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In-cylinder total sampling technique utilizing a single-cylinder diesel engine equipped with hydraulic valve actuation system has been developed. In this study, particulate matter (PM) included in the in-cylinder sample gas was collected on a quartz filter, and the polycyclic-aromatic hydrocarbons (PAHs) component and soot were subsequently quantified by thermal desorption-gas chromatograph mass spectrometry (TD-GCMS) and a carbon analyzer, respectively. Cylinder-averaged histories of PAHs and soot were obtained by changing the sampling timing. It was found that decreasing intake oxygen concentration suppresses in-cylinder soot oxidation, and the fuel with higher aromatic and naphthenic contents accelerates soot production.

The composition ratio of saturated and unsaturated fatty acid methyl esters (FAME) is depended on feedstock. Three FAMEs: soybean (SME), palm (PME) and coconut oil (CME) methyl esters were mixed to make fuels which have different composition ratio. The ignitability of fuel which mainly consisted of unsaturated FAME was inferior. Power was slightly reduced with increasing of mixing ratio of CME; however exhaust gas emissions were improved because CME contained a lot of oxygen atoms. Fuel which was equal mixture SME and CME indicated almost the same ignition characteristic as that of PME because they have same composition ratio.