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From the viewpoint of primary energy diversification and CO2 reduction, interests of using Biomass Fuel are rising. Some kinds of FAME (Fatty Acid Methyl Ester), which are obtained from oil fats like vegetable oil using transesterification reaction with methanol, are getting Palm Oilpular for bio-diesel recently. In this study, we have conducted many experiments of palm oil hydrogenations using our pilot plants, and checked the reactivity and the pattern of product yields. As a result, we figured out that the hydrocarbon oil equivalent to the conventional diesel fuel can be obtained from vegetable oils in good yield under mild hydrogenation conditions. Moreover, as a result of various evaluations for the hydrogenated palm oil (oxidation stability, lowtemperature flow property, LCA, etc.), we found that the hydrogenated palm oil by our technology has performances almost equivalent to conventional diesel fuel.

Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.

Recently, global warming and energy security have received significant attention. Thus an improvement of the vehicle fuel economy is strongly required. For engines, one effective way is to improve the engine thermal efficiency. Raising compression ratio [1] or turbo charging technologies have potential to achieve high thermal efficiency. However knock does not allow the high thermal efficiency. Knock depends on the fuel composition and the pressure and temperature history of unburnt end-gas [2-3]. For fuels, RON is well known for describing the anti knock quality. High RON fuels have high anti knock quality and result in higher thermal efficiency. This paper investigates the impact of high RON fuels on the thermal efficiency by using high compression ratio engine, turbo charged engine, and lean boosted engine [4]. Finally, it is shown that the high thermal efficiency can be approached with high RON gasoline and ethanol.

In an effort to reduce CO2 emissions, governments are increasingly mandating the use of various levels of biofuels. While this is strongly supported in principle within the energy and transportation industries, the impact of these mandates on the transport stock’s CO2 emissions and overall operating efficiency has yet to be fully explored. This paper provides information on studies to assess biodiesel influences and effects on engine performance, driveability, emissions and fuel consumption on state-of-the-art Euro IV compliant Toyota Avensis D4-D vehicles with DPNR aftertreatment systems. Two fuel matrices (Phases 1 & 2) were designed to look at the impact of fuel composition on vehicle operation using a wide range of critical parameters such as cetane number, density, distillation and biofuel (FAME) level and type, which can be found within the current global range of Diesel fuel qualities.

It has been reported that engine oils containing magnesium detergents gel under special conditions. The authors have previously reported on the mechanism by which magnesium detergents form needle crystals, which is the main cause of the gelation[1]. For this article, the authors conducted tests in actual vehicles using several types of engine oils containing magnesium detergents, including oils for which gelation problems have been reported in the market. The gelation was reproduced, and the test oils were ranked by their propensity to gel. In addition, a laboratory test method was used in which water and CO2 were mixed into engine oil under controlled conditions, then left stored in a bottle for twenty days, after which the kinematic viscosity and the quantity of insolubles of the mixture were measured. The study demonstrated the correlation between the laboratory test method and the actual vehicle tests.

Since ethanol is a renewable source of energy and it contributes to lower CO2 emissions, ethanol produced from biomass is expected to increase in use as an alternative fuel. It is recognized that for spark ignition (SI) engines ethanol has advantages of high octane number and high combustion speed and has a disadvantage of difficult startability at low temperature. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency, and emissions. The combustion characteristics under cold engine conditions are also examined. Ethanol has high anti-knock quality due to its high octane number, and high latent heat of evaporation, which decreases the compressed gas temperature during the compression stroke. In addition to the effect of latent heat of evaporation, the difference of combustion products compared with gasoline further decreases combustion temperature, thereby reducing cooling heat loss.

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).

Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.

In order to determine the main factors causing the mileage-related increase in formaldehyde emission from methanol-fueled vehicles, mileage was accumulated on three types of vehicle, each of which had a different air-fuel calibration system. From exhaust emission data obtained during and after the mileage accumulation, it was found that lean burn operation resulted in by far the highest formaldehyde emission increase. An investigation into the reason for the rise in engine-out formaldehyde emission revealed that deposits in the combustion chamber emanating from the lubricating oil promotes formaldehyde formation. Furthermore it was learnt that an increase in engine-out NOx emissions promotes partial oxidation of unburned methanol in the catalyst, leading to a significant increase in catalyst-out formaldehyde emission.

Current and future engine technologies and fuels are mutually dependent. The increased use of alternative fuels has been linked to deterioration in performance of injectors, fuel filters and engines as a result of insoluble deposit formation. The present work aimed to study the impact of Diesel/biodiesel blends formulation (biodiesel feedstock and content) and temperature on the oxidation stability based on total acid number (TAN). The biofuels used in the fuel matrix were: rapeseed, soy and palm methyl esters (RME, SME and PME respectively). The Diesel/biodiesel blends were made with 0%v/v, 5%v/v, 10% v/v and 20%v/v of biodiesel blended with additive-free new Diesel. The oxidation stability of Diesel/biodiesel blends was to evaluate during 6 months fuels storage, under 20°C and 40°C, and fuels severe oxidation into a reactor vessel to better understand the parameters leading to fuel oxidation on-board.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

This paper introduces vehicle test method, data processing and result parameters of an objective evaluation method to quantify on-center handling at freeway driving. Vehicle test is conducted on a flat straight road with a low frequency sinusoidal steering angle input. The result consists of eleven parameters that describe relations of two quantities such as gain, non-linearity and lag time.

Galvannealed steel sheet (GA) is very extensively used for vehicle panels. However ζ-phase (FeZn13) in GA coat causes poor stamping formability. Previously, there were no easy methods to evaluate the influence of ζ-phase on the frictional characteristics other than the X-ray diffraction method. This study will discuss the development of a new testing method: Dr. STAMP Method that is both efficient and convenient with pin-on-disc tester.

Clarifying the impact of ETBE 8% blended fuel on current Japanese gasoline vehicles, under the Japan Clean Air Program II (JCAPII) we conducted exhaust emission tests, evaporative emission tests, durability tests on the exhaust after-treatment system, cold starting tests, and material immersion tests. ETBE 17% blended fuel was also investigated as a reference. The regulated exhaust emissions (CO, HC, and NOx) didn't increase with any increase of ETBE content in the fuel. In durability tests, no noticeable increase of exhaust emission after 40,000km was observed. In evaporative emissions tests, HSL (Hot Soak Loss) and DBL (Diurnal Breathing Loss) didn't increase. In cold starting tests, duration of cranking using ETBE 8% fuel was similar to that of ETBE 0%. In the material immersion tests, no influence of ETBE on these material properties was observed.

In this report, adhesion mechanism between epoxy resin and primer and between primer and Ni platting in Hybrid vehicle (HV) was investigated. Adhesion forces are thought to be a combination of mechanical bond forces (such as anchor effect), chemical bond forces and physical bond forces (such as hydrogen bonding and Van der Waals force). Currently there is insufficient understanding of the adhesion mechanism. In particular, the extent to which the three bond forces contribute to adhesion strength. So the adhesion mechanism of polyimide primers was analyzed using a number of different methods, including transmission electron microscope (TEM) and atomic force microscope (AFM) observation, to determine the contributions of the three bonding forces. Molecular simulation was also used to investigate the relationship between adhesion strength and the molecular structure of the primer.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

The ignition delay and combustion characteristics of hydrogen jets in an argon-oxygen atmosphere were investigated to provide fundamental data for operating an argon-circulated hydrogen internal combustion engine. Experiments were conducted in a constant-volume combustion vessel to study the effects of ambient temperature, ambient pressure, oxygen concentration and injection pressure on a pre-burning system. The hydrogen-jet penetration and flame were also investigated based on high-speed shadowgraph images. The experimental results indicated that the ignition delay (τ) increases as the ambient temperature (Ti) decreases, similar to the results obtained in an air atmosphere. The heat-release rate results also exhibited similar trends.

Hydrogen can be produced from various renewable energy sources, therefore it is predicted that hydrogen could play a greater role in meeting society's energy needs in the mid- to long-term. Conventional hydrogen engines have some disadvantages: higher cooling loss results in low thermal efficiency and abnormal combustion (backfire, pre-ignition, higher burning velocity) limits high load operation. Direct injection is an effective solution to overcome these disadvantages, but combustion methods that enable both high efficiency and low NOx have yet to be studied in enough detail. In this research, high-efficiency and low-NOx hydrogen combustion was investigated using a prototype high-pressure hydrogen injector (maximum 30 MPa). Experiments were carried out with a 2.2-liter 4-cylinder diesel engine equipped with a centrally mounted hydrogen injector, a toroidal shape combustion chamber, and a spark plug in the glow plug position.

From the energy security and CO2 discharge reduction point of view, much attention has been paid to the usage of biofuel, ethanol, as an alternative source of energy in the transportation industry. Yet, the major drawback in applying highly concentrated ethanol in the spark ignited internal combustion engines is cold start instability. This is due to the characteristics of ethanol, large latent heat required to vaporize. This paper investigates necessary conditions for the engine cold start, using highly concentrated ethanol. Tests performed with varieties of ethanol fuel, a relationship between cold startability lower temperature limit and reid vapor pressure was observed. A method to boost the vaporization, intake valve timing control is introduced to obtain high compression peak temperature.

When adapted for use in automotive engines, CNG and LPG are considered environmentally friendly compared to gasoline or diesel fuel. However, when these gaseous fuels are used, wear of the valve seat insert and valve face increases if materials meant for use with gasoline are adopted. In comparison to a gasoline engine, the oxide membrane that is formed on the sliding surfaces of the valve face and valve seat insert is limited. As a consequence, adhesion occurs and increased wear of these components is the result. Based on analysis materials that are more compatible with these gaseous fuels were developed.