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In studying H2S emissions, it is desirable to have an analytical technique which is rapid, continuous, accurate and easy to use in a laboratory or vehicle exhaust environment. Typically, H2S has been measured using the EPA impinger method with collection times on the order of 1 to 2 minutes. Other techniques have been developed with significantly shorter response times. However, it has been shown that the major release of H2S occurs in less than 20 seconds after a vehicle changes from rich to lean operation. Therefore, it is highly desirable to have an H2S analytical technique with a response time of less than 10 seconds. In this paper, the benefits of use of a chemical ionization mass spectrometer (CIMS) to continuously monitor H2S and SO2, emissions are reported. Using the CIMS technique, the effects of several operating parameters on the release of H2S and SO2 from automotive catalysts were studied.

For the BMW V8 engine, a new LEV/EU3 emission concept has been developed by improvements to the previous engine management and secondary air supply and a complete new exhaust system. Beside the emission limits, also high engine output targets and high operating reliability were targeted. In addition the new exhaust system had to meet low cost targets. Based on these requirements an exhaust concept with separate pre catalyst and main catalyst was chosen. To reduce the heat mass and to optimize the pressure drop, 4.3mil/400cpsi thin wall ceramic substrates were used for the pre and main catalyst.

To meet LEV and EU Stage III emission requirements, it is necessary for new catalytic converters to be designed which exceed light-off temperature as quickly as possible. The technical solutions are secondary air injection, active heating systems such as the electrically heated catalytic converter, and the close coupled catalytic converter. Engine control functions are extensively used to heat the converter and will to play a significant role in the future. The concept of relocating the converter to a position close to the engine in an existing vehicle involves new conflicts. Examples include the space requirements, the thermal resistance of the catalytic coating and high temperature loads in the engine compartment.

In a joint research project between industrial companies and a number of research institutes, nitrogen oxide conversion in oxygen containing exhaust gas has been investigated according to the following procedure Basic investigations of elementary steps of the chemical reaction Production and prescreening of different catalytic material on laboratory scale Application oriented screening of industrial catalyst material Catalyst testing on a lean bum gasoline engine, passenger car diesel engines (swirl chamber and DI) and on a DI truck engine Although a number of solid body structures show nitrogen oxide reduction by hydrocarbons, only noble metal containing catalysts and transition metal exchanged zeolites gave catalytic efficiencies of industrial relevance. A maximum of 25 % NOx reduction was found in the European driving cycle for passenger cars, about 40 % for truck engines in the respective European test.

Longitudinal models are used to evaluate different vehicle-engine concepts with respect to driving behavior and emissions. The engine is generally map-based. An explicit calculation of both fluid dynamics inside the engine air path and cylinder combustion is not considered due to long computing times. Particularly for dynamic certification cycles (WLTC, US06 etc.), dynamic engine effects severely influence the quality of results. Hence, an evaluation of transient engine behavior with map-based engine models is restricted to a certain extent. The coupling of detailed 1D-engine models is an alternative, which rapidly increases the model computation time to approximately 300 times higher than that of real time. In many technical areas, the Fourier transformation (FT) method is applied, which makes it possible to represent superimposed oscillations by their sinusoidal harmonic oscillations of different orders.

For the NOx removal from diesel exhaust, the selective catalytic reduction (SCR) and lean NOx traps are established technologies. However, these procedures lack efficiency below 200 °C, which is of importance for city driving and cold start phases. Thus, the present paper deals with the development of a novel low-temperature deNOx strategy implying the catalytic NOx reduction by hydrogen. For the investigations, a highly active H2-deNOx catalyst, originally engineered for lean H2 combustion engines, was employed. This Pt-based catalyst reached peak NOx conversion of 95 % in synthetic diesel exhaust with N2 selectivities up to 80 %. Additionally, driving cycle tests on a diesel engine test bench were also performed to evaluate the H2-deNOx performance under practical conditions. For this purpose, a diesel oxidation catalyst, a diesel particulate filter and a H2 injection nozzle with mixing unit were placed upstream to the full size H2-deNOx catalyst.

Cars cause a lot of pollutants during the utilization phase. Within the last years environmental legislation tried to reduce the emissions by the introduction of very tight laws. The results are impressive: Most of the car exhaust emissions like carbonmonoxid and nitrous oxides have been reduced. At this stage new emission reduction limits in Europe as well as in the United States can only be achieved if the formulation of the catalyst system is significantly changed. An increased use of precious metals and rare earth materials is the result of such a modification which succeeds in a more expensive design of the total catalyst systems. More expensive means not only cost aspects but also the environmental burdens related to the increased production of precious metals and other catalyst components. The Life Cycle Engineering (LCE) of the catalyst system which achieves the new legislation is demonstrated as well as the effects to the usage phase.

There is a growing need for low-emissions concepts due to stricter emission regulations, more stringent homologation cycles, and the possibility of a ban on new engines by 2035. Of particular concern are the conditions during a cold start, when the Three-Way Catalyst is not yet heated to its light-off temperature. During this period, the catalyst remains inactive, thereby failing to convert pollutants. Reducing the time needed to reach this temperature is crucial to comply with the more stringent emissions standards. The post oxidation by means of secondary air injection, illustrated in this work, is a possible solution to reduce the time needed to reach the above-mentioned temperature. The strategy consists of injecting air into the exhaust manifold via secondary air injectors to oxidize unburned fuel that comes from a rich combustion within the cylinder.

Apart from the reduction of engine-out emissions from the powerplant, the development of an efficient and reliable catalytic converter heating system is an important task of automotive engineering in the future to meet standards that will require reduction of cold start emissions. Carrying out a comprehensive study in this field, BMW has tested and evaluated possible solutions to this challenge. In additon to the electrically heated catalytic converter (E-cat) and the afterburner chamber, an incorporated burner system would meet the requirement for fast catalyst light-off in the future, particularly in the case of larger engines.

The use of gas springs with a surge tank to generate blank holding forces in drawing tools is increasing. These gas spring systems are characterized by an almost constant behaviour of the spring force over the spring displacement. To prevent an increase of the normal pressure with increasing stroke in a drawing process, it is advantageous to obtain a degressive force-displacement behaviour of the gas springs. For this reason, a gas spring system was developed to realize a decrease of the blank holding forces over the stroke without large additional expenditure. The technical realization takes place in an exact controlling of the upper and lower pressure chamber of the nitrogen cylinder.

The production of the BMW ALPINA B12 5.7 with Switch-Tronic transmission provides the markets of Europe and Japan with an exclusive, luxury-orientated, high performance limited series limousine. This is the first vehicle worldwide to be fitted with the progressive exhaust gas aftertreatment technology known as the Electrically Heated Catalyst (EHC), in which the effectiveness of the power utilized is increased significantly by an alternating heating process for both catalytic converters. Only since this achievement has the implementation of the EHC been viable without extensive modification to the battery and alternator. With this exhaust gas aftertreatment concept, the emissions of this high performance vehicle will fall to less than half the maximum permissible for compliance with 1996 emission standards.

Fast and exact measurement of engine oil consumption is a very difficult task. Our aim is to achieve this measurement at a common test bed without engine modifications. We resolved this problem with a new technique using Laser Mass Spectrometry to detect appropriate tracers in the raw engine exhaust. The tracers are added to the engine oil. to the engine oil. For detection of these tracers we use a Laser Mass Spectrometer (LAMS). This is a combination of resonant laser ionization (with an all-solid-state laser) and Time-of-Flight Mass Spectrometry. Currently this is the only way to detect oil originated molecules (like our tracers) in the raw exhaust very fast (50 Hz) and sensitive (ppb-region). Thus, engine mapping of oil consumption over load and speed can be performed in 1-2 days with about 90 measurements. Even measurement during dynamic engine operation is possible, but not quantitative (due to the lack of information about dynamic exhaust gas mass flow).

Air charge calibration of turbocharged SI gasoline engines with both variable inlet valve lift and variable inlet and exhaust valve opening angle has to be very accurate and needs a high number of measurements. In particular, the modeling of the transition area from unthrottled, inlet valve controlled resp. throttled mode to turbocharged mode, suffers from small number of measurements (e.g. when applying Design of Experiments (DoE)). This is due to the strong impact of residual gas respectively scavenging dominating locally in this area. In this article, a virtual residual gas sensor in order to enable black-box-modeling of the air charge is presented. The sensor is a multilayer perceptron artificial neural network. Amongst others, the physically calculated air mass is used as training data for the artificial neural network.

External Exhaust Gas Recirculation (EGR) provides an opportunity to increase the efficiency of turbocharged spark-ignition engines. Of the competing technologies and configurations, Low-Pressure EGR (LP-EGR) is the most challenging in terms of its dynamic behavior. Only some of the stationary feasible potential can be used during dynamic engine operation. To guarantee fuel consumption-optimized engine operation with no instabilities, a load point-dependent limitation of the EGR rate or alternatively an adaptation of the operating point to the actual EGR rate is crucial. For this purpose, a precise knowledge of efficiency and combustion variance is necessary. Since the operating state includes the actual EGR rate, it has an additional dimension, which usually results in an immense measuring effort.