Technical Paper
Vapor and Liquid Composition Differences Resulting from Fuel Evaporation
1999-03-01
1999-01-0377
Liquid fuels and the fuel vapors in equilibrium with them typically differ in composition. These differences impact automotive fuel systems in several ways. Large compositional differences between liquid and vapor phases affect the composition of species taken up within the evaporative emission control canister, since the canister typically operates far from saturation and doesn't reach equilibrium with the fuel tank. Here we discuss how these differences may be used to diagnose the mode of emission from a sealed container, e.g., a fuel tank. Liquid or vapor leaks lead to particular compositions (reported here) that depend on the fuel components but are independent of the container material. Permeation leads to emissions whose composition depends on the container material. If information on the relative permeation rates of the different fuel components is available, the results given here provide a tool to decide whether leakage or permeation is the dominant mode of emission.