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Water injection is an effective method for knock control in spark-ignition engines. However, the requirement of a separate water source and the cost and complexity associated with a fully integrated system creates a limitation of this method to be used in volume production engines. The engine exhaust typically contains 10-15% water vapor by volume which could be condensed and potentially stored for future use. In this study, the exhaust condensate composition was assessed for its use as an effective replacement for distilled water. Specifically, condensate samples were collected pre and post-three-way catalyst (TWC) and analyzed for acidity and composition. The composition of the pre and post-TWC condensates was found to be similar however, the pre-TWC condensate was mildly acidic. The mild acidity has the potential to corrode certain components in the intake air circuit.

Southwest Research Institute (SwRI) converted a 2012 Buick Regal GS to use an engine with Dedicated EGR™ (D-EGR™). D-EGR is an engine concept that uses fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency [1]. To accomplish reformation of the gasoline in a cost-effective, energy efficient manner, a dedicated cylinder is used for both the production of EGR and reformate. By operating the engine in this manner, many of the sources of losses from traditional reforming technology are eliminated and the engine can take full advantage of the benefits of reformate. The engine in the vehicle was modified to add the following components: the dedicated EGR loop, an additional injector for delivering extra fuel for reformation, a modified boost system that included a supercharger, high energy dual coil offset (DCO) ignition and other actuators used to enable the control of D-EGR combustion.

A 13 L HD diesel engine was converted to run as a flame propagation engine using the HEDGE™ Dual-Fuel concept. This concept consists of pre-mixed gasoline ignited by a small amount of diesel fuel - i.e., a diesel micropilot. Due to the large bore size and relatively high compression ratio for a pre-mixed combustion engine, high levels of cooled EGR were used to suppress knock and reduce the engine-out emissions of the oxides of nitrogen and particulates. Previous work had indicated that the boosting of high dilution engines challenges most modern turbocharging systems, so phase I of the project consisted of extensive simulation efforts to identify an EGR configuration that would allow for high levels of EGR flow along the lug curve while minimizing pumping losses and combustion instabilities from excessive backpressure. A potential solution that provided adequate BTE potential was consisted of dual loop EGR systems to simultaneously flow high pressure and low pressure loop EGR.

The 2010 emissions standards for heavy-duty engines have established a limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, the California Air Resource Board (ARB) projects that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter (PM) and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.

A turbocharged 2.0 L PFI engine was modified to operate in a low-pressure loop and Dedicated EGR (D-EGR®) engine configuration. Both engine architectures were operated with a low and high octane gasoline as well as three ethanol blends. The core of this study focused on examining combustion differences at part and high loads between the selected fuels and also the different engine configurations. Specifically, the impact of the fuels on combustion stability, burn rates, knock mitigation, required ignition energy, and efficiency were evaluated. The results showed that the knock resistance generally followed the octane rating of the fuel. At part loads, the burn rates, combustion stability, and EGR tolerance was marginally improved with the high ethanol blends. When combustion was not knock or stability limited, the efficiency differences between the fuels were negligible. The D-EGR engine was much less sensitive to fuel changes in terms of burn rates than the LPL EGR setup.

Internal combustion engines (ICE) will be a part of personal transportation for the foreseeable future. One recent trend for engines has been downsizing which enables the engine to be run more efficiently over regulatory drive cycles. Due to downsizing, engine power density has increased which leads to problems with engine knock. Therefore, there is an increasing need to find a means to reduce the knock propensity of downsized engines. One of the ways of reducing knock propensity is by introducing Exhaust Gas Recirculation (EGR) into the combustion chamber, however, volumetric efficiency also reduces with EGR which places challenges on the boosting system. The individual benefits of high-pressure (HP-EGR) and low-pressure (LP-EGR) loop EGR system to assist the boosting system of a 2.0 L Gasoline Direct Injection (GDI) production engine are explored in this paper.

Four high-efficiency alternative combustion modes were modeled to determine the potential brake thermal efficiency (BTE) relative to a traditional lean burn compression ignition diesel engine with selective catalytic reduction (SCR) aftertreatment. The four combustion modes include stoichiometric pilot-ignited gasoline with EGR dilution (SwRI HEDGE technology), dual fuel premixed compression ignition (University of Wisconsin), gasoline partially premixed combustion (Lund University), and homogenous charge compression ignition (HCCI) (SwRI Clean Diesel IV). For each of the alternative combustion modes, zero-D simulation of the peak torque condition was used to show the expected BTE. For all alternative combustion modes, simulation showed that the BTE was very dependent on dilution levels, whether air or EGR. While the gross indicated thermal efficiency (ITE) could be shown to improve as the dilution was increased, the required pumping work decreased the BTE at EGR rates above 40%.

A push for more stringent emissions regulations has resulted in larger, increasingly complex aftertreatment solutions. In particular, oxides of nitrogen (NOX) and particulate matter (PM) have been controlled using two separate systems, selective catalytic reduction (SCR) and the catalyze diesel particulate filter (CDPF), or the functionality has been combined into a single device producing the SCR on filter (SCRoF). The SCRoF forgoes beneficial NO2 production present in the CDPF to avoid NH3 oxidation which occurs when using platinum group metals (PGM) for oxidation. In this study, mixed-metal oxides are shown to oxidize NO to NO2 without appreciable NH3 oxidation. This selectivity leads to enhanced performance when combined with a typical Cu-zeolite catalyst.

The dedicated exhaust gas recirculation (D-EGR®) concept developed by Southwest Research Institute (SwRI) has demonstrated a thermal efficiency increase on several spark-ignited engines at both low and high-load conditions. Syngas (H2+CO) is produced by the dedicated cylinder (D-cyl) which operates at a rich air-fuel ratio. The syngas helps to stabilize combustion under highly dilute conditions at low loads as well as mitigating knock at high loads. The D-cyl produces all the EGR for the engine at a fixed rate of approximately 25% EGR for a four-cylinder engine and 33% EGR for a six-cylinder engine. The D-cyl typically runs up to an equivalence ratio of 1.4 for gasoline-fueled engines, beyond which the combustion becomes unstable due to the decreasing laminar burning velocity caused by rich conditions. Conventional active-fueled and passive pre-chambers have benefits of inducing multi-site ignition and enhancing turbulence in the main chamber.

Recent legislation enacted for the European Union (EU) and the United States calls for a substantial reduction in particulate mass (and number in the EU) emissions from gasoline spark-ignited vehicles. The most prominent technology being evaluated to reduce particulate emissions from a gasoline vehicle is a wall flow filter known as a gasoline particulate filter (GPF). Similar in nature to a diesel particulate filter (DPF), the GPF will trap and store particulate emissions from the engine, and oxidize said particulate with frequent regeneration events. The GPF will also collect ash particles in the wall flow substrate, which are metallic components that cannot be oxidized into gaseous components. Due to high temperature operation and frequent regeneration of the GPF, the impact of ash on the GPF has the potential to be substantially different from the impact of ash on the DPF.

This paper describes a new method for measuring oil consumption using laser induced breakdown spectroscopy (LIBS). LIBS focuses a high energy laser pulse on a sample to form a transient plasma. As the plasma cools, each element produces atomic emission lines which can be used to identify and quantify the elements present in the original sample. In this work, a LIBS system was used on simulated engine exhaust with a focus on quantifying the inorganic components (termed ash) of the particulate emissions. Because some of the metallic elements in the ash almost exclusively result from lube oil consumption, their concentrations can also be correlated to an oil consumption rate. Initial testing was performed using SwRI’s Exhaust Composition Transient Operation Laboratory®(ECTO-Lab®) burner system so that oil consumption and ash mass could be precisely controlled.

Dedicated EGR (D-EGR) is an EGR strategy that uses in-cylinder reformation to improve fuel economy and reduce emissions. The entire exhaust of a sub-group of power cylinders (dedicated cylinders) is routed directly into the intake. These cylinders are run fuel-rich, producing H2 and CO (reformate), with the potential to improve combustion stability, knock tolerance and burn duration. A 2.0 L turbocharged D-EGR engine was packaged into a 2012 Buick Regal and evaluated on drive cycle performance. City and highway fuel consumption were reduced by 13% and 9%, respectively. NOx + NMOG were 31 mg/mile, well below the Tier 2 Bin 5 limit and just outside the Tier 3 Bin 30 limit (30 mg/mile).

There are numerous off-road diesel engine applications. In some applications there is more focus on metrics such as initial cost, packaging and transient response and less emphasis on fuel economy. In this paper a combustion concept is presented that may be well suited to these applications. The novel combustion concept operates in two distinct operation modes: lean operation at light engine loads and stoichiometric operation at intermediate and high engine loads. One advantage to the two mode approach is the ability to simplify the aftertreatment and reduce cost. The simplified aftertreatment system utilizes a non-catalyzed diesel particulate filter (DPF) and a relatively small lean NOx trap (LNT). Under stoichiometric operation the LNT has the ability to act as a three way catalyst (TWC) for excellent control of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx).

Formation of urea-derived deposits in selective catalytic reduction (SCR) aftertreatment systems continues to be problematic at temperatures at and below 215 °C. Several consequences of deposit formation include: NOx and NH3 slip, exhaust flow maldistribution, increased engine backpressure, and corrosion of aftertreatment components. Numerous methods have been developed to reduce deposit formation, but to date, there has been no solution for continuous low-temperature dosing of Urea-Water Solution (UWS). This manuscript presents a novel methodology for reducing low-temperature deposit formation in SCR aftertreatment systems. The methodology described herein involves incorporation and dissolution of an HNCO hydrolysis catalyst directly into the UWS. HNCO is a transient species formed by the thermolysis of urea upon injection of UWS into the aftertreatment system.

The Dedicated EGR (D-EGR®) engine has shown improved efficiency and emissions while minimizing the challenges of traditional cooled EGR. The concept combines the benefits of cooled EGR with additional improvements resulting from in-cylinder fuel reformation. The fuel reformation takes place in the dedicated cylinder, which is also responsible for producing the diluents for the engine (EGR). The D-EGR system does present its own set of challenges. Because only one out of four cylinders is providing all of the dilution and reformate for the engine, there are three “missing” EGR pulses and problems with EGR distribution to all 4 cylinders exist. In testing, distribution problems were realized which led to poor engine operation. To address these spatial and temporal mixing challenges, a distribution mixer was developed and tested which improved cylinder-to-cylinder and cycle-to-cycle variation of EGR rate through improved EGR distribution.

In this study, the criteria pollutant emissions from a light duty vehicle equipped with Dedicated EGR® technology were compared with emissions from an identical production GDI vehicle without externally cooled EGR. In addition to the comparison of criteria pollutant mass emissions, an analysis of the gaseous and particulate chemistry was conducted to understand how the change in combustion system affects the optimal aftertreatment control system. Hydrocarbon emissions from the vehicle were analyzed usin g a variety of methods to quantify over 200 compounds ranging in HC chain length from C1 to C12. The particulate emissions were also characterized to quantify particulate mass and number. Gaseous and particulate emissions were sampled and analyzed from both vehicles operating on the FTP-75, HWFET, US06, and WLTP drive cycles at the engine outlet location.

Proposed emissions standards will require that emissions control systems function at extremely high efficiency. Recently, studies have shown that elevated gasoline fuel sulfur levels (GFSL) can impair catalytic converter efficiency. In this study, a variety of tri-metal catalysts were evaluated to determine if formulation changes could reduce emissions sensitivity to GFSL. Catalysts with elemental composition similar to an OEM, but with double the precious metal (PM) loading, were evaluated using 38 and 620 ppm GFSL. Doubling the PM loading significantly reduced catalyst sensitivity to sulfur. Doubling the rhodium loading, at the expense of the platinum loading, significantly improved NOx emission sulfur sensitivity.

The addition of exhaust gas recirculation (EGR) has demonstrated the potential to significantly improve engine efficiency by allowing high CR operation due to a reduction in knock tendency, heat transfer, and pumping losses. In addition, EGR also reduces the engine-out emission of nitrogen oxides, particulates, and carbon monoxide while further improving efficiency at stoichiometric air/fuel ratios. However, improvements in efficiency through enhanced combustion phasing at high compression ratios can result in a significant increase in cylinder pressure. As cylinder pressure and temperature are both important parameters for estimating the durability requirements of the engine - in effect specifying the material and engineering required for the head and block - the impact of EGR on surface temperatures, when combined with the cylinder pressure data, will provide an important understanding of the design requirements for future cylinder heads.

Dedicated-EGR™ (D-EGR™) is a concept where the exhaust of one dedicated cylinder (D-Cyl) is routed into the intake thus producing EGR to be used by the whole engine. The D-Cyl operates rich of stochiometric which produces syngas that enhances the EGR stream permitting faster combustion and greater knock mitigation. Operating an engine using D-EGR improves the knock resistance which can permit a higher compression ratio (CR) thereby increasing efficiency. One challenge of traditional D-EGR is that the D-Cyl combustion becomes unstable operating with both rich and EGR dilute conditions. Therefore, the ‘Split Intake D-EGR’ concept seeks to resolve this problem by feeding fresh air to the D-Cyl, thus allowing even richer operation in the D-Cyl which further increases the H2 and CO yield thereby enhancing the efficiency benefits.

Dedicated exhaust gas recirculation (D-EGR®) concept developed by Southwest Research Institute (SwRI) has demonstrated a thermal efficiency increase on many spark-ignited engines at both low and high load conditions. The syngas (H2+CO) produced in the dedicated cylinder (D-cyl) by rich combustion helps to stabilize combustion at highly dilute conditions at low loads and mitigate knock at high loads. The dedicated cylinder with 25% EGR can typically run up to equivalence ratio of 1.4, beyond which the combustion becomes unstable. By injecting fresh air near the spark plug gap at globally rich conditions, a locally lean or near-stoichiometric mixture can be achieved, thus facilitating the ignitability of the mixture and increasing combustion stability. With more stable combustion a richer global mixture can be introduced into the D-cyl to generate higher concentrations of syngas. This in turn can further improve the engine thermal efficiency.