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Diesel oxidation catalysts (DOC) combined with NOx adsorbers and passive selective catalytic reduction (SCR) systems have demonstrated effectiveness in achieving high conversion efficiencies for CO, HC, and NOx emissions. This integrated exhaust after-treatment system has shown its efficiency in meeting the demanding BS6 Real Driving Emissions (RDE) standards. However, the assessment of emissions at the end of the system's life reveals a decrease in the conversion efficiency of aged exhaust systems, particularly affecting NOx, HC and CO emissions. Factors such as thermal aging and catalyst poisoning are identified as key contributors to the degradation of the after-treatment performance. This paper elucidates correlation methodologies applied to aged Lean NOx Trap (LNT) exhaust after-treatment systems. These methodologies aid in understanding the aging behavior of LNT samples and devising strategies to enhance the emissions performance aged samples during the end-of-life tests.