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Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.

Since ethanol is a renewable source of energy and it contributes to lower CO2 emissions, ethanol produced from biomass is expected to increase in use as an alternative fuel. It is recognized that for spark ignition (SI) engines ethanol has advantages of high octane number and high combustion speed and has a disadvantage of difficult startability at low temperature. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency, and emissions. The combustion characteristics under cold engine conditions are also examined. Ethanol has high anti-knock quality due to its high octane number, and high latent heat of evaporation, which decreases the compressed gas temperature during the compression stroke. In addition to the effect of latent heat of evaporation, the difference of combustion products compared with gasoline further decreases combustion temperature, thereby reducing cooling heat loss.

Recently, the demands of vehicle owners have become more diversified. This is particularly true in the paint appearance of the vehicle. Responding to these demands Toyota has developed an ink jet painting system, Toyota Fantasy Print System. This system can illustrate practically any picture which the customer desires. The system utilized a subtractive method of paint mixture which mixes or piles up these four permeable inks. The development of durable ink as well as equipment which can efficiently and effectively apply the ink onto the required contoured surface.

In order to achieve the Toyota Environmental Challenge of 2050 (zero CO2 emissions), we have developed an innovative coating system that achieves more than 95% transfer efficiency. In order to reduce paint loss in the painting process, it is necessary to eliminate overdust and bounce dust. The most important point is how to spray (atomization, particle flight, adhesion) without shaping air. We have developed a “super high transfer efficiency system” that eliminates the need for shaping air. We continue to challenge the development of innovative technologies to view the paint shop as clean and eco-friendly environment.

In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.

The reduction of the heat loss from the in-cylinder gas to the combustion chamber wall is one of the key technologies for improving the thermal efficiency of internal combustion engines. This paper describes an experimental verification of the “temperature swing” insulation concept, whereby the surface temperature of the combustion chamber wall follows that of the transient gas. First, we focus on the development of “temperature swing” insulation materials and structures with the thermo-physical properties of low thermal conductivity and low volumetric heat capacity. Heat flux measurements for the developed insulation coating show that a new insulation material formed from silica-reinforced porous anodized aluminum (SiRPA) offers both heat-rejecting properties and reliability in an internal combustion engine. Furthermore, a laser-induced phosphorescence technique was used to verify the temporal changes in the surface temperature of the developed insulation coating.

Underbody coating is used to prevent chipping damage of the automobile underbody and wheel well. Multi-functional material that gives sound insulating properties is called sound insulating underbody coating. This paper describes the development of underbody coating material with powdered acrylic composition as an alternative to polyvinyl chloride resin. The new material also has better foaming properties. It is possible to ensure excellent sound insulating performance with thin film. This multi-functional underbody coating is the first application in the world with weight reduction and cost saving, and in a more environmentally acceptable manner.

This paper presents the effect of the oil circulation ratio on the system performance of a CO2 climate control system and the effect of an oil separator on the oil circulation behavior using a new oil circulation ratio measurement method. In this study, the oil circulation ratio of a CO2/PAG mixture at various system conditions was measured. When the oil circulation ratio increases from 0.5 wt.% to 7 wt.%, the coefficient of performance decreases by 8% and 11% for idling and driving conditions, respectively. Without the oil separator, the oil circulation ratio increases more than 10 wt.%; with the oil separator, it was maintained at below detection level and 1.1 wt.% for idling and driving conditions, respectively.

This paper presents the oil circulation behavior in a CO2 climate control system operating at low evaporating temperature down to -32°C. The increase of oil circulation ratio (OCR) from 0 to 6 wt.% during steady state conditions degrades the coefficient of performance and cooling capacity by 15% and 8%, respectively. The pressure drop across the heat exchangers increases, especially in the gas cooler. In low temperature CO2 systems some fluctuations of oil and refrigerant flow rates were observed during cyclic operations when the system did not equip the oil separator, but was observed only at high oil charge when the system did equip the oil separator. These instabilities lead to a periodic compressor performance fluctuation, which caused system performance degradations. Therefore, the use of an oil separator is recommended for the low temperature operation if an ordinary metering valve is adopted as an expansion device without any special control strategy.

Toyota has been introducing several hybrid vehicles (HV) since 1997 as a countermeasure to the concerns raised by automobile, like CO2 reduction, energy security, and pollutant emission reduction in urban areas. Plug in hybrid Vehicle (PHV) uses electric energy from grid rather than fuel for most short trips and therefore presents a next step forward towards an even more effective solution for these concerns. For longer trips, the PHV works as a conventional hybrid vehicle, providing all the benefits of Toyota full hybrid technology, such as low fuel consumption, user-friendliness and long cruising range. This paper describes a newly developed plug-in hybrid system and its vehicle performance. This system uses a Li-ion battery with high energy density and has an EV-range within usual trip length without sacrificing cabin space.

From the viewpoint of measures for environmental issues, the amount of solvents in paint for aluminum wheels needs to be minimized. Environmentally friendly powder coatings have been used widely for primer coating and clear coating, but there is no precedent for its use for base coating. This time, we optimized the condition of surface treatment of pigment and hardening behavior of constituent resin in the melting process and succeeded in developing a metallic powder coating for aluminum wheels that fulfills the appearance and the quality requirements of aluminum wheels.

Through a polymer design and precise morphology control, The Super Olefin Polymer, TSOP-1 and TSOP-5 were developed for the material consolidation of interior and exterior parts, respectively. Due to a good balance of TSOP performance, several conventional materials were consolidated into one material for each application. Accordingly, considerable amounts of weight reduction and cost savings have been obtained. In addition to the excellent recyclability of TSOP, the coated bumpers collected from the market were re-utilized through paint decomposition technology. The first dashboard construction, molded partially with foam-padded skin, was also realized. The current amount of TSOP used in a vehicle is about 30% of the total amount of plastic materials. Through the usage of TSOP, 70% of the material consolidation has been achieved.

JCAPII gasoline workgroup reported vehicle emission study to comprehend the impact of ETBE blending. In previous study, we focused on the compatibility of ETBE blended gasoline with Japanese current gasoline vehicles in-use. Based on recent discussion with ETBE 8% blended gasoline into the market, more information becomes necessary. In this second report, we studied to comprehend the actual emission impact using realistic model fuels using several base stocks. Fuel properties of T50, T90 and aromatic compound content were selected through discussions. Specifications were changed within the range of the market. Both ETBE 0% and 8% were combined for these fuel matrixes. In total, eight fuels and two reference fuels were tested. Two J-ULEV vehicles (one MPI, and a stoichiometric-SIDI) were procured as representatives. We discussed quantitative and qualitative impact toward emissions. Data regarding CO2 and fuel economy change were also reported.

Stringent emission regulations call for advanced catalyst substrates with thinner walls and higher cell density. However, substrates with higher cell density increase backpressure, thinner cell wall substrates have lower mechanical characteristics. Therefore we will focus on cell configurations that will show a positive effect on backpressure and emission performance. We found that hexagonal cells have a greater effect on emission and backpressure performance versus square or round cell configurations. This paper will describe in detail the advantage of hexagonal cell configuration versus round or square configurations with respect to the following features: 1 High Oxygen Storage Capacity (OSC) performance due to uniformity of the catalyst coating layer 2 Low backpressure due to the large hydraulic diameter of the catalyst cell 3 Quick light off characteristics due to efficient heat transfer and low thermal mass

Internal combustion engines will play an important role in the coming decades, even considering targets of carbon neutrality for a sustainable future. This will be especially true in regions where pure electrified vehicle implementation is not yet practical, or for long-range heavy load transportation purposes, even in regions where BEV infrastructure is well established. HEV/PHEV’s importance and contribution to CO2 emission reduction together with carbon neutral fuels such as hydrogen, e-fuel and biomass fuel etc. will remain crucial regardless of region/transport sectors. In this respect, brake thermal efficiency improvements by friction reduction needs further investigation. This is especially so with the crankshaft bearings’ lubrication system, which can provide as much as 40% of the total mechanical losses in some cases. It is a well-established fact, that plain bearings require a minimum oil flow volume to maintain their real function rather than oil pressure.

Solar and other green energy technologies are attracting attention as a means of helping to address global warming caused by CO2 and other emission gases. Countries, factories, and individual homes around the world have already introduced photovoltaic energy power sources, a trend that is likely to increase in the future. Electric vehicles powered from photovoltaic energy systems can help decrease the CO2 emmissions caused by vehicles. Unlike vehicles used for solar car racing, it is not easy to equip conventional vehicles with solar modules because the available area for module installation is very small to maintain cabin space, and the body lines of conventional vehicles are also usually slightly rounded. These factors decrease the performance of photovoltaic energy systems and prevent sufficient electric power generation. This research aimed to estimate the effectiveness of a solar module power generating system equipped on a conventional car, the Toyota Prius PHV.

To meet increasing driveability expectation and government stringent fuel economy regulations reducing CO2 emissions of passenger cars; Toyota developed a new 8-speed automatic transmission "Direct Shift-8AT". Direct Shift-8AT is the first stepped automatic transmission model based on “TNGA” philosophy. New models which received Direct Shift-8AT are the new Camry, Highlander and Sienna. Direct Shift-8AT has an innovative control method with gear train and torque converter models, providing enhanced driveability and fuel economy performance through high efficiency transmission technology. This paper describes details of the new technology and vehicle performance.

It is necessary for us to reduce CO2 emissions in order to hold down global warming which is advancing year by year. Toyota Motor Corporation believes that not only the introduction of BEVs but also the sale of the hybrid vehicles must spread in order to achieve the necessary CO2 reduction. Therefore, we planned to improve the attractiveness of future hybrid vehicles. Prius has always made full use of hybrid technologies and leading to significant CO2 reduction. Toyota Motor Corporation has developed a 2.0L hybrid system for the new Prius. We built the system which could achieve a comfortable drive along following the customer’s intention while improving the fuel economy more than a conventional system. The engine improves on both output and thermal efficiency. The transaxle decreases mechanical loss by downsizing the differential, and adoption of low viscosity oil.

To solve various environmental problems, fuel-efficient vehicles that reduce CO2 emissions as well as exhaust gas emissions have been developed. In such vehicles, a regenerative brake is used to further reduce fuel consumption. Because the market size for such vehicles is expanding, a brake system is required that can be used in a wide range of vehicles extending from internal combustion engine vehicles (ICEVs) to electric vehicles (EVs). In addition, issues such as deceleration fluctuation and brake pedal fluctuation arise because the regenerative brake force is dependent on the vehicle speed. This paper presents a brake system configuration and its element technologies that can replace existing brake systems in different vehicles ranging from ICEVs to EVs. The proposed system can realize a regenerative cooperative brake not only by replacing the brake booster unit but also without replacing the modulator.

Silver metallic colors with thin and smooth aluminum flake pigments have been introduced for luxury brand OEMs. Regarding the paint formulation for these types of colors, low non-volatile(NV) and high aluminum flake pigment contents are known as technology for high metallic appearance designs. However, there are two technical concerns. First is mottling which is caused by uneven distribution of the aluminum flake pigments in paint film and second is poor film property due to high aluminum pigment concentration in paint film. Therefore, current paint systems have limitation of paint design. As a countermeasure for those two concerns, we had investigated cellulose nanofiber (CNF) dispersion liquid as both the coating binder and rheology control agent in a new type of waterborne paint system. CNF is an effective rheology control agent because it has strong hydrogen bonds with other fiber surfaces in waterborne paint.