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Technical Paper

A New V-8 Engine for the LEXUS LS 400

1989-09-01
892003
A new 4.0 liter V8 engine, 1UZ-FE, has been developed for the luxury sedan, LEXUS LS400. The engine has 4 camshafts and 32 valves, and weighs only 195 kg (430 lbs) having many light alloy components and carefully designed configurations. The appropriate engine displacement and high technology adopted throughout from design to manufacturing process enable the LS400 to run powerfully with excellent fuel economy and a pleasant sounds. It develops 250HP at 5600 rpm and 260ft-lbs of torque at 4400 rpm, and its fuel economy figure, well exceeds the EPA's tax charge level of 22.5mpg. These figures have been achieved through the newest technologies applied to every part of the design, such as: Well studied intake and exhaust systems, centrally located spark plug in the TOYOTA original four-valve combustion chamber, which has a narrow valve including angle, and low friction components like aluminum alloy valve lifters and well balanced moving parts.
Technical Paper

Analysis and Simplification of Thermal Endurance Tests of NOx Storage-Reduction Catalysts

2004-03-08
2004-01-1496
Our two types of NOx storage-reduction (NSR) catalyst have been tested under various conditions of thermal endurance; the performance of these catalysts have been regressed to give the formulas that enable to estimate the performance after thermal endurance; and we have found the method to simplify (shorten the duration of) the thermal endurance tests and that the thermal deterioration of NSR catalysts is controlled by the worst condition of endurance (at least approximately). The regression formula for the amount of potassium that contributes to the catalyst performance (active K) after the endurance has also been obtained. These formulas predict that the amount of active K is the least for the worst condition of endurance and suggest a difference in deterioration mechanism that reflects the performance between low and high temperatures and the portion of worse deterioration (front or rear).
Journal Article

Analysis of Influence of Snow Melting Agents and Soil Components on Corrosion of Decorative Chrome Plating

2016-04-05
2016-01-0539
The dissolution and exfoliation of chromium plating specific to Russia was studied. Investigation and analysis of organic compounds in Russian soil revealed contents of highly concentrated fulvic acid. Additionally, it was found that fulvic acid, together with CaCl2 (a deicing agent), causes chromium plating corrosion. The fulvic acid generates a compound that prevents reformation of a passivation film and deteriorates the sacrificial corrosion effectiveness of nickel.
Technical Paper

Analysis of Potassium Storage Components in NOx Catalysts Application of Analytical Techniques and DFT Computations to Catalytic Analysis

2004-03-08
2004-01-1494
By using analytical techniques (FT-IR, TG-MS, ICP) and DFT calculations, the potassium (K) used as a storage component in NOx Catalysts can be analyzed. The results from this study show that the, K exists as K2CO3, and that the amount, molecular structure, and thermal stability of K2CO3 are different, depending on the support material (ZrO2, Al2O3, or TiO2). If the amount of K that interacts with the support to form an inactive complex oxide is decreased, the amount of K2CO3 and NOx storage is increased. The amount of the inactive K varies with the basicity of the supports. K2CO3 that exists in unstable structures on the supports can be easy to react with NOx to form the nitrate. So, the higher the quantity of unstable K2CO3, the higher the NOx storage capacity. Based on these results, a development guideline was proposed to improve the NOx storage performance.
Technical Paper

Application of Structural Color Technology for Automotive Paint

2005-04-11
2005-01-0617
Currently, to achieve the desired design in automotive paint, absorption pigments, such as organic pigments, are used in combination with brilliant pigments (ex. aluminum or mica etc.). However, many beautiful colors exist in the world, especially in the natural world. Until now, automotive paints have not been able to replicate those colors. In this project, by first analyzing the coloring principles of the natural world, we have focused on the development of a previously non-existent coloring technology (structural color). By combining this with nanostructure control technology, we have established a radically new coloring process enabling the design of hues, chromaticity and reflection intensity. This technology has tangible results, as new pigments are available for paint formulations.
Journal Article

Development of Bio-Based Plastics for Injection Molding

2009-04-20
2009-01-0019
Technological development of materials derived from plants (e.g., polylactic acid (PLA), and the like) is required to break dependence on fossil fuels and reduce CO2. PLA has inferior hydrolysis resistance, impact resistance, and molding ability than polypropylene (PP), and in order to overcome these disadvantages, a novel PP/PLA alloy has been conceived where PLA is incorporated into a PP matrix. By optimizing compatibilizer and elastomer addition, PLA has been successfully dispersed into a PP matrix at a sub-micron order, and interior parts have been successfully developed that fulfill the performance, appearance, and mass-production capability requirements for practical application.
Technical Paper

Development of High Performance Three-Way-Catalyst Technology to Lower NOx Emission

2009-04-20
2009-01-1398
One primary result of the reduction of platinum group metals (PGM) within a catalytic converter is the decline in NOx conversion efficiency. This paper hypothesizes that the primary factor of this decline to be hydrocarbon (HC) poisoning. To maintain high NOx conversion efficiency as the PGM reduces, Rh activation improvement becomes significant to overcome the HC poisoning. Analysis of the Rh deterioration mechanism found that it is effective to separately arrange Rh and CeO2 on the converter, avoiding the Rh deactivation. By this improvement, we improved the catalyst activity at less than 25% of the original Rh loading.
Technical Paper

Development of High-Strength Aluminum Piston Material

2010-04-12
2010-01-0220
Mass reduction of parts is growing in importance as a means for reducing CO2 emissions from vehicles.The aim of the present research was to contribute to further mass reduction of pistons by developing a new aluminum casting material with highest level of fatigue strength. This goal was achieved using a development concept of creating a homogeneous structure in which Ti was added to create a fine structure and appropriate quantities of Fe and Mn were added to form a compound that is stable at high temperatures. Stand-alone tests of prototype pistons fabricated using the developed material show that the material is 14% stronger than the conventional material, thereby enabling increases in power and mass reduction.
Technical Paper

Development of Sealing Material Used in the Body Welding Shop

2007-04-16
2007-01-0418
1 The principal characteristics required of sealing materials used in the body shop have focused on their adhesion to oily steel sheets and quick curing performance. Means for attaining these characteristics have been narrowed down to a basic resin system and a curing system. Various techniques have been studied to ensure proper anti-corrosion performance at the sealer application boundaries and thin application areas. They include the addition of anti-corrosion fillers, the provision of conductivity (through electro-deposition), and the application of a micro foam film over the application boundaries. Thus, prospects for attaining the same level of anti-corrosion performance as existing materials have been achieved.
Technical Paper

Development of Simplified Finite Element Model for Ultra-High-Strength Steel Resistance Spot Weld Fractures

2020-04-14
2020-01-0220
This paper describes the development of a simplified fracture finite element (FE) model for resistance spot welds (RSW) of ultra-high-strength steel (UHSS) that can be incorporated into large-scale vehicle FE model. It is known that the RSW of UHSS generates two types of fracture modes: heat-affected zone (HAZ) and nugget zone fractures. Lap shear and peeling coupon tests using UHSS sheets found that the different RSW fracture modes occurred at different nugget diameters. To analyze this phenomenon, detailed simulated coupon tests were carried out using solid hexahedral elements. The analytical results revealed that RSW fractures are defined by both the application of plastic strain on the elements and the stress triaxiality state of the elements. A detailed model incorporating a new fracture criteria model recreated the different UHSS RSW fracture modes and achieved a close correlation with the coupon test results.
Technical Paper

Development of TLP-AI Technology to Realize High Temperature Operation of Power Module

2019-04-02
2019-01-0607
Application of SiC power devices is regarded as a promising means of reducing the power loss of power modules mounted in power control units. Due to those high thermostable characteristics, the power module with SiC power devices are required to have higher operating temperature than the conventional power module with Si power devices. However, the limitations of current packaging technology prevent the utilization of the full potential of SiC power devices. To resolve these issues, the development of device bonding technology is very important. Although transient liquid phase (TLP) bonding is a promising technology for enabling high temperature operation because its bonding layer has a high melting point, the characteristics of the TLP bonding layer tend to damage the power devices. This paper describes the development of a bonding technology to achieve high temperature operation using a stress reduction effect.
Technical Paper

Development of Three-Way Catalysts Enhanced NOx Purifying Activity

2018-04-03
2018-01-0942
Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).
Technical Paper

Development of Ultra Low Viscosity 0W-8 Engine Oil

2020-04-14
2020-01-1425
Further fuel economy improvement of the internal combustion engine is indispensable for CO2 reduction in order to cope with serious global environmental problems. Although lowering the viscosity of engine oil is an effective way to improve fuel economy, it may reduce the wear resistance. Therefore, it is important to achieve both improved fuel economy and reliability. We have developed new 0W- 8 engine oil of ultra-low viscosity and achieved an improvement in fuel economy by 0.8% compared to the commercial 0W-16 engine oil. For this new oil, we reduced the friction coefficient under boundary lubrication regime by applying an oil film former and calcium borate detergent. The film former increased the oil film thickness without increasing the oil viscosity. The calcium borate detergent enhanced the friction reduction effect of molybdenum dithiocarbamate (MoDTC).
Journal Article

Development of a Ceramic EHC

2022-03-29
2022-01-0536
In recent years, electrically heated catalysts (EHCs) have been developed to achieve lower emissions. In several EHC heating methods, the direct heating method, which an electric current is applied directly to the catalyst substrate, can easily activate the catalyst before engine start-up. The research results reported on the use of the direct heating EHC to achieve significant exhaust gas purification during cold start-up [1]. From the perspective of catalyst loading, ceramics is considered to be a better material for the substrate than metal due to the difference in coefficient of thermal expansion between the catalyst and the substrate, but the EHC made of ceramics has difficulties such as controllability of the current distribution, durability and reliability of the connection between the substrate and the electrodes.
Journal Article

Development of a Highly Anti-Corrosive Organic-Inorganic Hybrid Paint

2016-04-05
2016-01-0540
A highly anti-corrosive organic-inorganic hybrid paint for automotive steel parts has been developed. The inorganic component included in the paint is silicon dioxide (SiO2), which has the capability to passivate zinc. By application of the paint on a trivalent chromatetreated zinc-plated steel sheet or a trivalent chromate-treated zinc-nickel-plated steel sheet, high anti-corrosion protection can be provided to steel materials. Particularly in the case of application over a zinc-nickel-plated steel sheet, 0 mm corrosion depth after a cyclic corrosion test (CCT) of 450 cycles was demonstrated.
Journal Article

Development of a New Ceramic Substrate with Gas Flow Control Functionality

2017-03-28
2017-01-0919
Emission regulations in many countries and regions around the world are becoming stricter in reaction to the increasing awareness of environment protections, and it has now become necessary to improve the performance of catalytic converters to achieve these goals. A catalytic converter is composed of a catalytically active material coated onto a ceramic honeycomb-structured substrate. Honeycomb substrates play the role of ensuring intimate contact between the exhaust gas and the catalyst within the substrate’s flow channels. In recent years, high-load test cycles have been introduced which require increased robustness to maintain low emissions during the wide range of load changes. Therefore, it is extremely important to increase the probability of contact between the exhaust gas and catalyst. To achieve this contact, several measures were considered such as increasing active sites or geometrical surface areas by utilizing substrates with higher cell densities or larger volumes.
Technical Paper

Development of a New High Orientation Paint System to Achieve Outstanding Real Metallic Designs

2020-04-14
2020-01-0899
Silver metallic colors with thin and smooth aluminum flake pigments have been introduced for luxury brand OEMs. Regarding the paint formulation for these types of colors, low non-volatile(NV) and high aluminum flake pigment contents are known as technology for high metallic appearance designs. However, there are two technical concerns. First is mottling which is caused by uneven distribution of the aluminum flake pigments in paint film and second is poor film property due to high aluminum pigment concentration in paint film. Therefore, current paint systems have limitation of paint design. As a countermeasure for those two concerns, we had investigated cellulose nanofiber (CNF) dispersion liquid as both the coating binder and rheology control agent in a new type of waterborne paint system. CNF is an effective rheology control agent because it has strong hydrogen bonds with other fiber surfaces in waterborne paint.
Technical Paper

Examination of Crack Growth Behavior in Induction Hardened Material under Torsional Fatigue

2011-04-12
2011-01-0198
Since wear resistance and fatigue strength are key requirements for chassis components, induction hardening is widely used to apply compressive stress for controlling crack growth. Therefore, it is crucial that the influence of defects is examined with compressive residual stress applied to parts. In this report, the relationship between crack depth and compressive residual stress is evaluated using a cylindrical specimen and a torsional fatigue test. The test results were found to be consistent with CAE simulations performed in advance. In the future, it will be necessary to make this method applicable to product design to further improve vehicle safety performance.
Technical Paper

Fatigue Life Prediction Method for Laser Screw Welds in Automotive Structures

2016-04-05
2016-01-0394
This paper describes the development of a fatigue life prediction method for Laser Screw Welding (LSW). Fatigue life prediction is used to assess the durability of automotive structures in the early design stages in order to shorten the vehicle development time. The LSW technology is a spot-type joining method similar to resistance spot welding (RSW), and has been developed and applied to body-inwhite structures in recent years. LSW can join metal panels even when a clearance exists between the panels. However, as a result of this favorable clearance-allowance feature of LSW, a concave shape may occur at the nugget part of the joint. These LSW geometric features, the concavity of nuggets and the clearance between panels, are thought to affect the local stiffness behavior of the joint. Therefore, while assessing the fatigue life of LSW, it is essential to estimate the influence of these factors adequately for the representation of the local stiffness behavior of the joint.
Technical Paper

Friction Reduction Technology for Low Viscosity Engine Oil Compatible with LSPI Prevention Performance

2016-10-17
2016-01-2276
Increasing numbers of vehicles equipped with downsized, turbocharged engines have been introduced seeking for better fuel economy. LSPI (low speed pre-ignition), which can damage engine hardware, is a potential risk of the engines. We reported that engine oil formulation affects frequency of LSPI events, and formulating magnesium detergents into oil is a promising option to prevent LSPI events. From the viewpoint of achieving better fuel economy by engine oil, lowering viscosity is being required. However, it causes reduced oil film thickness and will expand boundary lubrication condition regions in some engine parts. Hence, a technology to reduce friction under boundary lubrication becomes important.
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