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Technical Paper

Vegetable Oil Hydrogenating Process for Automotive Fuel

2007-07-23
2007-01-2030
From the viewpoint of primary energy diversification and CO2 reduction, interests of using Biomass Fuel are rising. Some kinds of FAME (Fatty Acid Methyl Ester), which are obtained from oil fats like vegetable oil using transesterification reaction with methanol, are getting Palm Oilpular for bio-diesel recently. In this study, we have conducted many experiments of palm oil hydrogenations using our pilot plants, and checked the reactivity and the pattern of product yields. As a result, we figured out that the hydrocarbon oil equivalent to the conventional diesel fuel can be obtained from vegetable oils in good yield under mild hydrogenation conditions. Moreover, as a result of various evaluations for the hydrogenated palm oil (oxidation stability, lowtemperature flow property, LCA, etc.), we found that the hydrogenated palm oil by our technology has performances almost equivalent to conventional diesel fuel.
Technical Paper

Unregulated Emissions Evaluation of Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI), State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), and Fuel Qualities Effects (EtOH, ETBE, Aromatics and FAME)

2007-10-29
2007-01-4082
In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.
Technical Paper

Toyota Newly Developed 2VZ-FE Type Engine

1988-11-01
881775
Newly developed 2VZ-FE engine for CAMRY is a 2.5-liter water cooled and V-type 6-cylinder engine exported from TOYOTA for the first time. This engine has the TOYOTA original 4-valve DOHC system. That is, exhaust camshafts driven by intake camshafts using scissors gears. By its compact configuration with the gear driven camshafts, this V-type 6-cylinder engine is mounted on a front-wheel-drive vehicle which originally had an in-line 4-cylinder engine. By increasing IVZ-FE engine displacement (for domestic), compact pentroof-type combustion chambers, optimum air-fuel ratio and ignition timing by TCCS (TOYOTA Computer Controlled System) and other technologies, a high performance 153HP/5600rpm and a large torque 155ft·lbs/4400rpm have been achieved with a low fuel consumption.
Journal Article

The Impact of Diesel and Biodiesel Fuel Composition on a Euro V HSDI Engine with Advanced DPNR Emissions Control

2009-06-15
2009-01-1903
In an effort to reduce CO2 emissions, governments are increasingly mandating the use of various levels of biofuels. While this is strongly supported in principle within the energy and transportation industries, the impact of these mandates on the transport stock’s CO2 emissions and overall operating efficiency has yet to be fully explored. This paper provides information on studies to assess biodiesel influences and effects on engine performance, driveability, emissions and fuel consumption on state-of-the-art Euro IV compliant Toyota Avensis D4-D vehicles with DPNR aftertreatment systems. Two fuel matrices (Phases 1 & 2) were designed to look at the impact of fuel composition on vehicle operation using a wide range of critical parameters such as cetane number, density, distillation and biofuel (FAME) level and type, which can be found within the current global range of Diesel fuel qualities.
Technical Paper

Research of Knocking Deterioration due to Accumulated Carbon Deposits on Piston Surfaces

2019-04-02
2019-01-1141
The quantity of heavy components in fuel is increasing as automotive fuels diversify, and engine oil formulations are becoming more complex. These trends result in the formation of larger amounts of carbon deposits as reaction byproducts during combustion, potentially worsening the susceptibility of the engine to knock [1]. The research described in this paper aimed to identify the mechanism that causes knocking to deteriorate due to carbon deposits in low to medium engine load ranges, which are mainly used when the vehicle drives off and accelerates. With this objective, the cylinder temperature and pressure with and without deposits were measured, and it was found that knocking deteriorates in a certain range of ignition timing.
Technical Paper

Multipoint Spark Ignition for Lean Combustion

1985-10-01
852092
Effects of multipoint spark ignition on combustion duration, fuel consumption and lean misfire limit are discussed in this paper. A plate, which consists of 12 spark gaps in each cylinder, and a new CD ignition system have been developed for accomplishing the multipoint spark ignition. This plate was installed between cylinder block and head in a 4 cylinder engine. Compared with a single gap, the results of 12 gaps showed a reduced combustion duration by about 50%, a 5% decrease in fuel consumption and an extended lean misfire limit by about 3 air-fuel ratio numbers. Furthermore, the multipoint spark ignition on both sides of the combustion chamber was more effective than only on one side. With this system, HC emission can be reduced as well. The results of this study showed that, compared to those obtained with swirl, this multipoint spark ignition was more effective on improving fuel consumption.
Technical Paper

Improvements in Low Temperature Diesel Combustion with Blending ETBE to Diesel Fuel

2007-07-23
2007-01-1866
The effects of blending ETBE to diesel fuel on the characteristics of low temperature diesel combustion and exhaust emissions were investigated in a naturally-aspirated DI diesel engine with large rates of cooled EGR. Low temperature smokeless diesel combustion in a wide EGR range was established with ETBE blended diesel fuel as mixture homogeneity is promoted with increased premixed duration due to decreases in ignitability as well as with improvement in fuel vaporization due to the lower boiling point of ETBE. Increasing the ETBE content in the fuel helps to suppress smoke emissions and maintain efficient smokeless operation when increasing EGR, however a too high ETBE content causes misfiring at larger rates of EGR. While the NOx emissions increase with increases in ETBE content at high intake oxygen concentrations, NOx almost completely disappears when reducing the intake oxygen content below 14 % with cooled EGR.
Technical Paper

Improvement of DI Diesel Engine System by Utilizing GTL Fuels Characteristics

2009-06-15
2009-01-1933
Gas To Liquid (GTL) fuels synthesized from natural gas are known as clean fuels. Therefore, GTL fuels have been expected to be a promising option that can reduce the NOx and PM emissions from diesel engines and contribute to the energy security. In this study, in order to clarify the emission reduction potentials, the improvement of DI diesel engine and aftertreatment systems were investigated by utilizing GTL fuels characteristics. To achieve a further reduction of both NOx and PM emissions, the combustion chamber, injection pattern and EGR calibration were modified. From the results of tests, the engine out NOx emissions were reduced to the Euro 6 regulation level and in parallel the expected deteriorations of HC emission and fuel consumption were suppressed because of the characteristics of high cetane number and zero poly-aromatics hydrocarbons. Additionally, an aftertreatment system was optimized to GTL fuel in order to improve NOx conversion efficiency.
Technical Paper

High Efficiency and Clean Diesel Combustion Concept using Double Premixed Combustion: D-SPIA

2012-04-16
2012-01-0906
A new concept, Diesel Staggered Premixed Ignition with Accelerated oxidation (D-SPIA) was developed for lower exhaust emissions and carbon dioxide (CO₂) and this is based on divided fuel injection before top dead center (TDC). D-SPIA is a result of investigating various diesel combustion methods. Although the D-SPIA is a type of Premixed Charge Compression Ignition (PCCI), it has a distinct feature of double premixed combustion by optimum injection quantities and staggered timing, which can achieve an ideal heat release rate for low pollutant emissions and fuel consumption. Based on this concept, second injection timing and the proportion of the second fuel injection quantity play significant roles to reduce smoke, and hydrocarbon (HC) and carbon monoxide (CO) emissions. The second injection timing has a close relation to the premixed time of the second fuel injection and smoke level.
Technical Paper

Hardfaced Valve and P/M Valve Seat System for CNG and LPG Fuel Engines

2005-04-11
2005-01-0718
When adapted for use in automotive engines, CNG and LPG are considered environmentally friendly compared to gasoline or diesel fuel. However, when these gaseous fuels are used, wear of the valve seat insert and valve face increases if materials meant for use with gasoline are adopted. In comparison to a gasoline engine, the oxide membrane that is formed on the sliding surfaces of the valve face and valve seat insert is limited. As a consequence, adhesion occurs and increased wear of these components is the result. Based on analysis materials that are more compatible with these gaseous fuels were developed.
Technical Paper

GTL Fuel Impact on DI Diesel Emissions

2007-07-23
2007-01-2004
Reduction of exhaust emissions was investigated in a modern diesel engine equipped with advanced diesel after treatment system using a Gas-to-Liquid (GTL) fuel, a cleaner burning alternative diesel fuel. This fuel has near zero sulfur and aromatics and high cetane number. Some specially prepared GTL fuel samples were used to study the effects of GTL fuel distillation characteristics on exhaust emissions before engine modification. Test results indicated that distillation range of GTL fuels has a significant impact on engine out PM. High cetane number also improved HC and CO emissions, while these fuel properties have little effect on NOx emissions. From these results, it was found that low distillation range and high cetane number GTL fuel can provide a favorable potential in NOx/PM emissions trade-off. In order to improve the tail-pipe emissions in the latest diesel engine system, the engine modifications were carried out for the most favorable GTL fuel sample.
Technical Paper

Feasibility Study of Exhaust Emissions in a Natural Gas Diesel Dual Fuel (DDF) Engine

2012-09-10
2012-01-1649
The Diesel Dual Fuel (DDF) vehicle is one of the technologies to convert diesel vehicles for natural gas usage. The purpose of this research was to study the possibility of a DDF vehicle to meet emission standards for diesel vehicles. This research was done for small passenger vehicles and commercial vehicles. The exhaust emissions compliance of such vehicles in a New European Driving Cycle (NEDC) mode which was composed of Urban Driving Cycles (UDC) and an Extra Urban Driving Cycle (EUDC) was evaluated. (see APPENDIXFigure A1) In this study, the passenger vehicle engine, compliant with the EURO4 standard, was converted to a DDF engine. Engine bench tests under steady state conditions showed similar result to previous papers. Total hydrocarbon (HC) emission was extremely high, compared to diesel engine. The NEDC mode emissions of the DDF vehicle were estimated based on these engine bench test results.
Technical Paper

Effects of RME30 on Exhaust Emissions and Combustion in a Diesel Engine

2008-10-06
2008-01-2499
Considering the popularity of biodiesel fuels for diesel vehicles, the impacts of rapeseed oil methyl ester (RME), which is the most utilized biodiesel fuel in Europe, on tailpipe emissions from a diesel passenger car was investigated. In this study, 30% RME blended diesel fuel (RME30) was used and the comparison of tailpipe emissions between RME30 and a reference diesel fuel was conducted using a test vehicle with the latest engine and aftertreatment system. The results of the investigation reveal that RME30 generates about the same amount of NOx in tailpipe emissions as diesel fuel, and less HC, CO, and PM. These phenomena occurred in spite of attaching catalysts to the test vehicle, and therefore suggesting that the NOx conversion efficiency of the catalysts for RME30 is equal to that for diesel fuel. The injection rate for RME30 was the same as that for diesel fuel.
Technical Paper

Effects of Next-Generation Bio Diesel Fuel on the Engine Performance

2015-09-01
2015-01-1928
Hydrotreated Vegetable Oil (HVO) and Sugar-to-Diesel as next-generation bio diesel fuels consist of normal and iso-paraffin, and those carbon number of paraffinic hydrocarbons and distillation characteristics are narrow distribution. These characteristics would cause to deteriorate the evaporation and mixture with air and fuel. Therefore, in this study, the effects of normal paraffin (Tridecane) and iso-paraffin (HVO) on emission characteristics and cold start performance in a diesel engine were investigated by engine dynamometer tests, cold start vehicle tests, and spray analyzer tests. From the results, it was found that normal and iso-paraffin are beneficial for HC, CO, Smoke emission reduction. In addition, isomerization is effective for the diesel engine to fulfill cold start performance, since normal paraffin of narrow carbon number distribution became solidified under low temperature and high pressure condition in a common rail system.
Technical Paper

Effects of High Turbulence Flow on Knock Characteristics

2004-03-08
2004-01-0977
In enhancing the performance of automotive internal combustion engines, increasing the compression ratio offers an effective means of improving engine thermal efficiency. If the compression ratio is increased, however, the problem of knock occurs in exchange for improvement in engine thermal efficiency. In other words, an increase in compression ratio causes in-cylinder compressive end gas temperature to rise, resulting in the occurrence of knock. This in turn requires ignition timing retard to combat the knock. This trade-off makes it difficult to achieve the theoretical maximum combustion efficiency. In this paper, we clarify the feasibility of suppressing the occurrence of knock by increasing the burn rate. Specifically, we increase the burn rate by injecting high-pressure air directly into the combustion chamber, causing highly turbulent in-cylinder flow.
Technical Paper

Effects of GTL Fuel Properties on DI Diesel Combustion

2005-10-24
2005-01-3763
Reduction of vehicle exhaust emissions is an important contributor to improved air quality. At the same time demand is growing for new transportation fuels that can enhance security and diversity of energy supply. Gas to Liquids (GTL) Fuel has generated much interest from governments and automotive manufacturers. It is a liquid fuel derived from natural gas, and its properties - sulphur free, low polyaromatics and high cetane number - make it desirable for future clean light-duty diesel engines. In this paper, the effects of distillation characteristics and cetane number of experimental GTL test fuels on direct injection (DI) diesel combustion and exhaust emissions were investigated, together with their spray behaviour and mixing characteristics. The test results show that the lower distillation test fuels produce the largest reductions in smoke and PM emissions even at high cetane numbers. This is linked to the enhanced air/fuel mixing of the lighter fuel in a shorter time.
Technical Paper

Effects of Fuel Properties on Premixed Charge Compression Ignition Combustion in a Direct Injection Diesel Engine

2003-05-19
2003-01-1815
Effects of fuel distillation characteristics and cetane number on premixed charge compression ignition (PCCI) combustion were investigated for the purpose of reducing NOx and PM emissions from a direct injection diesel engine. The test engine had a hole type injection nozzle for conventional diesel combustion at high load operation. A low compression ratio and cooled EGR were applied to the test engine in order to reduce the compression temperature for avoiding pre-ignition. The investigation results show that, in the case of ignition control by EGR, a light fuel with lower distillation characteristics had an advantage of reducing smoke at higher loads. This means that high volatility fuel is effective in promoting lean mixture formation of fuel and air during the ignition delay. Moreover, lowering the cetane number was effective in reducing NOx emissions by suppression of combustion temperature.
Technical Paper

Effects of Cetane Number and Distillation Characteristics of Paraffinic Diesel Fuels on PM Emission from a DI Diesel Engine

2004-10-25
2004-01-2960
Fischer-Tropsch Diesel (FTD) fuel is expected to be a promising clean diesel fuel in the future because of its characteristics of zero sulfur, zero aromatics and a high cetane number. However, the optimum fuel properties for diesel engines have not been realized. In this study, the effects of cetane number and distillation characteristics on engine-out PM emissions from a conventional direct injection diesel engine were investigated by using paraffinic fuels which were made to simulate FTD fuel. From the results of the vehicle exhaust emissions test and engine dynamometer test, it was found that the narrow distillation characteristics (which eliminates heavy hydrocarbon fraction) could reduce the soluble organic fraction (SOF) in PM emissions, and the excess high cetane number characteristic promoted the formation of insoluble organic fraction (ISOF).
Technical Paper

Effects of Bio-Fuels on Vehicle Performance: Degradation Mechanism Analysis of Bio-Fuels

2004-10-25
2004-01-3031
In recent years, alternative sources of fuel are receiving a lot of attention in the automotive industry. Fuels derived from an agricultural feedstock are an attractive option. Bio-fuels based on vegetable oils offer the advantage being a sustainable, annually renewable source of automobile fuel. One of key issues in using vegetable oil based fuels is its oxidation stability. Since diesel fuels from fossil oil have good oxidation stability, automobile companies have not considered fuel degradation when developing diesel engines and vehicles as compared with gasoline engines. This paper presents the results of oxidation stability testing on bio-fuels. Oxidation stability was determined using three test methods, ASTM D525, EN14112 and ASTM D2274. The effects of storage condition, bio-fuel composition and antioxidants on the degradation of bio-fuels were all investigated. ASTM D525 is an effective test method to determine the effects of storage condition on bio-fuels stability.
Technical Paper

Effect of Sulfur-free and Aromatics-free Diesel Fuel on Vehicle Exhaust Emissions using Simultaneous PM and NOx Reduction System

2003-05-19
2003-01-1865
A new diesel after-treatment system, Diesel Particulate and NOx Reduction System (DPNR), is being developed for reducing PM and NOx emissions. We examined the effects of sulfur content in lubricants on exhaust NOx emission from DPNR catalyst, and examined the PM reduction ability using sulfur-free and aromatics-free fuel. After vehicle durability testing of 40,000 km without forced regeneration of PM and sulfur poisoning on DPNR catalyst, deterioration of DPNR was lower than using higher sulfur contents in fuel and oil. In addition to decreasing fuel sulfur, decreasing oil sulfur was also effective to maintain high NOx conversion efficiency. Although the catalyst was poisoned by sulfur in the lubricants, the influence of oil sulfur poisoning on the catalyst was lower than fuel sulfur poisoning. On the other hand, engine out PM emissions decreased by 70 % because of aromatics-free fuel. The pressure drop of DPNR did not increase during the 40,000 km vehicle durability test.
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