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Negative valve overlap (NVO) is a viable control strategy that enables low-temperature gasoline combustion (LTGC) at low loads. Thermal effects of NVO fueling on main combustion are well understood, but fuel reforming chemistry during NVO has not been extensively studied. The objective of this work is to analyze the impact of global equivalence ratio and available oxidizer on NVO product concentrations. Experiments were performed in a LTGC single-cylinder engine under a sweep of NVO oxygen concentration and NVO fueling rates. Gas sampling at the start and end of the NVO period was performed via a custom dump-valve apparatus with detailed sample speciation by gas chromatography. Single-zone reactor models using detailed chemistry at relevant mixing and thermodynamic conditions were used in parallel to the experiments to evaluate expected yields of partially oxidized species under representative engine time scales.

Diesel low temperature combustion (LTC) is an operational strategy that effectively limits soot and oxides of nitrogen (NOx) emissions in-cylinder. Unfortunately, LTC results in increased hydrocarbon emissions as compared to conventional diesel combustion (CDC). Previous work has shown that exhaust conditions resulting from LTC inhibit oxidation of HC within a diesel oxidation catalyst (DOC). Further, these elevated HC emissions result in engine-out particulate matter (PM) that primarily consists of semi-volatile organic material. The current work shows that a DOC incompletely oxidizes this PM forming material. These results investigated the effectiveness of both a DOC and a diesel particulate filter (DPF) in reducing particle emissions for LTC. In this work, engine-out, DOC-out, and DPF-out exhaust were sampled using a micro-dilution system. Particle distributions were determined with a scanning mobility particle sizer (SMPS) and engine exhaust particle sizer (EEPS).

The three foundational elements that determine mobile source energy use and tailpipe carbon dioxide (CO2) emissions are the tractive energy requirements of the vehicle, the energy conversion efficiency of the propulsion system, and the energy source. The tractive energy requirements are determined by the vehicle's mass, aerodynamic drag, tire rolling resistance, and parasitic drag. The energy conversion efficiency of the propulsion system is dictated by the tractive efficiency, non-tractive energy use, kinetic energy recovery, and parasitic losses. The energy source determines the mobile source CO2 emissions. For current vehicles, tractive energy requirements and overall energy conversion efficiency are readily available from the decomposition of test data. For future applications, plausible levels of mass reduction, aerodynamic drag improvements, and tire rolling resistance can be transposed into the tractive energy domain.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.