1999-10-25
1999-01-3564
To evaluate the performance of a variety of commercially available exhaust emission control technologies, the Manufacturers of Emission Controls Association (MECA) sponsored a test program at Southwest Research Institute (SwRI). The test engine was a current design heavy-duty diesel engine operated on standard No. 2 diesel (368 ppm) and lower sulfur (54 ppm) diesel fuel. Technologies evaluated included: diesel oxidation catalysts (DOCs), diesel particulate filters (DPFs), selective catalytic reduction (SCR), fuel-borne catalysts (FBCs) in combination with filters and oxidation catalysts, and combinations of the above technologies. The program was structured to demonstrate that a variety of exhaust emission control technologies, including exhaust gas recirculation, could be used to substantially reduce emissions from a modern MY 1998 heavy-duty diesel engine.
Technical Paper

Particle Emissions from Gasoline Direct Injection Engines during Engine Start-Up (Cranking)

2019-04-02
2019-01-1182
Engine start-up (cranking) can be an important source of particle emissions from vehicles. With the penetration of GDI vehicles in the global vehicle fleet, it is important to analyze and understand the contribution of start-up particle emissions from GDI vehicles, and the potential effects of fuel properties on that process. In this work, chassis dynamometer based investigation on the effect of several gasoline fuels (commercial and blended) on both, naturally aspirated and turbocharged GDI vehicles were conducted to understand the importance of engine start up, in particular, cranking. 10 commercially available gasoline fuels were tested on a naturally aspirated 2010 model year GDI vehicle, 3 among these commercially available fuels were tested on another 2009 model year turbocharged GDI vehicle, and 8 blended gasoline fuels were tested on 12 other GDI vehicles (7 turbocharged and 5 naturally aspirated) ranging in model years 2011-2015.
Technical Paper

Paint Integrity and Corrosion Sensor

2002-03-04
2002-01-0205
Atmospheric corrosion of steels, aluminum alloys, and Al-clad aluminum alloys is a problem for many civil engineering structures, commercial and military vehicles, and aircraft. Paint is usually the primary means to prevent the corrosion of steel bridge components, automobiles, trucks, and aircraft. Under ideal conditions, the coating provides a continuous layer that is impervious to moisture. At present, maintenance cycles for commercial and military aircraft and ground vehicles, as well as engineered structures, is based on experience and appearance rather than a quantitative determination of coating integrity. To improve the maintenance process and reduce costs, sensors are often used to monitor corrosion. The present suite of sensors designed to detect corrosion and marketed to predict the lifetime of the engineered components, however, are not useful for determining the condition of the protective paint coatings.
Technical Paper

Optimization of Surfactant and Catalyst Modified Urea-Water Solution Formulation for Deposit Reduction in SCR Aftertreatment Systems

2022-03-29
2022-01-0541
Selective Catalytic Reduction is the primary method of NOX emission abatement in lean-burn internal combustion. This process requires the decomposition of a 32.5 wt. % urea-water solution (UWS) to provide ammonia as a reducing agent for NOX, but at temperatures < 250 °C the injection of UWS is limited due to the formation of harmful deposits within an aftertreatment system and decreased ammonia production. Previous work has sufficiently demonstrated that the addition of surfactant and a urea/isocyanic acid (HNCO) decomposition catalyst to UWS can significantly decrease deposit formation within an aftertreatment system. The objective of this work was to further optimize the modified UWS formulation by investigating different types and concentrations of surfactants and titanium-based urea/HNCO catalyst. Because there is a correlation between surface tension and water evaporation, it was theorized that minimizing the surface tension of UWS would result in decreased deposit formation.
Technical Paper

Oil Consumption Pathway Impact on SCR-on-Filter Functional Performance and Lubricant Derived Ash Characteristics

2021-04-06
2021-01-0578
SCR-on-filter, or SCRoF, is an emerging technology for different market segments and vehicle applications. The technology enables simultaneous particulate matter trapping and NOX reduction, and provides thermal management and aftertreatment packaging benefits. However, there is little information detailing the lubricant derived exposure effects on functional SCR performance. A study was conducted to evaluate the impact of various oil consumption pathways on a light duty DOC and SCRoF aftertreatment system. This aftertreatment system was aged utilizing an engine test bench modified to enable increased oil consumption rates via three unique oil consumption pathways. The components were characterized for functional SCR performance, ash morphology, and ash deposition characteristics. This included utilizing techniques, such as SEM / EDS, to evaluate the ash structures and quantify the ash elemental composition.
Technical Paper

OPNET J1850 Network Simulator

1995-02-01
950037
MIL 3's OPNET simulator was used to model Chrysler's J1850 bus. Modeled were both J1850 bus characteristics and those portions of control modules (e.g., the engine controller) which communicate on the bus. Current Chrysler control module algorithms and proposed Chrysler J1850 message formats were used to design the control module models. The control module models include all messages which are transmitted at fixed intervals over the J1850 bus. The effects of function-based messages (e.g., messages to be transmitted on a particular sensor or push-button reading) on system load were investigated by transmitting an additional message with a fixed, relatively high priority at 50 millisecond intervals.
Technical Paper

Methanol Concentration Smart Sensor

1993-03-01
930354
A Methanol Concentration Smart Sensor has been developed to support the demand for alternately fueled vehicles operating on blends of methanol and gasoline in any mixture up to 85% methanol. The sensor measures concentration by exploiting the difference in dielectric properties between methanol and gasoline. The measurement is made based on the distributed capacitance of a coil of wire, contained in a reservoir through which the fuel passes. This signal, along with temperature compensation inputs, is then fed to an integral microprocessor, which provides a voltage output proportional to the methanol concentration of the fuel. The Powertrain Controller uses this information to modify injector pulse width and provide proper spark advance. This paper will explain the sensor's development methodology and function.
Journal Article

Meeting Future NOX Emissions Over Various Cycles Using a Fuel Burner and Conventional Aftertreatment System

2022-03-29
2022-01-0539
The commercial vehicle industry continues to move in the direction of improving brake thermal efficiency while meeting more stringent diesel engine emission requirements. This study focused on demonstrating future emissions by using an exhaust burner upstream of a conventional aftertreatment system. This work highlights system results over the low load cycle (LLC) and many other pertinent cycles (Beverage Cycle, and Stay Hot Cycle, New York Bus Cycle). These efforts complement previous works showing system performance over the Heavy-Duty FTP and World Harmonized Transient Cycle (WHTC). The exhaust burner is used to raise and maintain the Selective Catalytic Reduction (SCR) catalyst at its optimal temperature over these cycles for efficient NOX reduction. This work showed that tailpipe NOX is significantly improved over these cycles with the exhaust burner.
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