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A new diesel after-treatment system, Diesel Particulate and NOx Reduction System (DPNR), is being developed for reducing PM and NOx emissions. We examined the effects of sulfur content in lubricants on exhaust NOx emission from DPNR catalyst, and examined the PM reduction ability using sulfur-free and aromatics-free fuel. After vehicle durability testing of 40,000 km without forced regeneration of PM and sulfur poisoning on DPNR catalyst, deterioration of DPNR was lower than using higher sulfur contents in fuel and oil. In addition to decreasing fuel sulfur, decreasing oil sulfur was also effective to maintain high NOx conversion efficiency. Although the catalyst was poisoned by sulfur in the lubricants, the influence of oil sulfur poisoning on the catalyst was lower than fuel sulfur poisoning. On the other hand, engine out PM emissions decreased by 70 % because of aromatics-free fuel. The pressure drop of DPNR did not increase during the 40,000 km vehicle durability test.

Diesel particulate and NOx reduction system (DPNR) is an effective technology for the diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. The DPNR has been developed under the Toyota D-CAT (Diesel Clean Advanced Technology) concept. Further improvement of the DPNR is hoped for cleaner air in the future. This paper reviews the results of our study to improve the NOx purification performance on the DPNR. The NOx reduction performance of the catalysts deteriorates due to thermal deterioration and sulfur poisoning. In order to improve the thermal resistance of the catalysts, the suppression of precious metal sintering in the catalyst has been studied. As a result, higher catalytic activity after aging especially under lower temperature conditions was obtained. On the other hands, improvement of desulfurization performance is one of the key technologies in order to keep the high NOx reduction capability of the catalyst.

The Diesel Particulate and NOx Reduction System (DPNR) is an effective technology as a diesel after-treatment system, which can reduce particulate matter (PM) and nitrogen oxides (NOx) simultaneously. However, it requires desulfurization control since the DPNR catalyst is poisoned by sulfur components in the exhaust gas from the fuel and lubricant. Desulfurization control causes some degree of fuel penalty and thermal deterioration of the DPNR catalyst because it requires control of rich air fuel ratio and high temperature simultaneously. In this paper, we investigated a new system with a sulfur trap catalyst which can trap sulfur components included in the exhaust gas as sulfates (Sulfur trap DPNR). In this system, desulfurization control is not performed because the sulfur poisoning of the DPNR catalyst is drastically suppressed by the sulfur trap catalyst. In the present DPNR, periodic desulfurization control is required.