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The project objective was to investigate the ultrafine solid particle emissions of the prevalent traffic, by performing field measurements at an urban traffic artery in Zurich/Switzerland. Subsequently, various scenarios were postulated to assess the potential of the diesel particle filters (DPF) to improve curbside air quality. Soot aerosols are known to be carcinogenic [1]. If all heavy-duty diesel vehicles were equipped with DPFs, then the number of particles emitted from the entire vehicle fleet could be reduced by 75 to 80%. For PM10, the curtailment scope is considerably lower, around 20%, because more than half of those emissions are not from the exhaust and therefore would not be filtered.

The increased interest in use of methanol makes it important to determine what levels of methanol and formaldehyde emissions may be acceptable. This paper reviews the available health data for methanol and formaldehyde to define what approximate ranges of concentrations, termed ranges of concern, could be acceptable from a toxicological viewpoint. Air quality models are then used to predict the in-use fleet average exhaust emission levels in localized situations (heavily impacted by mobile sources) corresponding to these ranges of concern. Using predicted fleet compositions, approximate target emission levels are given for the light-duty portion of the fleet which could yield these fleet averages. Finally, there is a brief summary of available methanol and formaldehyde emissions data from neat methanol-fueled vehicles which are compared to the target levels.

Due to its high efficiency and superior durability the diesel engine is again becoming a prime candidate for future light-duty vehicle applications within the United States. While in Europe the overall diesel share exceeds 40%, the current diesel share in the U.S. is 1%. Despite the current situation and the very stringent Tier 2 emission standards, efforts are being made to introduce the diesel engine back into the U.S. market. In order to succeed, these vehicles have to comply with emissions standards over a 120,000 miles distance while maintaining their excellent fuel economy. The availability of technologies such as high-pressure common-rail fuel systems, low sulfur diesel fuel, NOx adsorber catalysts (NAC), and diesel particle filters (DPFs) allow the development of powertrain systems that have the potential to comply with the light-duty Tier 2 emission requirements. In support of this, the U.S.

A review of many years of published work has shown that hydrogen embrittlement can occur under rolling contact conditions. Breakdown of lubrication and contamination with water have been cited as the probable sources of atomic hydrogen. In this paper, a unique fracture morphology is identified and the mechanism of the fracture progression from initiation to final catastrophic failure is proposed. Development of beneficial residual compressive stress near the contacting surfaces is one approach used to avoid this type of failure. Several alternative methods capable of developing a more desirable stress distribution will be discussed.

Methylcyclopentadienylmanganese tricarbonyl (MMT) while originally marketed in the late 50's and early 60's as a secondary antiknock to leaded fuels, is presently being marketed as a primary antiknock targeted for the EPA required lead-free gasoline grade tailored for use in catalyst-equipped vehicles. This paper reviews and discusses new information related to the effect of manganese gasoline additives on the performance of catalysts, regulated emissions, and several currently unregulated emissions. In addition, estimates of human exposures to automotive-generated manganese particulate and the toxicological characteristics of manganese are discussed as they related to an assessment of the potential public health consequences should manganese additives come into widespread use. EPA's position regarding the use of manganese additives is presented and discussed.

Regulated emissions (THC, CO, NOx, and PM) and particulate SOF and sulfate fractions were determined for a 1995 Detroit Diesel Series 50 urban bus engine at varying fuel sulfur levels, with and without catalytic converters. When tested on EPA certification fuel without an oxidation catalyst this engine does not appear to meet the 1994 emissions standards for heavy duty trucks, when operating at high altitude. An ultra-low (5 ppm) sulfur diesel base stock with 23% aromatics and 42.4 cetane number was used to examine the effect of fuel sulfur. Sulfur was adjusted above the 5 ppm level to 50, 100, 200, 315 and 500 ppm using tert-butyl disulfide. Current EPA regulations limit the sulfur content to 500 ppm for on highway fuel. A low Pt diesel oxidation catalyst (DOC) was tested with all fuels and a high Pt diesel oxidation catalyst was tested with the 5 and 50 ppm sulfur fuels.

This study applies the methodology developed for two earlier evaluations of diesel particulate controls to urban buses. Since these vehicles are used almost exclusively in urban areas where population is most dense, the analysis indicates the net benefits of control are very high.

This paper discusses the systems used by the Office of Mobile Source Air Pollution Control of EPA to measure and analyze automotive sulfuric acid emissions. This system involves mixing the entire vehicle exhaust with dilution air in a dilution tunnel. Sulfuric acid samples are collected by passing a small portion of the dilute exhaust through Fluoropore filters. The sulfuric acid content of the filters is determined by an automated barium chloranilate method. This paper also discusses test results from a number of advanced prototype vehicles including two stratified charge cars, a Dresser carburetor vehicle, three dual catalyst cars, and a 3-way catalyst car.

The E-35 “Running Loss” program was planned in the fall of 1996, and conducted in the summer of 1997, as the third part of a series of Coordinating Research Council (CRC) sponsored evaporative emission test programs. One hundred and fifty vehicles (half cars - half light duty trucks) were recruited at a local I/M lane, and tested for running loss emissions at the ATL Facility in Mesa, AZ. The previous CRC programs had studied hot soak, and then diurnal emissions. Running loss emissions were measured in a Running Loss SHED (RL-SHED) for a 25 minute, 7.5 mile trip on a hot summer day (95°F). Vehicles from model years 1971 through 1991 were tested. A wide range in emission levels was observed - from a low of 0.13 g/mile to 43 g/mile. The test results were not able to establish whether car emissions are different, or the same, as light duty trucks. The major causes of the high emissions were liquid leaks on carburetor equipped models.

Hydraulic fluids of the HFC category are aqueous polymer solutions with a fire resistance enhancing water content of 35 to approx. 50 %. The use of HFC fluids, above all in mobile and stationary drives in mining and in casting is subject to restrictions resulting from a number of features of a fluid. Field practice has shown that while axial-piston pumps may be successfully operated using HFC fluids, rolling bearing failures reduce their operational lifetimes. The bearing failures essentially result from material fatigue. This can be remedied by new quality steel for roller bearings. The combination of high fatigue life and corrosion resistance assures a wide application range for nitrogen-treated steel qualities.

The application of resistive materials as part of an exhaust emission control system is presented and discussed. The importance of cold start emissions is emphasized, and results are presented from experiments conducted with two different conductive materials. Most of the testing was conducted using methanol as the fuel, although some tests were run using gasoline-fueled vehicles.

A corona discharge device (CDD) used in conjunction with automotive stoichiometric catalysts has been shown to be effective in reducing exhaust tailpipe emissions and catalytic converter light-off temperatures. The CDD used here is a low power, low cost corona discharge device mounted ahead of the catalytic converter in the exhaust stream. Creation of radicals and other oxidizing species in the exhaust by the non-thermal plasma is shown to significantly improve catalyst conversion efficiencies for HC, CO and NOx. Burner flow data shows improvement in steady-state conversion efficiencies as well as improved catalyst light-off performance. Engine-dynamometer and vehicle data on spark ignition engines using production type (stoichiometric) control also shows improved performance with aged catalysts, and various levels of fuel sulfur. The reversibility of sulfur poisoning was also observed.

This report describes in detail new test procedures designed to minimize test variability, and the resulting false failures of new technology vehicles. There are currently six promulgated test procedures. The new procedures differ from the current ones in that they include controlled preconditioning, second chance testing, and sampling and score selecting algorithms. These are intended to minimize the variability in testing conditions and thereby reduce false failures of clean vehicles. High emitting vehicles which have been escaping detection with the current test procedures may continue to do so under the new ones. It is EPA's hope that these new procedures will improve the possibility of using more stringent cutpoints and non-idle test modes in the future to detect these high emitters by eliminating the additional false failures that would otherwise occur by instituting such measures under current procedures.

In 2005, the United States Environmental Protection Agency (EPA) and Southwest Research Institute (SwRI) embarked on a mission to help the city of Beijing, China, clean its air. Working with the Beijing Environmental Protection Bureau (BEPB), the effort was a pilot diesel retrofit demonstration program involving three basic retrofit technologies to reduce particulate matter (PM). The three basic technologies were the diesel oxidation catalyst (DOC), the flowthrough diesel particulate filter (FT-DPF), and the wallflow diesel particulate filter (WF-DPF). The specific retrofit systems selected for the project were verified through the California Air Resources Board (CARB) or the EPA verification protocol [1]. These technologies are generally verified for PM reductions of 20-40 percent for DOCs, 40-50 percent for the FT-DPF, and 85 percent or more for the high efficiency WF-DPF.

The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.

Adding oxygenates to diesel fuel has shown the potential for reducing particulate (PM) emissions in the exhaust. The objective of this study was to select the most promising oxygenate compounds as blending components in diesel fuel for advanced engine testing. A fuel matrix was designed to consider the effect of molecular structure and boiling point on the ability of oxygenates to reduce engine-out exhaust emissions from a modern diesel engine. Nine test fuels including a low-sulfur (∼1 ppm), low-aromatic hydrocracked base fuel and 8 oxygenate-base fuel blends were utilized. All oxygenated fuels were formulated to contain 7% wt. of oxygen. A DaimlerChrysler OM611 CIDI engine for light-duty vehicles was controlled with a SwRI Rapid Prototyping Electronic Control System. The base fuel was evaluated in four speed-load modes and oxygenated blends only in one mode. Each operating mode and fuel combination was run in triplicate.

Simple tests were performed to investigate the operating characteristics of zirconia galvanic cells (lambda sensors) in automotive closed loop “three-way” emission control systems. Commercially available cells were exposed to typical gaseous components of exhaust gas mixtures. The voltages generated by the cells were at their maximum values when hydrogen, and, in some instances, carbon monoxide, was available for reaction with atmospheric oxygen that migrated through the cells' ceramic thimbles in ionic form. This dependence of galvanic activity on the availability of these particular reducing agents indicated that the cells were voltaic devices which operated as oxidation/reduction reaction cells, rather than simple oxygen concentration cells.

The potential discrepancy between the fuel economy shown on new vehicle labels and that achieved by consumers has been receiving increased attention of late. EPA has not modified its labeling procedures since 1985. It is likely possible that driving patterns in the U.S. have changed since that time. One possible modification to the labeling procedures is to incorporate the fuel economy measured over the emission certification tests not currently used in deriving the fuel economy label (i.e., the US06 high speed and aggressive driving test, the SC03 air conditioning test and the cold temperature test). This paper focuses on the US06 cycle and the possible incorporation of aggressive driving into the fuel economy label. As part of its development of the successor to the MOBILE emissions model, the Motor Vehicle Emission Modeling System (MOVES), EPA has developed a physically-based model of emissions and fuel consumption which accounts for different driving patterns.

The United States Environmental Protection Agency (EPA) has initiated Phase I of a regulatory program to control exhaust emissions of nonroad diesel engines over 37 kW. Central to any emissions regulation is the test procedure, which must include an appropriate test cycle. Based on actual in-use speed and estimated torque data collected from an agricultural tractor, a backhoe-loader, and a crawler tractor, three duty cycles were developed. Using an iterative process, comparison of chi-square statistical data was used to identify representative microtrips, segments of engine operation gathered during performance of selected activities. Representative microtrips for specific activities for a particular nonroad application were “strung” together to make up a test cycle. Before accepting the test cycle, data for the cycle was compared to statistical data used to characterize the raw data in an effort to validate that the cycle was representative of the raw data.

This numerical study examines the chemical-kinetics mechanism responsible for EGR NOx reduction in standard engines. Also, it investigates the feasibility of using EGR alone in hydrogen-air and methanol-air combustion to help generate and retain the same radicals previously found to be responsible for the inducement of the autoignition (in such mixtures) in IC engines with the SONEX Combustion System (SCS) piston micro-chamber. The analysis is based on a detailed chemical kinetics mechanism (for each fuel) that includes NOx production. The mechanism for H-air-NOx combustion makes use of 19 species and 58 reactions while the methanol-air-NOx mechanism is based on the use of 49 species and 227 reactions. It was earlier postulated that the combination of thermal control and charge dilution provided by the EGR produces an alteration in the combustion mechanisms (for both the hydrogen and methanol cases) that lowers peak cycle temperatures-thus greatly reducing the production of NOx.