Search Results

The 2007 Diesel particulate matter (DPM) standard of 0.01 g/bhp-hr represents a 90% reduction of the previous standard and corresponds to roughly 100 micrograms (μg) gained on the filter sample used to determine compliance. The factors that influence the accuracy and precision by which this filter can be weighed are analyzed and quantified. The total uncertainty, representing best and typical cases, is between 1 and 5 μg. These uncertainties are used to compute the total uncertainty of the brake specific emission calculation. This uncertainty also depends on flowrate uncertainty, face velocity, and secondary dilution ratio. For a typical case, the total fractional uncertainty is in the range of ∼5 – 70% at 10% of the standard and ∼1 – 10% at 90% of the standard.

Particulate emissions from heavy-duty buses were measured in real time under conditions encountered during the standard Central Business District (CBD) driving cycle. The buses tested were equipped with 1994 Detroit Diesel Engine Corporation 6V92-TA engines, and some included after treatment devices on the exhaust. Instantaneous, time-resolved measurements of CO2 and amorphous carbon concentrations were obtained using an optical extinction technique and compared to simultaneous results obtained using conventional dilution tunnel sampling methods. Good agreement was obtained between the real-time extinction measurements and the diluted CO2 and cycle-integrated filter measurements. The instantaneous measurements revealed that acceleration transients accounted for roughly 80% of the particulate mass emitted during the cycle but only about 45% of the fuel consumption.

Results of comparisons of computed and measured soot and NO in a direct-injection Diesel engine are presented. The computations are carried out using a three-dimensional model for flows, sprays and combustion in Diesel engines. Autoignition of the Diesel spray is modeled using an equation for a progress variable which measures the local and instantaneous tendency of the fuel to autoignite. High temperature chemistry is modeled using a local chemical equilibrium model coupled to a combination of laminar kinetic and turbulent characteristic times. Soot formation is kinetically controlled and soot oxidation is represented by a model which has a combination of laminar kinetic and turbulent mixing times. Soot oxidation appears to be controlled near top-dead-center by mixing and by kinetics as the exhaust is approached. NO is modeled using the Zeldovich mechanism.

The US Environmental Protection Agency (EPA)’s heavy duty diesel emission standard was tightened beginning from 2007 with the introduction of ultra-low-sulfur diesel fuel. Most heavy duty diesel applications were required to equip Particulate Matter (PM) after-treatment systems to meet the new tighter, emission standard. Systems utilizing Diesel Oxidation Catalyst (DOC) and Catalyzed-Diesel Particulate Filter (DPF) are a mainstream of modern diesel PM after-treatment systems. To ensure appropriate performance of the system, periodic cleaning of the PM trapped in DPF by its oxidation (a process called “regeneration”) is necessary. As a result, of this regeneration, DOC’s and DPF’s can be exposed to hundreds of thermal cycles during their lifetime. Therefore, to understand the thermo-mechanical performance of the DOC and DPF is an essential issue to evaluate the durability of the system.

Earlier work [1] shows that kinetics of Diesel soot oxidation is different from that of ethylene diffusion flame soot oxidation [2], possibly due to metals from lube oil. This study investigates the influence of metals on soot oxidation and the exhaust particle emissions using lube oil dosed fuel (2 % by volume). This method does not simulate normal lube oil consumption, but is used as a means of adding metals to particles for oxidation studies. This study also provides insight into the effect of systems that mix lube oil with fuel to minimize oil change service. The HTO-TDMA (High Temperature Oxidation-Tandem Differential Mobility Analyzer) technique [1] was used to measure the surface specific oxidation rate of Diesel particles over the temperature range 500-750 °C. Diesel particles sampled from the exhaust stream of a Diesel engine were size segregated by differential mobility and oxidized in situ in air in a heated flow tube of known residence time and temperature profile.

Particle size distribution and number concentration measurements have been made in the diluted exhaust of a medium-duty, turbocharged, aftercooled, direct-injection Diesel engine using a unique variable residence time micro-dilution system that allows systematic variation of dilution and sampling conditions, and a scanning mobility particle sizer (SMPS). The measurements show that the number concentrations in the nanoparticle (Dp < 50 nm) and the ultrafine (Dp < 100 nm) ranges are very sensitive to dilution conditions and fuel sulfur content. Changes in concentration of up to two orders of magnitude have been observed when conditions are varied over the range that might be encountered in typical laboratory dilution systems. For example, at a dilution ratio of 12, dilution temperature of 32 °C, and a residence time of 1000 ms, the number concentrations reach 6 × 108 part.

Reducing Carbon Dioxide (CO2) emissions is one of the major challenges for automobile manufacturers. This is driven by environmental, consumer, and regulatory demands in all major regions worldwide. For conventional vehicles, a host of technologies have been applied that improve the overall efficiency of the vehicle. This reduces CO2 contributions by directly reducing the amount of energy consumed to power a vehicle. The hybrid electric vehicle (HEV) continues this trend. However, there are limits to CO2 reduction due to improvements in efficiency alone. Other major improvements are realized when the CO2 content of the energy used to motivate vehicles is reduced. With the introduction of Extended Range Electric Vehicles (E-REVs) and Plug-in HEVs (PHEVs), electric grid energy displaces petroleum. This enables the potential for significant CO2 reductions as the CO2 per unit of electrical energy is reduced over time with the improving mix of energy sources for the electrical grid.

A two-dimensional optimization process which simultaneously adjusts the spark timing and air-fuel ratio of a lean-burn natural gas fueled engine has been demonstrated. This has been done by first mapping the thermal efficiency against spark timing and equivalence ratio at a single speed and load combination to obtain the 3-D surface of efficiency versus the other two variables. Then the ability of the control system to find and hold the combination of timing and air-fuel ratio which gives the highest thermal efficiency was explored. The control system described in SAE Paper No. 940546 was used to map the thermal efficiency versus equivalence ratio and ignition timing. NOx, CO, and HC maps were also obtained to determine the tradeoffs between efficiency and emissions. A load corresponding to a brake mean effective pressure of 0.467 MPa was maintained by a water brake dynamometer. A speed of 2000 rpm was maintained by a fuel-controlled governor.

In this work, engine-out particle mass (PM) and particle number (PN) emissions were experimentally examined from a gasoline direct injection (GDI) engine operating in two lean combustion modes and one stoichiometric mode with a fuel of known properties. Ten steady state operating points, two constant speed load steps, and an engine cold start were examined. Results showed that solid particles emitted from the engine under steady state stoichiometric conditions had a uniquely broad size distribution that was relatively flat between the diameters of 10 and 100 nm. In most operating conditions, lean homogenous modes can achieve lower particle emissions than stoichiometric modes while improving engine thermal efficiency. Alternatively, lean stratified operating modes resulted in significantly higher PN and PM emissions than both lean homogeneous and stoichiometric modes with increased efficiency only at low engine load.

A one-stage dilution tunnel has been developed to sample and dilute diesel exhaust. The tunnel has the capability of simulating many aspects of the atmospheric dilution process. The dilution rate and overall dilution ratio, temperature, relative humidity, and residence time in the tunnel, as well as residence time and temperature in the transfer line between the tunnel and exhaust sampling point may be varied. In this work we studied the influence of the exhaust transfer line, tunnel residence time, and dilution air temperature on the exhaust particle size distribution. The influences of fuel sulfur content on the size distribution and on the sensitivity of the size distribution to dilution and sampling conditions were also examined. We do not suggest an optimum dilution scheme, but do identify critical variables.

The effects of fuel sulfur content and dilution conditions on diesel engine PM number emissions have been researched extensively through steady state testing. Most results show that the concentration of nuclei-mode particles emitted increases with fuel sulfur content. A few studies further observed that fuel sulfur content has little effect on the emissions of heavily-used engines. It has also been found that primary dilution conditions can have a large impact on the size and number distribution of the nuclei-mode particles. These effects, however, have not yet been fully understood through transient testing, the method used by governments worldwide to certify engines and regulate emissions, and a means of experimentation which generates realistic conditions of on-road vehicles by varying the load and speed of the engine.

A system has been developed that allows near real time measurements of total, volatile, and nonvolatile particle concentrations in engine exhaust. It consists of a short section of heated catalyst, a cooling coil, and an electrical aerosol analyzer. The performance of this catalytic stripper system has been characterized with nonvolatile (NaCl), volatile sulfate ((NH4)2 SO4), and volatile hydrocarbon (engine oil) particles with diameters ranging from 0.05-0.5 μm. The operating temperature of 300°C gives essentially complete removal of volatile sulfate and hydrocarbon particles, but also leads to removal of 15-25% of solid particles. This system has been used to determine total, volatile, and nonvolatile particle concentrations in the exhaust of a Diesel engine and a spark ignition engine. Volatile volume fractions measured in Diesel exhaust with the catalytic stripper system increased from 19-65% as the equivalence ratio (load) decreased from 0.64-0.13.

In today’s highly competitive automotive environment people are always looking to develop processes that are fast, efficient, and effective. Moving testing from expensive prototype vehicles into the laboratory is an approach being implemented for many different vehicle subsystems. Specifically a process has recently been developed at General Motors that predicts exhaust back pressure performance for a running vehicle using laboratory testing and spreadsheet calculations. This paper describes the laboratory facility and procedure, the theory behind the calculations, and the correlation between vehicle test and laboratory based results. It also comments on the benefits of the process with respect to reduction in design iterations, quicker availability of results, and money savings.

The focus of this work was the physical characterization of exhaust aerosol from the University of Minnesota Formula SAE team's engine. This was done using two competition fuels, 100 octane race fuel and E85. Three engine conditions were evaluated: 6000 RPM 75% throttle, 8000 RPM 50% throttle, and 8000 RPM 100% throttle. Dilute emissions were characterized using a Scanning Mobility Particle Sizer (SMPS) and a Condensation Particle Counter (CPC). E85 fuel produced more power and had lower particulate matter emissions at all test conditions, but more fuel was consumed.

An optimum combustion chamber was designed for a reverse-tumble wall-controlled gasoline direct-injection engine by systematically optimizing each design element of the combustion system. The optimization was based on fuel-economy, hydrocarbon, combustion-stability and smoke measurements at a 2000 rev/min test-point representation of road-load operating condition. The combustion-chamber design parameters that were optimized in this study included: piston-bowl depth, piston-bowl opening width, piston-bowl-volume ratio, exhaust-side squish height, bowl-lip draft angle, distance between spark-plug electrode and piston-bowl lip, spark-plug-electrode length, and injector spray-cone angle. No attempt was made to optimize the gross engine parameters such as bore and stroke or the intake system, since this study focused on optimizing a reverse-tumble wall-controlled gasoline direct-injection variant of an existing port-fueled injection engine.

As automotive exhaust emission levels reduce, there is a need for increased sensitivity of the NOx measurement. This paper documents work performed to increase the sensitivity of the existing Rosemount NGA 2000 CLD Analyzer. The effects of sample flow rate, ozone flow rate and ozone supply gas were explored. Limit of Detection (LOD) and Converter Efficiency were evaluated. The goal of this optimization has been to provide a cost effective and expeditious method to improve the low level NOx measurement. Changing the ozone generator supply gas from air to oxygen and increasing the sample and ozone flow rates resulted in a LOD improvement from 17 ppb to 8 ppb.

Diesel engines offer better fuel economy compared to their gasoline counterpart, but simultaneous control of NOx and particulates is very challenging. The blended 2-way SCR/DPF is recently emerging as a compact and cost-effective technology to reduce NOx and particulates from diesel exhaust using a single aftertreatment device. By coating SCR catalysts on and inside the walls of the conventional wall-flow filter, the 2-way SCR/DPF eliminates the volume and mass of the conventional SCR device. Compared with the conventional diesel aftertreatment system with a SCR and a DPF, the 2-way SCR/DPF technology offers the potential of significant cost saving and packaging flexibility. In this study, an engine dynamometer test cell was set up to repeatedly load and regenerate the SCR/DPF devices to mimic catalyst aging experienced during periodic high-temperature soot regenerations in the real world.

Heat transfer to the combustion chamber walls constitutes a significant portion of the overall energy losses over the working cycle of a direct injection (DI) diesel engine. In the last few decades, numerous research efforts have been devoted to investigating the prospects of boosting efficiency by insulating the combustion chamber. Relatively few studies have focused on the prospects of reducing emissions by applying combustion chamber insulation. A main purpose of this study is to assess the potential of reducing in-cylinder soot as well as boosting aftertreatment performance by means of partially insulating the combustion chamber. Based on the findings from a conceptual study, a Low Heat Rejection (LHR) design, featuring a Nimonic 80A insert into an Aluminum piston, was developed and tested experimentally at various loads in a single-cylinder Hatz-engine.

Nanoparticle formation during exhaust sampling and dilution has been examined using a two-stage micro-dilution system to sample the exhaust from a modern, medium-duty diesel engine. Growth rates of nanoparticles at different exhaust dilution ratios and temperatures have been determined by monitoring the evolution of particle size distributions in the first stage of the dilution system. Two methods, graphical and analytical, are described to determine particle growth rate. Extrapolation of size distribution down to 1 nm in diameter has been demonstrated using the graphical method. The average growth rate of nanoparticles is calculated using the analytical method. The growth rate ranges from 6 nm/sec to 24 nm/sec, except at a dilution ratio of 40 and primary dilution temperature of 48 °C where the growth rate drops to 2 nm /sec. This condition seems to represent a threshold for growth. Observed nucleation and growth patterns are consistent with predictions of a simple physical model.

Diesel engine ash emissions are composed of the non-combustible portions of diesel particulate matter derived mainly from lube oil, and over time can degrade diesel particulate filter performance. This paper presents results from a high temperature oxidation method (HTOM) used to estimate ash emissions, and engine oil consumption in real-time. Atomized lubrication oil and diesel engine exhaust were used to evaluate the HTOM performance. Atomized fresh and used lube oil experiments showed that the HTOM reached stable particle size distributions and concentrations at temperatures above 700°C. The HTOM produced very similar number and volume weighted particle size distributions for both types of lube oils. The particle number size distribution was unimodal, with a geometric mean diameter of about 23 nm. The volume size distribution had a geometric volume mean diameter of about 65 nm.