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Simulations using CFD and chemical kinetics models have been applied to gain a better understanding of the effect of the recirculated gases on the autoignition process during cold starting of a direct injection diesel engine. The cranking gases recirculated (CGR) contain fuel vapor and partial oxidation products which affect the autoignition process in different ways. Some hydrocarbons (HCs) species enhance the reaction rates and reduce ignition delay. Meanwhile other HCs species and the partial oxidation products of the autoignition process have an opposing effect. The simulation covered a wide range of the hydrocarbons and aldehydes concentrations and their effect on the ignition delay in a 1.2L Ford DIATA 4-cylinders, water cooled, turbocharged and intercooled diesel engine. The simulated opposing effects of HCs and HCHO on the ignition delay are validated by experimental results at room temperature.

Surrogates for JP-8 have been developed in the high temperature gas phase environment of gas turbines. In diesel engines, the fuel is introduced in the liquid phase where volatility plays a major role in the formation of the combustible mixture and autoignition reactions that occur at relatively lower temperatures. In this paper, the role of volatility on the combustion of JP-8 and five different surrogate fuels was investigated in the constant volume combustion chamber of the Ignition Quality Tester (IQT). IQT is used to determine the derived cetane number (DCN) of diesel engine fuels according to ASTM D6890. The surrogate fuels were formulated such that their DCNs matched that of JP-8, but with different volatilities. Tests were conducted to investigate the effect of volatility on the autoignition and combustion characteristics of the surrogates using a detailed analysis of the rate of heat release immediately after the start of injection.