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Engine transient operation has attracted a lot of attention from researchers due to its high frequency of occurrence during daily vehicle operation. More emissions are expected compared to steady state operating conditions as a result of the turbo-lag problem. Ambient temperature has significant influences on engine transients especially at engine start. The effects of ambient temperature on engine-out emissions under the New European Driving Cycle (NEDC) are investigated in this study. The transient engine scenarios were carried out on a modern 3.0 L, V6 turbocharged common rail diesel engine fuelled with winter diesel in a cold cell within the different ambient temperature ranging between +20 °C and −7 °C. The engine with fuel, coolant, combustion air and lubricating oil were soaked and maintained at the desired test temperatures during the transient scenarios.