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Schlieren and shadowgraph imaging have been used for many years to identify refractive index gradients in various applications. For evaporating fuel sprays, these techniques can differentiate the boundary between spray regions and background ambient gases. Valuable information such as the penetration rate, spreading angle, spray structure, and spray pattern can be obtained using schlieren diagnostics. In this study, we present details of a z-type schlieren system setup and its application to port-fuel-injection gasoline sprays. The schlieren high-speed movies were used to obtain time histories of the spray penetration and spreading angle. Later, these global parameters were compared to specifications provided by the injector manufacturer. Also, diagnostic parameters such as the proportion of light cut-off at the focal point and the orientation of knife-edge (schlieren-stop) used to achieve the cut-off were examined.

Single droplet theory is used to simulate the behavior of fuel sprays in high-speed open-chamber diesels. A model for sprays in still air is presented which includes the air motion induced by the spray. Calculated paths and vaporization histories for droplets injected into swirling air are also presented. It is shown that the paths of vaporizing drops are closely approximated by solid sphere calculations. The effects of swirl speed, engine rpm, and squish air motion are also investigated.

For a better understanding of soot formation and oxidation processes in conventional diesel and biodiesel spray flames, the morphology, microstructure and sizes of soot particles directly sampled in spray flames fuelled with US#2 diesel and soy-methyl ester were investigated using transmission electron microscopy (TEM). The soot samples were taken at 50mm from the injector nozzle, which corresponds to the peak soot location in the spray flames. The spray flames were generated in a constant-volume combustion chamber under a diesel-like high pressure and high temperature condition (6.7MPa, 1000K). Direct sampling permits a more direct assessment of soot as it is formed and oxidized in the flame, as opposed to exhaust PM measurements. Density of sampled soot particles, diameter of primary particles, size (gyration radius) and compactness (fractal dimension) of soot aggregates were analyzed and compared. No analysis of the soot micro-structure was made.

Developing relatively cheap and widely available resources for heterogeneous solid catalyst synthesis is a promising approach for biodiesel fuel industry. Seashell which is essentially calcium carbonate can be used as a basic support for transesterification heterogeneous catalysts. In the present investigation, the alcoholysis of waste frying oil has been carried out using seashell-supported K₃PO₄ as solid catalyst. The rationale for this derives from the fact that waste frying oil contains both long-chain free fatty acids (FFA) and triglycerides (TG) which are catalyzed on acid and basic sites respectively. Thus, the K₃PO₄/seashell catalyst may serve the dual role of promoting both esterification and transesterification reactions. The catalyst was synthesized following a dipping impregnation of pre-crushed and calcined seashell in an aqueous solution of K₃PO₄. Samples with different percentage loadings of K₃PO₄ (5 to 25 wt%) were prepared.

A detailed description of a numerical method for computing unsteady flows in engine intake and exhaust systems is given. The calculations include the effects of heat transfer and friction. The inclusion of such calculations in a mathematically simulated engine cycle is discussed and results shown for several systems. In particular, the effects of bell-mouth versus plain pipe terminations and the effects of a finite surge tank are calculated. Experimental data on the effect of heat transfer from the back of the intake valve on wave damping are given and show the effect to be negligible. Experimental data on wave damping during the valve closed period and on the temperature rise of the air near the valve are also given.

This paper describes a method for studying reactions of hydrocarbons in S.I. engine exhaust gases. The reaction of ethane is described using an Arrhenius model (experimentally E = 86,500 cal/mole) for the rate of ethane diappearance and empirical correlations for distributions of the products carbon monoxide, ethylene, formaldehyde, methane, acetylene, and propane as a function of the fraction of ethane reacted. The results show that the nature of partial oxidation products from a nonreactive hydrocarbon may be less desirable from an air pollution viewpoint than the initial hydrocarbon.

The ratio of two temperature gradients across the combustion-chamber wall in a diesel engine is used to provide a heat flow ratio showing the radiant heat transfer as a per cent of local total heat transfer. The temperature gradients were obtained with a thermocouple junction on each side of the combustion-chamber wall. The first temperature gradient was obtained by covering the thermocouple at the cylinder gas-wall interface with a thin sapphire window, while the second was obtained without the window. Results show that the time-average radiant heat transfer is of significant magnitude in a diesel engine, and is probably even more significant in heat transfer during combustion and expansion.

Simultaneous two-component measurements of gas velocity and multi-dimensional numerical simulation are employed to characterize the evolution of the in-cylinder turbulent flow structure in a re-entrant bowl-in-piston engine under motored operation. The evolution of the mean flow field, turbulence energy, turbulent length scales, and the various terms contributing to the production of the turbulence energy are correlated and compared, with the objectives of clarifying the physical mechanisms and flow structures that dominate the turbulence production and of identifying the source of discrepancies between the measured and simulated turbulence fields. Additionally, the applicability of the linear turbulent stress modeling hypothesis employed in the k-ε model is assessed using the experimental mean flow gradients, turbulence energy, and length scales.

Engine experiments were conducted on a heavy-duty single-cylinder engine to explore the effects of charge preparation, fuel stratification, and premixed fuel chemistry on the performance and emissions of Reactivity Controlled Compression Ignition (RCCI) combustion. The experiments were conducted at a fixed total fuel energy and engine speed, and charge preparation was varied by adjusting the global equivalence ratio between 0.28 and 0.35 at intake temperatures of 40°C and 60°C. With a premixed injection of isooctane (PRF100), and a single direct-injection of n-heptane (PRF0), fuel stratification was varied with start of injection (SOI) timing. Combustion phasing advanced as SOI was retarded between -140° and -35°, then retarded as injection timing was further retarded, indicating a potential shift in combustion regime. Peak gross efficiency was achieved between -60° and -45° SOI, and NOx emissions increased as SOI was retarded beyond -40°, peaking around -25° SOI.

This study looks at the application of a titanium dioxide (TiO2) catalytic nanoparticle suspension to the surface of the combustion chamber as a coating, as well as the addition of hydrogen gas to a four-stroke spark-ignited carbureted engine as a possible technique for lowering engine-out emissions. The experiments were conducted on two identical Generac gasoline powered generators using two, four and six halogen work lamps to load the engine. One generator was used as a control and the second had key components of the combustion chamber coated with the catalytic suspension. In addition to the coating, both engines were fed a hydrogen and oxygen gas mixture and tested at low, medium and high loads. Using an unmodified engine as a control set, the following three conditions were tested and compared: addition of hydrogen only, addition of coating only, and addition of hydrogen to the coated engine.

The objective of this research was to investigate the effect of injection pressure on air entrainment into transient diesel sprays. The main application of interest was the direct injection diesel engine. Particle Image Velocimetry was used to make measurements of the air entrainment velocities into a spray plume as a function of time and space. A hydraulically actuated, electronically controlled unit injector (HEUI) system was used to supply the fuel into a pressurized spray chamber. The gas chamber density was maintained at 27 kg/m3. The injection pressures that were studied in this current research project were 117.6 MPa and 132.3 MPa. For different injection pressures, during the initial two-thirds of the spray plume there was little difference in the velocities normal to the spray surface. For the last third of the spray plume, the normal velocities were 125% higher for the high injection pressure case.

A correlation was developed to predict the ignition delay of PRF blends at a wide range of engine-relevant operating conditions. Constant volume simulations were performed using Cantera coupled with a reduced reaction mechanism at a range of initial temperatures from 570-1860K, initial pressures from 10-100atm, oxygen mole percent from 12.6% to 21%, equivalence ratios from 0.30-1.5, and PRF blends from PRF0 to PRF100. In total, 6,480 independent ignition delay simulations were performed. The correlation utilizes the traditional Arrhenius formulation; with equivalence ratio (φ), pressure (p), and oxygen mole percentage (xo2) dependencies. The exponents α, β, and γ were fitted to a third order polynomial with respect to temperature with an exponential roll-off to a constant value at low temperatures to capture the behavior expressed by the reaction mechanism. The location and rate of the roll-off functions were modified by linear functions of PRF.

DATA presented in this paper show temperature-time diagrams obtained from mufflers mounted on trucks which were traveling over their regular routes. Using these temperature data, specimens made of possible muffler materials were subjected to laboratory tests. A wide range of possible muffler materials and gas composition were covered in these tests. Results of the tests indicate that under long-run heavy-duty truck service, muffler failure occurs primarily because of high metal temperatures and that coated mild steel showed the most promise of longer muffler life.

Diesel fuels are complex mixtures of thousands of hydrocarbons. Since modeling their combustion characteristics with the inclusion of all hydrocarbon species is not feasible, a hybrid surrogate model approach is used in the present work to represent the physical and chemical properties of three different diesel fuels by using up to 13 and 4 separate hydrocarbon species, respectively. The surrogates are arrived at by matching their distillation profiles and important properties with the real fuel, while the chemistry surrogates are arrived at by using a Group Chemistry Representation (GCR) method wherein the hydrocarbon species in the physical property surrogates are grouped based on their chemical classes, and the chemistry of each class is represented by using up to two hydrocarbon species.

The purpose of the tests conducted on a single-cylinder laboratory engine was to determine the mechanism of combustion that affect exhaust emissions and the relationship of those mechanisms to engine design and operating variables. For the engine used in this study, the exhaust emissions were found to have the following dependence on various engine variables. Hydrocarbon emission was reduced by lean operation, increased manifold pressure, retarded spark, increased exhaust temperature, increased coolant temperature, increased exhaust back pressure, and decreased compression ratio. Carbon monoxide emission was affected by air-fuel ratio and premixing the charge. Oxides of nitrogen (NO + NO2 is called NOx) emission is primarily a function of the O2 available and the peak temperature attained during the cycle. Decreased manifold pressure and retarded spark decrease NOx emission. Hydrocarbons were found to react to some extent in the exhaust port and exhaust system.

Future fuels will come from a variety of feed stocks and refinement processes. Understanding the fundamentals of combustion and pollutants formation of these fuels will help clear hurdles in developing flex-fuel combustors. To this end, we investigated the combustion, soot formation, and soot oxidation processes for various classes of fuels, each with distinct physical properties and molecular structures. The fuels considered include: conventional No. 2 diesel (D2), low-aromatics jet fuel (JC), world-average jet fuel (JW), Fischer-Tropsch synthetic fuel (JS), coal-derived fuel (JP), and a two-component surrogate fuel (SR). Fuel sprays were injected into high-temperature, high-pressure ambient conditions that were representative of a practical diesel engine. Simultaneous laser extinction measurement and planar laser-induced incandescence imaging were performed to derive the in-situ soot volume fraction.

Numerical simulations of soot formation were performed for n-dodecane spray using the transported probability density function (TPDF) method. Liquid n-dodecane was injected with 1500 bar fuel pressure into a constant-volume vessel with an ambient temperature, oxygen volume fraction and density of 900 K, 15% and 22.8 kg/m3, respectively. The interaction by exchange with the mean (IEM) model was employed to close the micro-mixing term. The unsteady Reynolds-averaged Navier-Stokes (RANS) equations coupled with the realizable k-ε turbulence model were used to provide turbulence information to the TPDF solver. A 53-species reduced n-dodecane chemical mechanism was employed to evaluate the reaction rates. Soot formation was modelled with an acetylene-based two-equation model which accounts for simultaneous soot particle inception, surface growth, coagulation and oxidation by O2 and OH.

A detailed mathematical model of the thermodynamic events of a crankcase scavenged, two-stroke, SI engine is described. The engine is divided into three thermodynamic systems: the cylinder gases, the crankcase gases, and the inlet system gases. Energy balances, mass continuity equations, the ideal gas law, and thermodynamic property relationships are combined to give a set of coupled ordinary differential equations which describe the thermodynamic states encountered by the systems of the engine during one cycle of operation. A computer program is used to integrate the equations, starting with estimated initial thermodynamic conditions and estimated metal surface temperatures. The program iterates the cycle, adjusting the initial estimates, until the final conditions agree with the beginning conditions, that is, until a cycle results.

In this work computational and experimental approaches are combined to characterize in-cylinder flow structures and local flow field properties during operation of the Sandia 1.9L light-duty optical Diesel engine. A full computational model of the single-cylinder research engine was used that considers the complete intake and exhaust runners and plenums, as well as the adjustable throttling devices used in the experiments to obtain different swirl ratios. The in-cylinder flow predictions were validated against an extensive set of planar PIV measurements at different vertical locations in the combustion chamber for different swirl ratio configurations. Principal Component Analysis was used to characterize precession, tilting and eccentricity, and regional averages of the in-cylinder turbulence properties in the squish region and the piston bowl.

Highly time resolved measurements of cylinder pressure acquired simultaneously from three transducers were used to investigate the nature of knocking combustion and to identify biases that the pressure measurements induce. It was shown by investigating the magnitude squared coherence (MSC) between the transducer signals that frequency content above approximately 40 kHz does not originate from a common source, i.e., it originates from noise sources. The major source of noise at higher frequency is the natural frequency of the transducer that is excited by the impulsive knock event; even if the natural frequency is above the sampling frequency it can affect the measurements by aliasing. The MSC analysis suggests that 40 kHz is the appropriate cutoff frequency for low-pass filtering the pressure signal. Knowing this, one can isolate the knock event from noise more accurately.