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The wear mechanisms of the methanol engine were studied using dynamometer tests. Formic acid from methanol combustion mixes with the lubricant oil and attacks the metal surfaces. The iso tacho prorissis method was successfully applied to analyze the formic acid content of the used oil. A large amount of condensed water is also formed by methanol combustion and accelerates the wear. Wear can be effectively reduced by shortening lubricant oil change intervals, by using a special oil and by durable surface treatment of engine parts.

Diamond-like carbon (DLC) coating has excellent properties like high hardness and low friction. So it has attracted considerable attention in recent years as a low-friction coating material. However, some DLC coatings display increased wear in oil containing Mo-DTC (Molybdenum-dithiocarbamates). Wear analyses of sliding surface after block-on-ring tests were conducted suggest that the decomposition product from Mo-DTC, MoO3, reacts with active sites in the DLC to promote the wear of DLC.

In order to develop the valve rocker arm material for the new type engine, we investigated various materials whose chemical compositions were selected using 30% chromium cast iron, which had shown good results in screening evaluation tests, as the basis. High chromium cast irons are well known for their abrasive wear resistance, but it has been very difficult to apply them for use as rocker arm material because their machinability is very poor, and because it is difficult for them to have a regular microstructure. In this paper, both the manufacturing method for the rocker arm which decreases the disadvantages that high chromium cast iron have and the rocker arm material best suited for this method are described.

One of the main causes of the inadequate transient response of a 4-valve engine was established as being partition wall-wetting. The possibility of resolving this problem by improving fuel atomization was investigated. An air-mix type injector, although producing finer droplets with more uniform distribution, was not found effective in improving transient response. The development of a two-hole injector is described. This new injector produces twin sprays which are directed into the siamese intake ports without wetting the partition wall. As a consequence, the lean A/F ratio excursion is reduced, torque stumble is eliminated and the conversion efficiency of a three-way catalyst is increased.

This paper describes an analysis of the rise in timing belt temperature occuring under high engine speed operation that was made to establish the cause of heat deterioration of the belt materials. Surface temperatures of the belt were accurately measured by correcting thermo-vision detected radiations to eliminate environmental radiation. The temperature profile of a belt cross-section was obtained by a specially developed thermo-couple device. The experimental results indicated that heat generated by the belt contributes significantly to the temperature rise and that the primary cause of the heat generation is bending hysteresis of the belt cords. In addition, a description is made of a method of calculating the rate of heat generation in the belt. In this simulation method, the energy dissipated as heat is calculated from the bending strains and loss moduli of the belt materials. Calculated results were found to agree well with experimental results.

For viscous couplings(VCs) as a driving force transmission system of vehicles, requirement of torque characteristics has been getting very stringent. Because the torque characteristics significantly affect four wheel drive vehicles' abilities such as traction performance and driving stability. Furthermore, the recent concerns on high fuel economy, low pollution and low cost require that design of VCs should be increasingly compact, light weighted and excellent in transmitted torque's stability. It is an easy way to increase viscosity of viscous coupling fluids(VCFs) for the compact design of the VC. But it might cause increase in heat load and wear of plates which resulted in degradation of the VCF. The degradation affects VCF's viscosity and impairs stability in torque transmission. Therefore it is indispensable to develop high viscosity VCF which is excellent in long-term viscosity's stability.

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.

The change of the fuel flow rate in an injector with mileage accumulation causes poor drivability and exhaust emission deterioration in Otto-type methanol fueled vehicles with a multi-point fuel injection system. This is one of the serious problems which needs to be solved for the practical use of methanol fueled vehicles. The investigation results reveal that the wear of contact surfaces between a valve needle and a valve body increases the resistance force for valve needle movement and causes the change of dynamic fuel flow rate in the injector. The effects of several countermeasures to solve this problem are evaluated.

Recently, the California Air Resources Board (CARB) has proposed a new set of evaporative emissions and “Useful Life” standards, called LEVII EVAP regulations, which are more stringent than those of the enhanced EVAP emissions regulations. If the new regulations are enforced, it will become increasingly important for the carbon canister to reduce Diurnal Breathing Loss (DBL) and to prevent deterioration of the canister. Therefore, careful studies have been made on the techniques to meet these regulations by clarifying the working capacity deterioration mechanism and the phenomenon of DBL in a carbon canister. It has been found that the deterioration of working capacity would occur if high boiling hydrocarbons, which are difficult to purge, fill up the micropores of the activated carbon, and Useful Life could be estimated more accurately according to the saturated adsorption mass of the activated carbon and the canister purge volume.

The deterioration of the friction reducing properties of engine oils containing molybdenum dithiocarbamates (MoDTCs) in service was studied. A quantitative analysis of MoDTCs and zinc dithiophosphates (ZDTPs) remaining in aged oils revealed that ZDTPs were consumed faster than MoDTCs. The consumption rate of ZDTPs was slow in the presence of MoDTCs and peroxide-decomposing antioxidants. The frictional properties of aged oils were evaluated with a reciprocating friction tester (SRV tester). The friction coefficient measured with the SRV tester was correlated to the properties of the aged oils, such as the TAN increase, TBN, and concentration of remaining ZDTPs.

The use of brakes on public roads depends on traffic conditions and the road itself. In order to research into brake usage on various roads and under various conditions, a micro-computer data logging system was developed. The recorded data were analyzed by a large computer and the severity of brake usages was defined. The relationship between the severity and the brake disc rotor temperature was derived, and used to predict brake pad wear/life. The predicted wear coincided fairly clossly with measured wear.

The knock-suppression effectiveness of exhaust-gas recirculation (EGR) can vary between implementations that take EGR gases after the three-way catalyst and those that use pre-catalyst EGR gases. A main difference between pre-and post-catalyst EGR gases is the level of trace species like NO, UHC, CO and H2. To quantify the role of NO, this experiment-based study employs NO-seeding in the intake tract for select combinations of fuel types and compression ratios, using simulated post-catalyst EGR gases as the diluent. The four investigated gasoline fuels share a common RON of 98, but vary in octane sensitivity and composition. To enable probing effects of near-zero NO levels, a skip-firing operating strategy is developed whereby the residual gases, which contain trace species like NO, are purged from the combustion chamber. Overall, the effects of NO-seeding on knock are consistent with the differences in knock limits for preand post-catalyst EGR gases.

Two types of new conceptual lead free overlays are developed for automotive internal combustion(IC) engine bearings. The overlays are consisted of molybdenum disulfide(MoS2) and polyamideimide(PAI) resin for binding. One of the overlays is suitable for diesel engines with higher unit load and the other overlay is suitable for gasoline engines with higher sliding velocity. Both overlays indicate good corrosion resistance and wear resistance comparing with conventional lead base overlay. Moreover, higher fatigue resistance is obtained in combination with high performance lead free bearing alloy. These new bearings have the potential to become alternative materials to conventional copper lead bearings with lead base overlay.

This paper describes lubricant technology to enhance the durability of the low friction performance of gasoline engine oils which were formulated with molybdenum dithiodicarbamates (MoDTCs) as friction modifiers. This paper also describes an evaluation method which consists of three tests: (1) Our in-house rig test to simulate oil deterioration in an engine stand; (2) Quantitative analysis of MoDTC and ZnDTP in oils and; (3) A friction test (SRV). It was found that the low friction performance of fuel economy engine oils deteriorated primarily due to the consumption of MoDTC and ZnDTP. Calcium salicylates had better durability of low friction performance than calcium sulfonates. Furthermore, sulfurized compounds enhanced the durability. Based on these findings, an experimental oil was formulated.

Torque loss reduction at differential gear unit is important to improve the fuel economy of automobiles. One effective way is to decrease the viscosity of lubricants as it results in less churning loss. However, this option creates a higher potential for thin oil films, which could damage the mechanical parts. At tapered roller bearings, in particular, wear at the large end face of rollers and its counterpart, known as bearing bottom wear is one of major failure modes. To understand the wear mechanism, wear at the rolling contact surface of rollers and its counterpart, known as bearing side wear, was also observed to confirm the wear impact on the tapered roller bearings. Because gear oils are also required to avoid seizure under extreme pressure, the combination of a phosphorus anti-wear agent and a sulfurous extreme pressure agent are formulated.

Fluoroelastmers are well known for their resistance to heat and fluids, and have become major material for crankcase oil seals. On the other hand, new additive formulations are developed for engine lubricants used for fuel economic gasoline engines. In this paper, the effects of those additives on properties of fluoroelastmers are investigated. The results of the immersion tests of both test plaques and oil seal products indicate that dithiocarbamates, friction modifier, have hardening effects on fluoroelastmers. The fluoroelastmer deterioration mechanism is determined by analysis of elastmer samples after immersion in oil.

The influence of engine oil viscosity on the wear of piston rings and cam faces has been investigated by fired engine tests using a radioisotope (RI) tracer technique. High-temperature and high-shear-rate (HTHS; 150°C, 1O6 s-1) viscosities of the experimental oils prepared are 2.2, 2.4, 2.6 and 3.1 mPa•s. At an oil temperature of 90°C the wear of piston rings and cam faces did not increase, even if the HTHS viscosity was lowered down to 2.2 mPa•s. However, both piston rings and cam faces exhibited an increase in wear below 2.4 mPa•s at 130°C. It was also recognized that valve train wear did not significantly increase with reducing viscosity in the motored engine tests at a temperature of 50°C. From these test results, it was suggested that the oil with the HTHS viscosity of 2.6 mPa•s sufficiently demonstrates the antiwear performance equivalent to that with around 3.0 mPa•s for application to piston rings and cam faces.

To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

The authors developed a high-reliability low-cost gold-plated connector for automobiles. The connector is covered with three plated layers, nickel, palladium-nickel alloy, and gold. The three-layer plating helps to reduce the required thickness of gold. This paper describes the reasons why palladium-nickel plating was adopted and compares the corrosion resistance, oxidation resistance and wear resistance of three-layer-plated materials with those of conventional gold-plated materials. In addition, the characterisitics of three-layer-plated connectors were compared with those of conventional gold-plated connectors. It was found that the reliability of three-layer-plated connectors was as high as that of conventional gold-plated connectors.