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Trivalent chromate coating is replacing the conventional hexavalent chromate coating applied on zinc plating. Zinc plating uses one of three types of plating baths (zincate, cyanide and chloride) according to the characteristics required of subject parts. It has been recognized that trivalent chromate coating provides different corrosion resistance depending on the type of zinc plating bath used. Zinc plating with chromate coating were analyzed to clarify the cause of the corrosion resistance variation with the type of zinc plating bath. It has been revealed that the chromate coating thickness and the condition of top SiO2 layer vary with the type of zinc plating bath, resulting in corrosion resistance variation.

In an evaluation of crashworthiness for the cars made of aluminum alloys, the evaluation considering fracture phenomenon comes to be needed because conventional aluminum alloys have low fracture strain (10-20%). In case of the development of a B-Pillar made by die cast, if crack occurrence, furthermore, separation of a part can be estimated by using CAE in crashworthiness evaluations, we can reduce the number of prototype makings and the cost of development using expensive dies. Therefore, we performed crashworthiness evaluations by CAE using some sort of a damage & fracture material model. It is known as “Orthotropic damage & fracture model”.

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).

Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.

Performance improvements were studied for the diesel particulate and NOx reduction system (DPNR), a system that simultaneously reduces NOx and Particulate Matter (PM) from diesel engine exhaust gas. The experimental system (hereinafter called the “dual DPNR”) consists of two DPNR catalysts arranged in parallel, each provided with an exhaust throttle valve downstream to control the exhaust gas flow to the catalyst, plus a fuel injector that precisely controls the air-fuel ratio and the catalyst bed temperature. The fuel injector is used to supply a rich mixture to the DPNR catalyst, and the flow of exhaust gas is switched between the two catalysts by operating the exhaust throttle valves alternately. Tests were conducted with the engine running at steady state. The results indicated that the NOx reduction performance dramatically improved and the loss of fuel economy from the NOx reduction reduced.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

We have tried to improve damping capacity of an aluminum alloy by means of dispersing ceramic particles (low damping SiC and high damping NdNbO4) of different sizes and volume fractions in the aluminum alloy by powder metallurgy. It is shown that the damping capacity is increased in every case accompanying an increase of Young's modulus. It is also shown that the intrinsic damping capacity of dispersed particles does not play a role in improving the damping capacity. The increase of the damping capacity seems to be attributed to dislocations breakaway, interaction of fine particles and dislocations, and relaxation of interface between ceramic particles and aluminum matrix.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

The knock-suppression effectiveness of exhaust-gas recirculation (EGR) can vary between implementations that take EGR gases after the three-way catalyst and those that use pre-catalyst EGR gases. A main difference between pre-and post-catalyst EGR gases is the level of trace species like NO, UHC, CO and H2. To quantify the role of NO, this experiment-based study employs NO-seeding in the intake tract for select combinations of fuel types and compression ratios, using simulated post-catalyst EGR gases as the diluent. The four investigated gasoline fuels share a common RON of 98, but vary in octane sensitivity and composition. To enable probing effects of near-zero NO levels, a skip-firing operating strategy is developed whereby the residual gases, which contain trace species like NO, are purged from the combustion chamber. Overall, the effects of NO-seeding on knock are consistent with the differences in knock limits for preand post-catalyst EGR gases.

HEV and PHEV require an improved aftertreatment system to clean the exhaust gas in various driving situations. The efficiency of aftertreatment system is significantly influenced by the residence time of the gas in a catalyst which gas flow has generally strong pulsation. Simulation showed up to 70% reduction of exhaust gas emission if the pulsation could be completely attenuated. A new concept exhaust manifold was designed to minimize pulsation flow by wall impingement, with slight increase of pressure loss. Experimental results with new concept exhaust manifold showed exhaust gas emission were reduced 16% at cold condition and 40% at high-load condition.

When developing an off-road vehicle, it is essential to create excellent drivability that enables the vehicle to be driven on all surfaces while ensuring passenger comfort. Since durability is another indispensable performance aspect for these vehicles, the development method must be capable of considering a high-level combination of a wide range of performance targets. This paper proposes a method to identify the region in which each performance aspect is realized through a complex domain combination problem. The proposed method is helpful in the initial design stage when the detailed specifications of the target vehicle are not determined because it is capable of considering both the specifications and usage method of the target vehicle, such as the selection of road profiles and driving speeds as design variables. The proposed method has the advantage of enabling efficient concurrent studies to search for feasible regions.

Urea selective catalytic reduction (SCR) systems are a promising technology for helping to lower NOx emissions from diesel engines. These systems also require on-board diagnostic (OBD) systems to detect malfunctioning catalysts. Conventional OBD methodology for a SCR catalyst involves the measurement of NOx concentration downstream of the catalyst. However, considering future OBD regulations, erroneous diagnostics may occur due to variations in the actual environment. Therefore, to enhance OBD accuracy, a new methodology was examined that utilizes NH3 slip as a new diagnostic parameter in addition to NOx. NH3 slip increases as the NOx reduction performance degrades, because both phenomena are based on deterioration in the capability of the SCR catalyst to adsorb NH3. Furthermore, NH3 can be measured by existing NOx sensors because NH3 is oxidized to NO internally. To make use of NH3 slip, an estimation model was developed.

A technique for induction-hardening local portions of vehicle body reinforcements press-formed of thin sheet steel has been developed, with the aim of ensuring occupant safety in a side collision. This technique for increasing the tensile strength of sheet steel was practically applied to the front floor cross member and center pillar reinforcement. Owing to this method, the weight of body reinforcements can be decreased. New induction-hardening systems have also been developed for the present technique. One is an apparatus which allows induction-hardening a part with a three-dimensionally curved surface. Another is a straightening quench technique used to retain the same dimensional accuracy as the original press-formed part.

From the viewpoint of measures for environmental issues, the amount of solvents in paint for aluminum wheels needs to be minimized. Environmentally friendly powder coatings have been used widely for primer coating and clear coating, but there is no precedent for its use for base coating. This time, we optimized the condition of surface treatment of pigment and hardening behavior of constituent resin in the melting process and succeeded in developing a metallic powder coating for aluminum wheels that fulfills the appearance and the quality requirements of aluminum wheels.

The experimental research vehicle ES3 body was realized by using various aluminum-joining technologies: MIG welding, laser welding, self-piercing riveting. These technologies were applied selectively to make full use of their individual characteristics, according to the body structure and joined materials. Of these technologies, self-piercing riveting is advantageous in several respects. Aiming to expand the application range of riveting technology, we developed a die that prevents cracks in joining aluminum casting, and a method to improve rivet driving in thick, multi-pile portion. We further studied the feasibility of aluminum rivets. This paper outlines the ES3 body structure and it's joining technologies used and introduces the further improvements we developed concerning self-piercing riveting.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

Influence of sulfur poisoning on NOx storage - reduction catalysts (NSR catalysts) was examined using both model gas and an actual vehicle. Deterioration of NSR catalysts is explained as the balance of sulfate formation in lean operating conditions and the amount of sulfate decomposed under rich operating conditions. This study focused on sulfate decomposition characteristics of NSR catalysts. First, sulfate decomposition characteristics of an NSR catalyst were examined in a model gas test. It was found that the initial temperature of SOx release was higher than the sulfur poisoning temperature. Crystal growth of sulfate by increasing temperature was assumed, and hence suppressed SOx release. Second, various sulfur concentrations (8 - 500 ppm) in gasoline were used for vehicle durability. The duration of one durability cycle was 1,260 seconds, including a 60 second regeneration of sulfur poisoning (AFR 14.2, 700 °C).