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The wear mechanisms of the methanol engine were studied using dynamometer tests. Formic acid from methanol combustion mixes with the lubricant oil and attacks the metal surfaces. The iso tacho prorissis method was successfully applied to analyze the formic acid content of the used oil. A large amount of condensed water is also formed by methanol combustion and accelerates the wear. Wear can be effectively reduced by shortening lubricant oil change intervals, by using a special oil and by durable surface treatment of engine parts.

Diamond-like carbon (DLC) coating has excellent properties like high hardness and low friction. So it has attracted considerable attention in recent years as a low-friction coating material. However, some DLC coatings display increased wear in oil containing Mo-DTC (Molybdenum-dithiocarbamates). Wear analyses of sliding surface after block-on-ring tests were conducted suggest that the decomposition product from Mo-DTC, MoO3, reacts with active sites in the DLC to promote the wear of DLC.

In order to develop the valve rocker arm material for the new type engine, we investigated various materials whose chemical compositions were selected using 30% chromium cast iron, which had shown good results in screening evaluation tests, as the basis. High chromium cast irons are well known for their abrasive wear resistance, but it has been very difficult to apply them for use as rocker arm material because their machinability is very poor, and because it is difficult for them to have a regular microstructure. In this paper, both the manufacturing method for the rocker arm which decreases the disadvantages that high chromium cast iron have and the rocker arm material best suited for this method are described.

This paper describes the application of a life prediction method for stainless steel exhaust manifolds. Examination of the exhaust manifold cracks indicated that many of the failures could be attributed to out-of-phase thermal fatigue due to compressive strains that occur at high temperatures. Therefore, the plastic strain range was used as the crack initiation criteria. In addition, the comparison of the calculated thermal fatigue stress-strain hysteresis to the experimental hysteresis made it clear that it was essential to use the stress-strain data that was obtained through tensile and compression testing by keeping the test specimens at the maximum temperature of the thermal fatigue test mode. A finite element crack prediction method was developed using the aforementioned material data and good results were obtained.

This paper describes an analysis of the rise in timing belt temperature occuring under high engine speed operation that was made to establish the cause of heat deterioration of the belt materials. Surface temperatures of the belt were accurately measured by correcting thermo-vision detected radiations to eliminate environmental radiation. The temperature profile of a belt cross-section was obtained by a specially developed thermo-couple device. The experimental results indicated that heat generated by the belt contributes significantly to the temperature rise and that the primary cause of the heat generation is bending hysteresis of the belt cords. In addition, a description is made of a method of calculating the rate of heat generation in the belt. In this simulation method, the energy dissipated as heat is calculated from the bending strains and loss moduli of the belt materials. Calculated results were found to agree well with experimental results.

For a vehicle fatigue and strength testing system, two methods are usually used to accurately simulate the road-load on the test bench: one is the “separation of road-load into multi-axial loads” method and the other is the “compensation with frequency response function” method. These methods have remarkably improved the abnormality detection capability and accuracy of bench testing. For power steering or other units, however, the road-load points drift while the vehicle is driven. Further more, the road-load is applied in a complex manner to the vehicle. These factors make it difficult to separate the road-load into multi-axial loads and to provide stable measurement of the frequency response function. Thus, further progress of these methods has been delayed. The objective of this study was to make the bench testing of power steering units possible.

The change of the fuel flow rate in an injector with mileage accumulation causes poor drivability and exhaust emission deterioration in Otto-type methanol fueled vehicles with a multi-point fuel injection system. This is one of the serious problems which needs to be solved for the practical use of methanol fueled vehicles. The investigation results reveal that the wear of contact surfaces between a valve needle and a valve body increases the resistance force for valve needle movement and causes the change of dynamic fuel flow rate in the injector. The effects of several countermeasures to solve this problem are evaluated.

Recently, the California Air Resources Board (CARB) has proposed a new set of evaporative emissions and “Useful Life” standards, called LEVII EVAP regulations, which are more stringent than those of the enhanced EVAP emissions regulations. If the new regulations are enforced, it will become increasingly important for the carbon canister to reduce Diurnal Breathing Loss (DBL) and to prevent deterioration of the canister. Therefore, careful studies have been made on the techniques to meet these regulations by clarifying the working capacity deterioration mechanism and the phenomenon of DBL in a carbon canister. It has been found that the deterioration of working capacity would occur if high boiling hydrocarbons, which are difficult to purge, fill up the micropores of the activated carbon, and Useful Life could be estimated more accurately according to the saturated adsorption mass of the activated carbon and the canister purge volume.

The deterioration of the friction reducing properties of engine oils containing molybdenum dithiocarbamates (MoDTCs) in service was studied. A quantitative analysis of MoDTCs and zinc dithiophosphates (ZDTPs) remaining in aged oils revealed that ZDTPs were consumed faster than MoDTCs. The consumption rate of ZDTPs was slow in the presence of MoDTCs and peroxide-decomposing antioxidants. The frictional properties of aged oils were evaluated with a reciprocating friction tester (SRV tester). The friction coefficient measured with the SRV tester was correlated to the properties of the aged oils, such as the TAN increase, TBN, and concentration of remaining ZDTPs.

It may be possible to simplify the structure and control systems of a lithium-ion battery by replacing the conventional liquid electrolyte with a solid electrolyte, resulting in higher energy density. However, power performance is a development issue of batteries using a solid electrolyte. To increase battery power performance, in addition to lithium ionic conductivity within the bulk of the electrolyte, it is also necessary to boost the lithium ionic conductivity at the interface between the electrode active material and the electrolyte, and to boost electron and lithium ionic conductivity within the cathode and anode active material. This research studied the mechanism of resistance reduction by electrode surface modification. Subsequently, this research attempted to improve electron conductivity by simultaneously introducing oxygen vacancies and carrying out nitrogen substitution in the crystalline structure of the Li4Ti5O12 anode active material.

The use of brakes on public roads depends on traffic conditions and the road itself. In order to research into brake usage on various roads and under various conditions, a micro-computer data logging system was developed. The recorded data were analyzed by a large computer and the severity of brake usages was defined. The relationship between the severity and the brake disc rotor temperature was derived, and used to predict brake pad wear/life. The predicted wear coincided fairly clossly with measured wear.

ϵ-caprolactam was polymerized in the interlayer space of montmorillonite, the clay mineral yielding a nylon-clay hybrid (NCH). X-ray and TEM measurements revealed that each template of the silicate, which was 1 nm thick, was dispersed in the nylon 6 matrix, and that the interlayer distance of clay increased continuously from 1.2 nm for the unintercalated material to 21.4 nm for the intercalated material. Thus, NCH is a polymer-based molecular composite or a nano-composite. NCH contains 1-15 vol% of monolayer clay. Injection-molded NCH showed excellent mechanical properties compared with nylon 6 in terms of tensile strength, tensile modulus and heat resistance. The tensile modulus of NCH was twice that of Nylon 6, and the heat distortion temperature increased from 65°C for nylon 6 to 145°C for the NCH containing only 1.6 vol% of a clay mineral. It was found that such excellent properties of an NCH system was due to the strong ionic interaction between nylon 6 and the silicate layer.

Two effects of rich-spike duration on NOx-storing have been analyzed. The first one, that NOx-storing speed decreases as rich-spike duration increases, is explained as the influence of NOx diffusion in wash-coat layer, which is quantified by a simple mathematical expression for NOx-storing rate. The second one, a peculiar behavior of NOx-storing in appearance of the outlet NOx concentration, is clarified: Heat produced directly or indirectly (via oxygen storage in ceria) by rich-spike warms up the downstream part, which releases excess NOx at the raised temperature. Contributions of the oxygen storage and the carbonate of NOx-storage material are also discussed.

A method of fatigue life estimation for the spot-welds of vehicle body structures by means of Finite Element Analysis (FEA) was studied. 6 general forces applied to a nugget of spot-weld under multiaxial loads were determined and the Nominal Structural Stress (σns) was calculated from them. It was confirmed that fatigue strength of the spot-welds under various multiaxial loads could be estimated universally by using σns. Based on the theory of elasticity of plates, stress of spot-weld nugget was analyzed. The theoretical equations for determining the principal stress at the nugget edge from6 general forces acting on a nugget were derived. And the principal stress was defined as the σns. The value of σns was determined by FEM that used a solid model and compared with the theoretical calculation value. They agreed quite well. Fatigue tests of DC specimens under various multiaxial loads (shear plus cross tension and tensile shear plus torsion) were conducted.

This paper describes lubricant technology to enhance the durability of the low friction performance of gasoline engine oils which were formulated with molybdenum dithiodicarbamates (MoDTCs) as friction modifiers. This paper also describes an evaluation method which consists of three tests: (1) Our in-house rig test to simulate oil deterioration in an engine stand; (2) Quantitative analysis of MoDTC and ZnDTP in oils and; (3) A friction test (SRV). It was found that the low friction performance of fuel economy engine oils deteriorated primarily due to the consumption of MoDTC and ZnDTP. Calcium salicylates had better durability of low friction performance than calcium sulfonates. Furthermore, sulfurized compounds enhanced the durability. Based on these findings, an experimental oil was formulated.

The influence of engine oil viscosity on the wear of piston rings and cam faces has been investigated by fired engine tests using a radioisotope (RI) tracer technique. High-temperature and high-shear-rate (HTHS; 150°C, 1O6 s-1) viscosities of the experimental oils prepared are 2.2, 2.4, 2.6 and 3.1 mPa•s. At an oil temperature of 90°C the wear of piston rings and cam faces did not increase, even if the HTHS viscosity was lowered down to 2.2 mPa•s. However, both piston rings and cam faces exhibited an increase in wear below 2.4 mPa•s at 130°C. It was also recognized that valve train wear did not significantly increase with reducing viscosity in the motored engine tests at a temperature of 50°C. From these test results, it was suggested that the oil with the HTHS viscosity of 2.6 mPa•s sufficiently demonstrates the antiwear performance equivalent to that with around 3.0 mPa•s for application to piston rings and cam faces.

In order to further improve the performance of NOx storage-reduction catalysts (NSR catalysts), focus was placed on their high temperature performance deterioration via sulfur poisoning and heat deterioration. The reactions between the basicity or acidity of supports and the storage element, potassium, were analyzed. It was determined that the high temperature performance of NSR catalysts is enhanced by the interaction between potassium and zirconia, which is a basic metal oxide. Also, a new zirconia-titania complex metal oxides was developed to improve high temperature performance and to promote the desorption of sulfur from the supports after aging.

The authors developed a high-reliability low-cost gold-plated connector for automobiles. The connector is covered with three plated layers, nickel, palladium-nickel alloy, and gold. The three-layer plating helps to reduce the required thickness of gold. This paper describes the reasons why palladium-nickel plating was adopted and compares the corrosion resistance, oxidation resistance and wear resistance of three-layer-plated materials with those of conventional gold-plated materials. In addition, the characterisitics of three-layer-plated connectors were compared with those of conventional gold-plated connectors. It was found that the reliability of three-layer-plated connectors was as high as that of conventional gold-plated connectors.

This paper deals with friction under wet condition in the disk brake system of automobiles. In our previous study, the variation of friction coefficient μ was observed under wet condition. And it was experimentally found that μ becomes high when wear debris contains little moisture. Based on the result, in this paper, we propose a hypothesis that agglomerates composed of the wet wear debris induce the μ variation as the agglomerates are jammed in the gaps between the friction surfaces of a brake pad and a disk rotor. For supporting the hypothesis, firstly, we measure the friction property of the wet wear debris, and confirm that the capillary force under the pendular state is a factor contributing to the μ variation. After that, we simulate the wear debris behavior with or without the capillary force using the particle-based simulation. We prepare the simulation model for the friction surfaces which contribute to the friction force through the wear debris.

The effect of phosphorus concentration in gasoline engine oils on the valve train wear was experimentally investigated by using the JASO M328-91 3A valve train wear (3A-VTW) test method. The phosphorus concentration is determined proportionally to the amount of zinc dithiophosphate (ZDDP), which is formulated as both antiwear agent and antioxidant. Lower concentrations of ZDDP generally bring about larger wear in the valve train. However, it was found from the experiments that valve train wear remained low despite a decrease of phosphorus concentration when secondary ZDDPs with short alkyl chain together with appropriate ashless dispersants were selected. Since adsorptivity of secondary ZDDPs with short alkyl chain lengths onto rubbing metal surfaces is higher than that of primary types, the secondary types give excellent antiwear characteristics.