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Previous work has shown that wallboard can be successfully manufactured to contain up to 30% phase change material (PCM), or wax, thus enabling this common building material to serve as a thermal energy storage device. This material was analyzed for passive solar applications and found to save energy with a reasonable pay-back time period. Further evaluations of the wallboard are reported in this paper. This analysis looks at potential applications of PCM wallboard as a load management device and as a comfort enhancer. Results show that the wallboard is ineffective in modifying the comfort level but can provide significant load management relief with no energy penalty. Modifications to typical heating and air-conditioner control strategies were necessary for successful load management.

The potential peaking of world conventional oil production and the possible imperative to reduce carbon emissions will put great pressure on vehicle manufacturers to produce more efficient vehicles, on vehicle buyers to seek them out in the marketplace, and on energy suppliers to develop new fuels and delivery systems. Four cases for stabilizing or reducing light vehicle fuel use, oil use, and/or carbon emissions over the next 50 years are presented. Case 1 - Improve mpg so that the fuel use in 2020 is stabilized for the next 30 years. Case 2 - Improve mpg so that by 2030 the fuel use is reduced to the 2000 level and is reduced further in subsequent years. Case 3 - Case 1 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. Case 4 - Case 2 plus 50% ethanol use and 50% low-carbon fuel cell vehicles by 2050. The mpg targets for new cars and light trucks require that significant advances be made in developing cost-effective and very efficient vehicle technologies.

Porous wall permeability is one of the most critical factors for the estimation of backpressure, a key performance indicator in automotive particulate filters. Current experimental and analytical filter models could be calibrated to predict the permeability of a specific filter. However, they fail to provide a reliable estimation for the dependence of the permeability on key parameters such as wall porosity and pore size. This study presents a novel methodology for experimentally determining the permeability of filter walls. The results from four substrates with different porosities and pore sizes are compared with several popular permeability estimation methods (experimental and analytical), and their validity for this application is assessed. It is shown that none of the assessed methods predict all permeability trends for all substrates, for cold or hot flow, indicating that other wall properties besides porosity and pore size are important.

The successful commercialization of Electric Vehicles (EVs) and Hybrid Electric Vehicles (HEVs) can provide significant benefits by reducing the United States' growing dependence on petroleum fuels for transportation; decreasing polluting and greenhouse gas emissions; and facilitating a long-term transition to sustainable renewable energy sources. Recognizing these benefits, the U.S. Department of Energy (DOE) supports an active program of long-range R&D to develop electric vehicle (EV) and hybrid electric vehicle (HEV) technologies and to accelerate their commercialization. The DOE Office of Advanced Automotive Technologies (OAAT) supports several innovative R&D programs, conducted in partnership with DOE's national laboratories, industry, other government agencies, universities, and small businesses. The Office has two key R&D cooperative agreements with the U.S. Advanced Battery Consortium (USABC) to develop high-energy batteries for EVs and high-power batteries for HEVs.

The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.

Thermal diffusivity and thermal conductivity of grey cast iron have been measured as a function of graphite flake morphology, chemical composition and position in a finished brake rotor. Cast iron samples used for this investigation were cut from “step block” castings designed to produce iron with different graphite flake morphologies resulting from different cooling rates. Samples were also machined from prototype alloys and from production brake rotors representing a variation in foundry practice. Thermal diffusivity was measured at room and elevated temperatures via the flash technique. Heat capacity of selected samples was measured with differential scanning calorimetry, and these results were used to calculate the thermal conductivity. Microstructure of the various cast iron samples was quantified by standard metallography and image analysis techniques, and the chemical compositions were determined by optical emission spectroscopy.

The Partnership for a New Generation of Vehicles (PNGV) is linking the research efforts of a broad spectrum of U.S. Federal agencies and laboratories with those of the domestic auto manufacturers in pursuit of three specific, interrelated goals: 1) reduce manufacturing production costs and product development times for all car and truck production; 2) pursue advanced technologies for near-term vehicle improvements that increase fuel efficiency and reduce emissions of standard vehicles; and 3) within the next decade, develop a new class of vehicle that will achieve up to three times the fuel efficiency of today's comparable vehicle, and, at the same time, cost no more to own and drive than today's automobile, maintain performance, size, and utility of comparable vehicles, and meet or exceed safety and emission requirements.

The U.S. Department of Energy's Office of Energy Efficiency & Renewable Energy initiated a study that conducted coastdown testing and chassis dynamometer testing of three vehicles, each at multiple test weights, in an effort to determine the impact of a vehicle's mass on road load force and energy consumption. The testing and analysis also investigated the sensitivity of the vehicle's powertrain architecture (i.e., conventional internal combustion powertrain, hybrid electric, or all-electric) on the magnitude of the impact of vehicle mass. The three vehicles used in testing are a 2012 Ford Fusion V6, a 2012 Ford Fusion Hybrid, and a 2011 Nissan Leaf. Testing included coastdown testing on a test track to determine the drag forces and road load at each test weight for each vehicle. Many quality measures were used to ensure only mass variations impact the road load measurements.

With the advent of stricter vehicle emission standards, the improvement of three way catalyst performance and durability remains a pressing issue. A critical consideration in catalyst design is the potential for variations in fuel sulfur levels to have a significant impact on the ability to reach TLEV, LEV, and ULEV emission levels. As a result, a better understanding of the role of PGM composition in the interplay between thermal durability and sulfur tolerance is required. Three way catalysts representative of standard Pd-only, Pd/Rh and Pt/Rh formulations were studied over a variety of aging and evaluation conditions. The parameters investigated included aging temperature, air fuel ratio and sulfur level. Evaluations were performed on a 1994 TLEV vehicle using different sulfur level fuels. The effect of PGM loading was also included within the study.

On April 6, 1984, EPA announced a final rule (40 CFR Part 600, Vol. 49, No. 68) which amended the Federal Fuel Economy Information Program by prescribing adjustment factors for the Federal fuel economy numbers and by establishing a new format for the Federal fuel economy label displayed on new vehicles. This rule, one of over 5, 000 documents printed in the 1984 Federal Register rule section, presents some interesting lessons about development of government regulations. The contents of this rule amended an existing rule, did not have a “major” impact on the economy, and was not considered to be controversial. Nonetheless, this rule represents at least nine years of work, negotiations, and deliberations by Federal and private sector organizations. The history of this rule can provide insight into the Federal rulemaking process, and the forces affecting that process.

In a collaborative programme, the effects of gasoline sulphur content on regulated emissions from three-way catalyst equipped vehicles have been studied. The programme evaluated the sulphur tolerance of three different catalyst formulations on the same range of vehicles. The catalyst chemistries were chosen to be representative of typical current formulations in different markets, as follows: 1. Platinum/Rhodium (Pt/Rh) 2. Platinum/Rhodium/Nickel (Pt/Rh/Ni) 3. Palladium/Rhodium (Pd/Rh) Each vehicle/catalyst combination was tested with fuels containing sulphur at nominal levels of 50, 250 and 450 ppm weight. All fuels were produced using the low sulphur fuel as a base and doping to 250 and 450 ppm S with a mixture of nine sulphur compounds, typical of those actually occurring in European gasolines. The results show clear differences between the magnitudes of the sulphur effect with different catalyst formulations.

Progress made in reducing engine-out particulate emissions has prompted a revival in the design of flow-through oxidation catalysts for diesel engine applications. Effort in this area has focused primarily in the area of SOF control for the further reduction of particulate emissions. The work reported here covers some of the catalyst design parameters important for SOF and gas phase pollutant control. This is illustrated with both laboratory reactor and engine evaluation data for several formulary and operating parameters. Platinum-based catalysts are shown to be generally the most active, but they require treatments or additives to reduce the inherently high activity of platinum for the oxidation of SO2 present in the exhaust. The effect of additives and their loading on the oxidation activity of Pt/alumina for HC, CO, SOF and SO2 oxidation is discussed in detail and additives are identified which reduce SO2 oxidation with minimal effect on HC, CO or SOF oxidation activity.

This paper summarizes the Next Generation Natural Gas Vehicle (NG-NGV) Program that is led by the U.S. Department Of Energy's (DOE's) Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of this program is to develop and implement one Class 3-6 compressed natural gas (CNG) prototype vehicle and one Class 7-8 liquefied natural gas (LNG) prototype vehicle in the 2004 to 2007 timeframe. OHVT intends for these vehicles to have 0.5 g/bhp-hr or lower emissions of oxides of nitrogen (NOx) by 2004 and 0.2 g/bhp-hr or lower NOx by 2007. These vehicles will also have particulate matter (PM) emissions of 0.01 g/bhp-hr or lower by 2004. In addition to ambitious emissions goals, these vehicles will target life-cycle economics that are compatible with their conventionally fueled counterparts.

This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.

This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.

The Cooperative Automotive Research for Advanced Technology (CARAT) program is designed to accelerate the commercialization of innovative technologies that will overcome barriers to achieving the goals of the Partnership for a New Generation of Vehicles Program. Aimed at harnessing the creativity and capabilities of American small businesses and colleges and universities, this unique technology R&D program seeks to develop and bring advanced technologies into use in production vehicles at a faster rate. CARAT's focus is developing and commercializing technology that overcomes key technical barriers preventing the production of vehicles with ultra-high fuel efficiency. CARAT begins with technologies that already have a firm technical basis and, through a unique three-stage process, ends with fully validated technologies ready for mass production. The program is open to all U.S. entrepreneurs and small businesses, colleges, and universities.

The effects of hybridization on heavy-duty vehicles are not well understood. Heavy vehicles represent a broader range of applications than light-duty vehicles, resulting in a wide variety of chassis and engine combinations, as well as diverse driving conditions. Thus, the strategies, incremental costs, and energy/emission benefits associated with hybridizing heavy vehicles could differ significantly from those for passenger cars. Using a modal energy and emissions model, we quantify the potential energy savings of hybridizing commercial Class 3-7 heavy vehicles, analyze hybrid configuration scenarios, and estimate the associated investment cost and payback time.

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

Selective NOx recirculation (SNR), involving adsorption, selective external recirculation and decomposition of the NOx by the combustion process, is itself a promising technique to abate NOx emissions. Three types of materials containing Ba: barium aluminate, barium tin perovskite and barium Y-zeolites have been developed to adsorb NOx under lean-burn or Diesel conditions, with or without the presence of S02. All these materials adsorb NO2 selectively (lean-burn conditions), and store it as nitrate/nitrite species. The desorption takes place by decomposition of these species at higher temperatures. Nitrate formation implies also sulfate formation in the presence of SO2 and SO3, while the NO2/SO2 competition governs the poisoning of such catalysts.

The SNR-technique is a new NOx aftertreatment system for lean burn gasoline and diesel applications. The objective of SNR is NOx removal from lean exhaust gas by NOx adsorption and subsequent selective external recirculation and decomposition of NOx in the combustion process. The SNR-project is composed of two major parts. Firstly the development of NOx adsorbents which are able to store large quantities of NOx in lean exhaust gas, and secondly the NOx decomposition by the combustion process. Emphasis of this paper is the investigation of NOx reduction in the combustion process, including experimental investigation and numerical simulation. The NOx decomposition process has been proven in diesel and lean-burn gasoline engines. Depending on the type of engine NOx-conversion rates up to 90 % have been observed. Regarding the complete SNR-system, including the efficiency of the adsorbing material and the NOx decomposition by the combustion, a NOx removal of more than 50% is achievable.