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Low NOx and soot free premixed diesel combustion can be realized by increasing ignition delays in low oxygen atmospheres, as well as the combustion here also depends on fuel ignitability. In this report single intermittent spray combustion with primary reference fuels and a normal heptane-toluene blend fuel under several oxygen concentrations in a constant volume combustion vessel was analyzed with high-speed color video and pressure data. Temperature and KL factor distributions are displayed with a 2-D two-color method. The results show that premixing is promoted with a decrease in oxygen concentration, and the local high temperature regions, above 2200 K, as well as the duration of their appearance decreases with the oxygen concentration. With normal heptane, mild premixed diesel combustion can be realized at 15 vol% oxygen and there is little luminous flame.

Laser Doppler velocimetry has been used to measure velocity and turbulence intensity profiles in the wall boundary layer of a spark-ignited homogeneous-charge research engine. By using a toroidal contoured engine head it was possible to bring the laser probe volume to within 60 μm of the wall. Two different levels of engine swirl were used to vary the flow Reynolds number. For the high swirl case under motored operation the boundary layer thickness was less than 200 μm, and the turbulence intensity increased as the wall was approached. With low swirl the 700-1000 μm thick boundary layer had a velocity profile that was nearly laminar in shape, and there was no increase in turbulence intensity near the wall. When the engine was fired the boundary layer thickness increased for both levels of swirl.

The volatile organic compounds (VOC) from diesel engines, including formaldehyde and benzene, are concerned and remain as unregulated harmful substances. The substances are positively correlated with THC emissions, but the VOC and aldehyde compounds at light load or idling conditions are more significant than THC. When coolant temperatures are low at light loads, there are notable increases in formaldehyde and acetaldehyde, and with lower coolant temperatures the increase in aldehydes is more significant than the increase in THC. When using ultra high EGR so that the intake oxygen content decreases below 10%, formaldehyde, acetaldehyde, benzene, and 1,3-butadiene increase significantly while smokeless and ultra low Nox combustion is possible.

Ultra low emissions and high performance combustion was achieved with a combination of high EGR, a three-way catalyst, and a highly oxygenated liquid fuel, neat dimethoxy methane (DMM), in an ordinary DI diesel engine. The smokeless nature of neat DMM effectively allowed stoichiometric diesel combustion by controlling BMEP with EGR. NOx, THC, and CO emissions were reduced with a three-way catalyst. At lower BMEP with excess air, the EGR effectively reduced NOx. High-speed video in a bottom view type engine revealed that luminous flame decreased with increased fuel oxygen content and almost disappeared with DMM.

Significant improvements in exhaust emissions and engine performance in an ordinary DI diesel engine were realized with highly oxygenated fuels. The smoke emissions decreased sharply and linearly with increases in oxygen content and entirely disappeared at an oxygen content of 38 wt-% even at stoichiometric conditions. The NOx, THC, and CO were almost all removed with a three-way catalyst under stoichiometric diesel combustion at both the higher and lower BMEP with the combination of EGR and a three-way catalyst. The engine output for the highly oxygenated fuels was significantly higher than that with the conventional diesel fuel due to the higher air utilization.

Diesel combustion and exhaust gas emissions under transient operation (when fuel amounts abruptly increased) were investigated under a wide range of operating conditions with a newly developed gas sampling system. The relation between gas emissions and piston wall temperatures was also investigated. The results indicated that after the start of acceleration NOx, THC and smoke showed transient behaviors before reaching the steady state condition. Of the three gases, THC was most affected by piston wall temperature; its concentration decreased as the wall temperature increased throughout the acceleration except immediately after the start of acceleration. The number of cycles, at which gas concentrations reach the steady-state value after the start of acceleration, were about 1.2 times the cycle constant of the piston wall temperature for THC, and 2.3 times for smoke.

Time resolved changes in unburned hydrocarbon emissions and their components were investigated in a DI diesel engine with a specially developed gas sampling system and gas chromatography. The tested transient operations include starting and increasing loads. At start-up with high equivalence ratios the total hydrocarbon (THC) at first increased, and after a maximum gradually decreased to reach a steady state value. Reducing the equivalence ratio of the high fueling at start-up and shortening the high fueling duration are effective to reduce THC emissions as long as sufficient startability is maintained. Lower hydrocarbons, mainly C1-C8, were the dominant components of the THC and mainly determined the THC behavior in the transient operations while the proportion of hydrocarbon (HC) components did not significantly change. The unregulated toxic substances, 1,3 butadiene and benzene were detected in small quantities.

Time series analysis of diesel exhaust gas emissions under transient operation was carried out using a uniquely developed gas sampling system to efficiently collect all exhaust gas throughout transient cycles. The effects of fuel properties and other engine operation parameters on the exhaust emissions under transient runs when fuel amounts abruptly increase were analyzed. The results showed that THC increased abruptly to 2 or 6 times the final steady-state concentration immediately after the start of acceleration and then decreased to the steady-state values after 70∼200 cycles. At acceleration, NOx increased abruptly to about 80 % of the final NOx concentration, and then increased gradually to reach the final values after 60∼500 cycles. The behaviors of THC and NOx during transient operation can be described by exponential functions of the elapsed cycle numbers and the final emission concentrations.

A detailed thermodynamic analysis was performed to demonstrate the fundamental efficiency advantage of an opposed-piston two-stroke engine over a standard four-stroke engine. Three engine configurations were considered: a baseline six-cylinder four-stroke engine, a hypothetical three-cylinder opposed-piston four-stroke engine, and a three-cylinder opposed-piston two-stroke engine. The bore and stroke per piston were held constant for all engine configurations to minimize any potential differences in friction. The closed-cycle performance of the engine configurations were compared using a custom analysis tool that allowed the sources of thermal efficiency differences to be identified and quantified.

The authors have reported significant smoke reduction in twin shaped semi-premixed diesel combustion with a newly designed combustion chamber to distribute the first and the second sprays into upper and lower layers. However, the first stage premixed combustion tends to advance far from the TDC, resulting in lowering of thermal efficiencies. In this report, improvement of thermal efficiency by optimizing the combustion phase with lower ignitability fuels was identified with the divided combustion chamber. The experiment was conducted with four fuels with different cetane numbers. The first stage premixed combustion can be retarded to the optimum phase with the fuel with cetane number 38, establishing high efficiencies.

To improve the combustion characteristics in semi-premixed diesel combustion, consisting in the first-stage premixed combustion of the primary fuel injection and the second-stage spray combustion of the secondary injection, the effect of splitting the primary injection was investigated in a diesel engine and analyzed with a CFD. The indicated thermal efficiency improves due to reductions in heat transfer losses to the in-cylinder wall and the combustion noise is suppressed with the split primary injections. The CFD analysis showed that the reduction in heat transfer loss with the split primary injections is due to a decrease in the combustion quantity near the combustion chamber wall.

Semi-premixed diesel combustion with a twin peak shaped heat release with the two-stage fuel injection (twin combustion) has the potential to establish efficient, low emission, and low noise operation. However, with twin combustion at low loads the indicated thermal efficiencies are poorer than at medium loads due to the lower combustion efficiencies. In this report, to increase the combustion efficiencies at low loads, the thermal efficiency related parameters were investigated in a 0.55 L single cylinder diesel engine. The results show that the indicated thermal efficiency improves with increases in the intake gas temperatures at low loads. However, at the higher loads where the combustion efficiencies are somewhat higher the indicated thermal efficiencies decrease with increases in the intake gas temperatures due to increases in the cooling losses.

Diesel soot suppression effects of catalytic fuel additives for a range of fuels with different properties were investigated with calcium naphthenate. A single cylinder DI diesel engine and a thermobalance were used to determine the soot reduction and its mechanism for seven kinds of fuels. Experimental results showed that the catalytic effect of the fuel additive was different for the different fuels, and could be described by a parameter considering cetane number and kinematic viscosity. The fuel additives reduced soot more effectively for fuels with higher cetane number and lower kinematic viscosity. This result was explained by soot oxidation characteristics for the different fuels. Oxidation of soot with the metallic additive proceeds in two stages: stage I, a very rapid oxidation stage; and stage II, a following slow or ordinary oxidation stage.

A study was performed in which the effects on the regulated emissions from a commercial small DI diesel engine were measured for different refinery-derived fuel blends. Seven different fuel blends were tested, of which two were deemed to merit more detailed evaluation. To investigate the effects of fuel properties on the combustion processes with these fuel blends, two-color pyrometry was used via optically accessible cylinderheads. Additional data were obtained with one of the fuel blends with a heavy-duty DI diesel engine. California diesel fuel was used as a baseline. The fuel blends were made by mixing the components typically found in gasoline, such as methyl tertiary-butyl ether (MTBE) and whole fluid catalytic cracking gasoline (WH-FCC). The mixing was performed on a volume basis. Cetane improver (CI) was added to maintain the same cetane number (CN) of the fuel blends as that of the baseline fuel.

This research focused on the effects of split injection on combustion in a diesel environment. It was done in a specially designed engine-fed combustion chamber (swirl ratio of 5) with full field optical access through a quartz window. The simulated engine combustion chamber used a special backwards spraying injector (105°). The electronically controlled injector could control the size and position of it's, two injections. Both injections were through the same nozzle and it produced very rapid injections (1.5 ms) with a maximum injection pressure of 130 MPa. Experimental data included: rate of injection, injector pressure, combustion chamber dumping (NO & NOx concentrations), flame temperature, KL factor (soot concentration) combustion pressure, and rate of pressure rise. Injection rates indicate that the UCORS injection system creates very rapid injections with the ability to produce controllable split injections.

This research focused on the effects of split injection on fuel spray behavior in a diesel environment. It was done in a special designed engine-fed combustion chamber (swirl ratio of 5) with full field optical access through a quartz window. The simulated engine combustion chamber used a special backwards spraying injector (105°). The electronically controlled injector could control the size and position of it's two injections. Both injections were through the same nozzle and it produced very rapid injections (1.5 ms) with a maximum injection pressure of 130 MPa. Experimental data included: rate of injection, injector pressure, spray plume images, tip penetration, liquid and vapor fuel distributions, combustion pressure, and rate of pressure rise. From 105° forward scatter images, tip penetration was observed to be very rapid and reached a plateau at 25 mm.

To date there is no universal agreement as to the interaction between fuel type, fuel-air mixture preparation and combustion chamber flow characteristics and their effect on soot formation. A propane fueled modified conical back-mixed steady flow reactor was built in which the fuel and air could be mixed together in varying degrees and reacted in at different mixing intensities. The onset of soot and soot loading were determined qualitatively by a photomultiplier focused on the volume inside the reactor. Increasing the degree of premix from a diffusion flame to a distribution of Φmax/Φavg = 5.0 resulted in increases of 3 to 17 percent of the soot-onset equivalence ratio and decreases in soot loading down to zero. Changes in the mixing intensity from 32.5 sec−1 to 75.7 sec−1 resulted in a change in the soot-onset equivalence ratio from 1.26 to 1.52. Soot loading was found to depend on both the mixing intensity, β, and the average number of mixes per mean residence time, β/α.

In this paper, effect of intake air temperature, coolant temperature, and compression ratio on start of heat release (SOHR) in HCCI engines is investigated. The operational range with HCCI operation was determined experimentally using a CFR (Cooperative Fuels Research) engine with n-butane as the fuel. In-cylinder pressure was processed to evaluate SOHR. The effect of intake air and coolant temperature on SOHR increases as engine speed increases. In order to gain more insight into the combustion phenomena, SOHR was calculated using the theory of Livengood-Wu and compared with the experimental data. Dependence of SOHR on the equivalence ratio shows good correspondence between experiment and calculation. On the contrary, dependence on the intake air temperature and compression ratio shows poorer correspondence with predictions, especially under low engine speed. We interpret this as an indication of the importance of the active intermediate species that remain in the combustion chamber.

A single cylinder, Cummins NH, direct-injection, diesel engine has been operated in order to evaluate the effects of aromatic content and aromatic structure on diesel engine particulates. Results from three fuels are shown. The first fuel, a low sulfur Chevron diesel fuel was used as a base fuel for comparison. The other fuels consisted of the base fuel and 10% by volume of 1-2-3-4 tetrahydronaphthalene (tetralin) a single-ring aromatic and naphthalene, a double-ring aromatic. The fuels were chosen to vary aromatic content and structure while minimizing differences in boiling points and cetane number. Measurements included exhaust particulates using a mini-dilution tunnel, exhaust emissions including THC, CO2, NO/NOx, O2, injection timing, two-color radiation, soluble organic fraction, and cylinder pressure. Particulate measurements were found to be sensitive to temperature and flow conditions in the mini-dilution tunnel and exhaust system.

Synthetic fuels (e-fuels) synthesized from H2 and CO by renewable electricity are expected as the next- generation diesel fuels and two types of e-fuels have received extensive attention: Fischer-Tropsch (FT) fuel and Oxymethylene dimethyl ether (OME). In this study the effects of OME blending ratios with 0 to 50 vol.% in FT fuels on combustion, emissions and spray characteristics in diesel engines are investigated. The results suggest that the OME blends to FT fuels suppressed the deterioration in combustion efficiency under low intake oxygen concentration conditions. The smoke emissions of FT fuels and OME blended fuels were both lower than those of diesel fuel and decreased with the increase in the OME blend ratio, and the soot-NOx trade-off relation in diesel engines can be improved.