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Technical Paper

A Comparative Study of New Magnesium Alloys Developed for Elevated Temperature Applications in Automotive Industry

2003-03-03
2003-01-0191
Recently several new magnesium alloys for high temperature applications have been developed with the aim to obtain an optimal combination of die castability, creep resistance, mechanical properties, corrosion performance and affordable cost. Unfortunately, it is very difficult to achieve an adequate combination of properties and in fact, most of the new alloys can only partially meet the required performance and cost. This paper aims at evaluating the current status of the newly developed alloys for powertrain applications. The paper also addresses the complexity of magnesium alloy development and illustrates the effect of alloying elements on properties and cost. In addition, the paper presents an attempt to set the position of each alloy in the integrated space of combined properties and cost
Technical Paper

A New Generation of Diesel Oxidation Catalysts

1992-10-01
922330
An overview is given on the state of the art of a new catalytic exhaust gas aftertreatment device for diesel engines. The function of a precious metal based, flow-through type diesel oxidation catalyst is explained. Much attention is paid to the durability of the diesel oxidation catalyst and especially to the influence of poisoning elements on the catalytic activity. Detailed data on the interaction of poisoning elements such as sulfur, zinc and phosphorus with the catalytic active sites are given. Finally it is demonstrated that it is possible to meet the stringent emission standards for diesel passenger cars in Europe with a new catalyst generation over 80.000 km AMA aging.
Technical Paper

A PDF-Based Model for Full Cycle Simulation of Direct Injected Engines

2008-06-23
2008-01-1606
In one-dimensional engine simulation programs the simulation of engine performance is mostly done by parameter fitting in order to match simulations with experimental data. The extensive fitting procedure is especially needed for emissions formation - CO, HC, NO, soot - simulations. An alternative to this approach is, to calculate the emissions based on detailed kinetic models. This however demands that the in-cylinder combustion-flow interaction can be modeled accurately, and that the CPU time needed for the model is still acceptable. PDF based stochastic reactor models offer one possible solution. They usually introduce only one (time dependent) parameter - the mixing time - to model the influence of flow on the chemistry. They offer the prediction of the heat release, together with all emission formation, if the optimum mixing time is given.
Technical Paper

A Study of the Thermochemical Conditions in the Exhaust Manifold Using Secondary Air in a 2.0 L Engine

2002-05-06
2002-01-1676
The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.
Journal Article

Analysis of Cycle-to-Cycle Variations of the Mixing Process in a Direct Injection Spark Ignition Engine Using Scale-Resolving Simulations

2016-11-16
2016-01-9048
Since the mechanisms leading to cyclic combustion variabilities in direct injection gasoline engines are still poorly understood, advanced computational studies are necessary to be able to predict, analyze and optimize the complete engine process from aerodynamics to mixing, ignition, combustion and heat transfer. In this work the Scale-Adaptive Simulation (SAS) turbulence model is used in combination with a parameterized lagrangian spray model for the purpose of predicting transient in-cylinder cold flow, injection and mixture formation in a gasoline engine. An existing CFD model based on FLUENT v15.0 [1] has been extended with a spray description using the FLUENT Discrete Phase Model (DPM). This article will first discuss the validation of the in-cylinder cold flow model using experimental data measured within an optically accessible engine by High Speed Particle Image Velocimetry (HS-PIV).
Technical Paper

Benefits of GTL Fuel in Vehicles Equipped with Diesel Particulate Filters

2009-06-15
2009-01-1934
Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.
Technical Paper

Catalytic NOx Reduction in Net Oxidizing Exhaust Gas

1990-02-01
900496
Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.
Technical Paper

Code Coupling, a New Approach to Enhance CFD Analysis of Engines

2000-03-06
2000-01-0660
A new method for the analysis of the gas flow in an internal combustion engine has been developed. It is based on the interactive coupling between commercially available three (STAR-CD) and one dimensional (PROMO) fluid dynamics codes. With this method the detailed transient flow distribution for any engine component of interest can be calculated taking into account the overall gas dynamic interaction with other engine components. The underlying physics and numerics are outlined. A description of the coupling procedure ensuring proper communication between the two computer codes is given. Also addressed is the averaging procedure adopted at the 3D boundaries, including the influence of the 1D/3D interface placement. A first application of this new method is presented, in which the gas flow in a turbo-charged DI-diesel-engine is simulated.
Technical Paper

Crank-Angle Resolved Temperature in SI Engines Measured by Emission-Absorption Spectroscopy

1999-10-25
1999-01-3542
Crank-angle resolved, gas temperatures are determined in the combustion chamber of a Volkswagen (VW) standard-production, port-injected SI engine. During idle, two different methods are applied: (1) a direct spectroscopic emission-absorption technique at a resonance line of potassium, seeded to the air stream to generate sufficient spectral absorptance (‘colouring’ technique), and (2) a more standard, indirect method in which temperatures are derived from pressure recordings using a two-zone thermodynamic model. Combustion temperatures obtained during idle with both the spectroscopic (1) and ‘two-zone’ (2) methods are in good agreement. In addition, the spectroscopic technique is extended to transient operating conditions where the ‘two-zone’ method is not applicable. Combustion temperatures measured during cold-start and abrupt load alteration are in good agreement with former investigations.
Journal Article

Development and Demonstration of LNT+SCR System for Passenger Car Diesel Applications

2014-04-01
2014-01-1537
The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.
Technical Paper

Effect of Cell Geometry on Emissions Performance of Ceramic Catalytic Converters

2002-03-04
2002-01-0354
More stringent emissions regulations, space limitations for catalytic converters in modern automotive applications, and new engine technologies constitute design challenges for today's engineers. In that context high cell density thinwall and ultrathinwall ceramic substrates have been designed into advanced catalytic converters. Whereas the majority of these substrates have a square cell geometry, a potential for further emissions improvement has been predicted for hexagonal cell structures. In order to verify these predictions, a ceramic substrate has been developed combining the features of high cell density, ultrathin cell walls, and hexagonal cell structure. Based on modeling data, the actual cell density and wall thickness of the hexagonal cell substrate will be defined. The performance of that substrate will be assessed by comparing experimental emissions results using two modern Volkswagen engines.
Technical Paper

Effect of HPDC Parameters on the Performance of Creep Resistant Alloys MRI153M and MRI230D

2005-04-11
2005-01-0334
The growing demand for the use of magnesium alloys in the production of automotive powertrain components led to the development of creep resistant diecasting alloys MRI153M and MRI230D. The present paper addresses the main high-pressure die casting parameters, which significantly affect the performance of components, produced of these new alloys. A systematic study was carried out in order to correlate die-casting parameters to the performance of new alloys. The results obtained clearly indicated that optimization of molten metal and die temperatures, injection profile parameters and lubrication mixtures allowed to improve the die castability and service properties of the new alloys and produce high performance components with intricate geometry. This was manifested by production of several practical demonstrators such as gearboxes, oil pans, oil pumps and crankcases.
Technical Paper

Engine-Independent Exhaust Gas Aftertreatment Using a Burner Heated Catalyst

2006-10-16
2006-01-3401
Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.
Technical Paper

European Diesel Research IDEA-Experimental Results from DI Diesel Engine Investigations

1994-10-01
941954
Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.
Technical Paper

Evaluation of an UV-Analyzer for the Simultaneous NO and NO2 Vehicle Emission Measurement

2004-06-08
2004-01-1830
For the measurement of NO and NO2 the CLD-analyzer (chemiluminescense detector) has been used for more than twenty-five years. The disadvantage of the CLD is that NO can be measured only. To obtain total NOX (NO+NO2) the exhaust gas sample has to flow through a catalytic converter, which reduces NO2 to NO. The converter has a efficiency between 90 and 100%. For precise NO and NO2 values it is an advantage to analyze NO and NO2 directly. This paper describes a new UV NOX-analyzer for the simultaneous measurement of NO and NO2. Two different configurations, for high and low concentrations, eg. CVS-bag analysis are presented. The performance of the analyzers is documented in comparison to the UV-RAS analyzer with converter for NOX [1] and the conventional CLD-analyzer. The benefits of the new analyzer compared to analyzers equipped with a converter are given in detailed test results.
Technical Paper

Exhaust Gas Aftertreatment of Volkswagen FSI Fuel Stratified Injection Engines

2002-03-04
2002-01-0346
For substantial reduction of fuel consumption of their vehicle fleet, Volkswagen AG has decided to develop spark-ignition engines with direct fuel injection. To launch this new engine concept with stratified lean operation mode while at the same time meeting the stringent EU IV emission standards, it was necessary to develop a suitable exhaust gas aftertreatment system. This was achieved as part of an intensive co-operation between Volkswagen AG and OMG, formerly dmc2 Degussa Metals Catalysts Cerdec AG. The paper describes the demands for exhaust gas aftertreatment due to lean burn operation. In addition the main development steps of the exhaust gas aftertreatment system for Volkswagen FSI engines and catalyst durability over vehicle lifetime are discussed. Focus is laid on the catalyst system design and coating variations. Volkswagen developed a new closed-loop emission control management system which uses NOx-sensor signals for the first time worldwide.
Technical Paper

Experimental and Numerical Analysis of Pre-Chamber Combustion Systems for Lean Burn Gas Engines

2019-04-02
2019-01-0260
The current trend in automobiles is towards electrical vehicles, but for the most part these vehicles still require an internal combustion engine to provide additional range and flexibility. These engines are under stringent emissions regulations, in particular, for the reduction of CO2. Gas engines which run lean burn combustion systems provide a viable route to these emission reductions, however designing these engines to provide sustainable and controlled combustion under lean conditions at λ=2.0 is challenging. To address this challenge, it is possible to use a scavenged Pre-Chamber Ignition (PCI) system which can deliver favorable conditions for ignition close to the spark plug. The lean charge in the main combustion chamber is then ignited by flame jets emanating from the pre-chamber nozzles. Accurate prediction of flame kernel development and propagation is essential for the analysis of PCI systems.
Technical Paper

Fuel/Air-Ratio Measurements in Direct Injection Gasoline Sprays Using 1D Raman Scattering

2000-03-06
2000-01-0244
One dimensional Spontaneous Raman Scattering measurements (RS) have been performed in a spray (standard gasoline, one-component and multi-component model fuels) which was operated in a high-temperature, high-pressure chamber, so that realistic engine conditions have been simulated. The present work investigates under what conditions 1D-RS can be employed for fuel/air-ratio measurements in realistic DI gasoline sprays. The distance from the spray axis has been determined, til that, coming from the outside, quantitative Raman measurement are possible. The equivalence ratio has been quantified for the one component fuel close to the spray. It turns out that the measurement error depends strongly on the type of fuel. These problems are caused by the PAH (polycyclic aromatic hydrocarbon) content of the fuel, which leads to interfering laser-induced fluorescence signals.
Technical Paper

High Temperature Mg Alloys for Sand and Permanent Mold Casting Applications

2004-03-08
2004-01-0656
The need to reduce weight of large and heavy components used by the automotive and aerospace industries such as engine block, cylinder head cover and helicopter gearbox housing has led to the development of new Mg gravity casting alloys that provide adequate properties and cost effective solution. The new Mg gravity casting alloys are designed for high stressed components that operate at a temperature up to 300°C. These new alloys exhibit excellent mechanical properties and creep resistance in T-6 conditions. The present paper aims at introducing three new Mg gravity casting alloys designated MRI 201S, MRI 202S and MRI 203S, which were recently developed by the Magnesium Research Institute of DSM and VW. Apart from the excellent high temperature performance of these alloys, they provide adequate castability and dimension stability along with good weldability and corrosion resistance.
Technical Paper

Impact of Sulfur in Gasoline on Nitrous Oxide and Other Exhaust Gas Components

2000-03-06
2000-01-0857
Sulfur content in gasoline is known to reduce the efficiency of the catalytic converters that are used to reduce pollutants in the exhaust gas of cars. There is some concern that nitrous oxide emissions (N2O) increase when fuel with a high sulfur content is used. The engine out and tailpipe mass emissions of two cars conforming to the California LEV-standard were analyzed. The influence of the fuel sulfur content on the emissions of the regulated and some unregulated pollutants during FTP test cycles was determined. Four fuels covering the range from less than 1 to 330 ppm sulfur content were used. Over that range of fuel sulfur concentration the engine out emissions of sulfur dioxide (SO2 ) of both cars increased. Tailpipe emissions of SO2 were only found at fuel sulfur concentrations of 150 and 330 ppm. For both vehicles a correlation between the N2O emissions and the fuel sulfur content was found.
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