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In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

Quality control of gasoline constituents and its effect on the Intake Valve Deposits (IVD) has become a recent issue. In this paper, the effects of gasoline and oil quality on intake valve deposits were investigated using an Intake Valve Deposit Test Bench and a Sludge Simulator. The deposit formation from the gasoline maximized at an intake valve temperature of approximately 160 °C, and the deposits formed from the engine oil were maximum at approximately 250 °C. Therefore, the contribution of the gasoline or the engine oil appears to depend on the engine conditions. The gasoline which contains MTBE or ethanol with no detergent additive slightly increases the deposition amount. The gasoline with a superior detergent significantly decreases the deposition amount even when MTBE or ethanol is blended in the gasoline. Appropriate detergent fuel additive retards the oil deterioration.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

Engine dynamometer tests were conducted to evaluate the effect of detergent additives and gasoline components on Combustion Chamber Deposits (CCD). Additives with polyether amine (PEA) and with polyolefin amine (POA) chemicals were used. Three kinds of POA additives were used. Our results show that some kinds of additives and aromatics in gasoline increase CCD formation. Different polyolefin detergents show different tendency of CCD formation. The amount of CCD showed good relationship with the unwashed gum level of the gasoline. In general, smaller dosages produce less CCD. This means that detergents which have good IVD and PFID effectiveness at smaller dosage are better with regard to CCD. We analyzed the CCD by C13-NMR, GPC and IR method. The detergent contributes to CCD. Vehicle emissions tests were carried out to evaluate the effects of CCD on exhaust emissions.

This paper describes lubricant technology which helps to prevent intake valve deposit (IVD) formation for use with conventional gasolines without detergents, as well as the IVD evaluation method used in testing. The FED 3462 method was modified to establish a new panel coking test method, with excellent correlation with the engine stand IVD test, for the quantitative evaluation of IVD. Tests have shown that IVD increases when the volatility of base oils becomes higher due to condensation and polymerization of engine oil additives. Furthermore, viscosity index improvers, metallic detergents and ashless dispersants have considerable effect on IVD formation. Based on various experiments, the authors have established a formulation technology for engine oils to lower IVD, which they incorporated in two newly formulated SG oils with lower IVD than conventional 5W-30 SG oil.

Fifty percent distillation temperature (T50) can be used as a warm-up driveability indicator for a hydrocarbon-type gasoline. MTBE-blended gasoline, however, provides poorer driveability than a hydrocarbon-type gasoline with the same T50. The purposes of this paper are to examine the reason for poor engine driveability caused by MTBE-blended gasolines, and to propose a new driveability indicator for gasolines including MTBE-blended gasolines. The static and dynamic evaporation characteristics of MTBE-blended gasolines such as the evaporation rate and the behavior of each component during evaporation were analyzed mainly by using Gas Chromatography/Mass Spectrometry. The results of the analysis show that the MTBE concentration in the vapor, evaporated at ambient temperature (e.g. 24°C), is higher than that in the original gasoline. Accordingly, the fuel vapor with enriched MTBE flows into the combustion chamber of an engine just after the throttle valve is opened.