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Combustion diagnostics of highly diluted mixtures are essential for the estimation of the combustion quality, and control of combustion timing in advanced combustion systems. In this paper, a novel fast response flame detection technique based on active plasma is introduced and investigated. Different from the conventional ion current sensing used in internal combustion engines, a separate electrode gap is used in the detecting probing. Further, the detecting voltage across the electrode gap is modulated actively using a multi-coil system to be slightly below the breakdown threshold before flame arrival. Once the flame front arrives at the probe, the ions on the flame front tend to decrease the breakdown voltage threshold and trigger a breakdown event. Simultaneous electrical and optical measurements are employed to investigate the flame detecting efficacy via active plasma probing under both quiescent and flow conditions.