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Technical Paper

The Variation of Functional Characteristics of a Euro VI Selective Catalytic Reduction Reactor after Ageing

2020-09-15
2020-01-2205
The selective catalytic reduction (SCR) of nitrogen oxides by ammonia is commonly applied as a method of exhaust aftertreatment for lean burn compression ignition (CI) engines. The catalytic reactor of an SCR system, like all catalytic emission control devices, is susceptible to partial deactivation as its operating time progresses. Long-term exposure of an SCR reactor to exhaust gas of fluctuating temperature and composition results in variations of the characteristics of its catalytically active layer. The aim of this study was to observe and investigate the variation of parameters characterizing the SCR reactor as a result of its ageing. Attention was paid to changes in ammonia storage capacity, selectivity of chemical reactions and maximum achievable NOx conversion efficiency. The experimental setup was a heavy duty (HD) Euro VI-compliant engine and its aftertreatment system (ATS). The setup was installed on a transient engine dyno instrumented with emission measurement devices.
Technical Paper

The Measurement of Particulate Matter from Construction Machinery under Actual Operating Conditions

2015-09-29
2015-01-2810
The paper describes the measurement of PM emission from an excavator engine under actual operating conditions. The exploration of the relations between the engine operating parameters and its emissions requires measurements under actual conditions of engine operation. The specificity of the emission measurements, PM in particular, requires technologically advanced measuring devices. The situation gets even more complicated when, beside the PM mass. The particle size distribution and number (PN) also need to be measured. An important technical issue is the difficulty in fitting the measurement equipment in/on the vehicle in operation (e.g. excavator), which is why the presented investigations were carried out in a laboratory under simulated operation. The laboratory technicians applied load to the engines through the excavator hydraulic system.
Technical Paper

The Influence of Synthetic Oxygenates on Euro IV Diesel Passenger Car Exhaust Emissions - Part 3

2008-10-06
2008-01-2387
The paper presents the test results relating to the influence of carbonate oxygenated additives to diesel fuel on exhaust emissions. Following the previous tests of glycol ethers (SAE Paper 2007-01-0069) and maleates (SAE Paper 2008-01-1813), the authors decided to use carbonates to obtain an even greater reduction in PM emissions. The significant effectiveness of carbonates on PM emission reduction was confirmed in tests performed by the authors. Diethyl carbonate was the most effective oxygenated compound with regard to PM emission reduction among all the 11 oxygenates which have been tested so far. Moreover, it is important to note that diethyl carbonate caused only a small increase in NOx emissions, thus it allowed for an essential improvement in the PM/NOx trade-off. A significant increase in the CO and HC emissions was, however, a negative effect of the use of carbonates.
Technical Paper

The Influence of Synthetic Oxygenates on Euro IV Diesel Passenger Car Exhaust Emissions - Part 2

2008-06-23
2008-01-1813
The paper presents the test results of the influence of maleate oxygenated additives to diesel fuel on exhaust emissions. Following the previous tests of glycol ethers (SAE Paper 2007-01-0069), the authors decided to use maleates as oxygenates to obtain greater changes in PM/NOx trade-off than the changes obtained as a result of the use of glycol ethers. It was found that in the NEDC maleates at the same concentration as in the case of glycol ethers ensure more favourable changes of PM/NOx trade-off and, as a matter of fact, caused greater reduction in PM emissions without the growth of NOx emissions, however, at the cost of CO and HC emissions. The tests performed in the FTP-75 confirmed a significantly weaker influence of maleates, both positive (PM) and negative (CO, HC) than in the NEDC. They did not find in both cycles any influence of maleates at the tested concentration upon fuel consumption and CO2 emissions.
Technical Paper

The Influence of Synthetic Oxygenates on Euro IV Diesel Passenger Car Exhaust Emissions

2007-01-23
2007-01-0069
In the year 2005, the EURO IV fuel specification came into effect and the requirements for diesel fuel properties have become even more stringent. In this way, the potential of diesel fuel for emissions reduction has already been to a large extent exploited and the most emissions-sensitive fuel parameters can now be changed in a narrow range only. The shortfall in NOx and PM emissions control in diesel engines is, however, so great that more drastic fuel changes will be needed. One of the most promising fuel modifications for exhaust emissions control seems to be oxygenated additives. The objective of the study described in this paper was to analyze under transient conditions the influence of synthetic oxygenated fuel additives on exhaust emissions. The tests were conducted on a Euro IV passenger car. Six oxygenated additives were tested over the New European Driving Cycle (NEDC).
Technical Paper

The Influence of Oxygenated Diesel Fuels on a Diesel Vehicle PM/NOx Emission Trade-Off

2009-11-02
2009-01-2696
Research on the influence of oxygenated diesel fuels on the PM/NOx emission trade-off was carried out with use of 11 different synthetic oxygenated compounds, representing 3 chemical groups (glycol ethers, maleates, carbonates). Each of oxygenates were evaluated as a fuel additive at a concentration of 5% v/v in the same base diesel fuel. The tests were conducted on a passenger car equipped with a common rail turbocharged diesel engine over the European cycle NEDC and US FTP-75 cycle. All the tested oxygenates caused a reduction in PM emissions and most of them caused a certain increase in NOx emissions. The changes in emissions depended on the oxygenate type and cycle. In general, the favorable and unfavorable influence of oxygenated compounds was more intensive during the NEDC, which is a softer and less transient cycle than the FTP-75. The most favorable changes in the PM/NOx emission trade-off were obtained for maleates and carbonates.
Journal Article

The Impact of Fuel Ethanol Content on Particulate Emissions from Light-Duty Vehicles Featuring Spark Ignition Engines

2014-04-01
2014-01-1463
Ethanol has long been a fuel of considerable interest for use as an automotive fuel in spark ignition (SI) internal combustion engines. In recent years, concerns over oil supplies, sustainability and geopolitical factors have lead multiple jurisdictions to mandate the blending of ethanol into standard gasoline. The impact of blend ethanol content on gaseous emissions has been widely studied; particulate matter emissions have received somewhat less attention, despite these emissions being regulated in the USA. Currently, in the EU particulate matter emissions from SI engines are partially regulated - only vehicles featuring direct injection SI engines are subject to emissions limits. A range of experiments was conducted to determine the impact of fuel ethanol content on the emissions of solid pollutants from Euro 5 passenger cars.
Technical Paper

The Formation of Ammonia in Three-Way Catalysts Fitted to Spark Ignition Engines - Mechanisms and Magnitudes

2022-08-30
2022-01-1026
Exhaust gas aftertreatment systems can, under certain conditions, create undesired chemical species as a result of their elimination reactions. A prime example of this is ammonia (NH3), which is not formed in the combustion reaction, but which can be formed within a three-way catalyst (TWC) when physicochemical conditions permit. The elimination of NOx in the TWC thus sometimes comes at the cost of significant emissions of NH3. Ammonia is a pollutant and a reactive nitrogen compound (RNC) and NH3 emissions should be analyzed in this context, alongside other RNC species. Examination of the literature on the subject published over the past two decades shows that ammonia, a species which is currently not subject to systematic emissions requirements for road vehicles in any market, is often identified as forming the majority of the RNC emissions under a range of operating conditions.
Journal Article

The Exhaust Emission from Light Duty Vehicles in Road Test in Urban Traffic

2010-05-05
2010-01-1558
The investigations into the emissions from light-duty vehicles are carried out on a chassis dynamometer in the NEDC test in Europe and FTP75 test in the US. Such tests do not entirely reflect the real road conditions. It should be noted that the changes in the methodology of emissions testing should go in the direction where they get closer to the actual road conditions. The paper presents the road test results obtained in an urban congested areas. The analysis of the road tests results (exhaust emissions and fuel consumption) was carried out considering the road conditions (vehicle speed and acceleration). The obtained data were used to specify the dependence characteristics for the influence of the dynamic engine properties on the exhaust emissions. For these measurements a portable SEMTECH DS analyzer by SENSORS, Particle Counter by AVL and Particle Seizer EEPS by TSI has been used.
Technical Paper

The Effect of Various Petrol-Ethanol Blends on Exhaust Emissions and Fuel Consumption of an Unmodified Light-Duty SI Vehicle

2011-09-11
2011-24-0177
Due to limited fossil fuel resources and a need to reduce anthropogenic CO₂ emissions, biofuel usage is increasing in multiple markets. Ethanol produced from the fermentation of biomass has been of interest as a potential partial replacement for petroleum for some time; for spark-ignition engines, bioethanol is the alternative fuel which is currently of greatest interest. At present, the international market for ethanol fuel consists of E85 fuel (with 85 percent ethanol content), as well as lower concentrations of ethanol in petrol for use in standard vehicles (E5, E10). The impact of different petrol-ethanol blends on exhaust emissions from unmodified vehicles remains under investigation. The potential for reduced exhaust emissions, improved security of fuel supply and more sustainable fuel production makes work on the production and usage of ethanol and its blends an increasingly important research topic.
Technical Paper

The Effect of Pure RME and Biodiesel Blends with High RME Content on Exhaust Emissions from a Light Duty Diesel Engine

2009-11-02
2009-01-2653
The use of biofuels (biodiesel and gasoline-alcohol blends) in vehicle powertrains has grown in recent years in European Union, the United States, Japan, India, Brazil and many other countries due to limited fossil fuel sources and necessary reduction of anthropogenic CO2 emissions. European car manufacturers have approved up to 5 percent of biodiesel blend in diesel fuel (B5 biodiesel blend) which meets European fuel standards EN 14214 and EN 590. The goal for research is to achieve higher biodiesel content in diesel fuel B10 and B20, without resorting to larger diesel engines and fuel feed system modernization. This paper evaluates the possibility of using higher FAME content in biodiesel blends (mixture of diesel fuel and Fatty Acid Methyl Esters) in modern Euro 4 vehicle with direct-injection, common-rail and turbocharged light-duty diesel engine with standard engine ECU calibration and standard injection equipment (not tuned for biodiesel).
Technical Paper

The Comparison of the Emissions from Light Duty Vehicle in On-road and NEDC Tests

2010-04-12
2010-01-1298
The investigations into the emissions from light-duty vehicles have been carried out on a chassis dynamometer (NEDC test in Europe and FTP75 test in the US). Such tests do not entirely reflect the real road conditions and that is why we should analyze the correlation of the laboratory versus on-road test results. The paper presents the on-road test results obtained in an urban and extra urban cycles. For these measurements a portable SEMTECH DS analyzer by SENSORS has been used. The device is an analyzer enabling an on-line measurement of the emission gases concentration in a real driving cycle under real road conditions. The road tests were performed on road portions of several kilometers each. The obtained results were compared with the results obtained for the same vehicle during the NEDC test on a chassis dynamometer. The comparative analysis was performed including the urban and extra-urban cycles.
Technical Paper

The Analysis of the Exhaust Emission Level in Combat Vehicles Under Real Operating Conditions

2011-01-19
2011-26-0041
The paper presents the results of tests on a combustion engine of an armored modular vehicle 8x8 Rosomak under combat simulating conditions. For the measurements of the toxic compounds a portable SEMTECH DS analyzer by SENSORS was used. The analyzer allowed a measurement of toxic compounds at the same time measuring the mass flow rate of the exhaust gases. The analysis of the PM emission was performed based on the measurement of the size of the particulate matter (analyzer 3090 EEPS - Engine Exhaust Particle Sizer™ Spectrometer - by TSI Incorporated) and counting of the particles (analyzer Particle Counter by AVL). The measurements of CO, HC, NOx, PM and fuel consumption were performed under the conditions of combat simulation and in the overboost mode. Based on the obtained results, an analysis of the engine and vehicle operation was performed and the on-road and unit exhaust emissions as well as on-road and unit fuel consumption were compared.
Technical Paper

The Analysis of the Emission of Particulate Matter from Non-Road Vehicles Under Actual Operating Conditions

2012-09-24
2012-01-1965
The paper discusses the measurement of the PM emissions from non-road vehicles (a farm tractor and an excavator) under actual operating conditions. Full exploration of the relations between the operating parameters of these vehicles and their emissions requires measurements under actual conditions of their operation. The specificity of the emission measurements, PM in particular, requires technologically advanced measuring devices. The situation gets even more complicated if, beside the PM mass, we also wish to obtain the PM size distribution and particle number (PN). One of the more important technical issues is the difficulty in fitting of the measurement equipment in/on the vehicle in operation (e.g. a farm tractor). That is the reason why the investigations were carried out in a laboratory. The laboratory technicians applied load to the engines through external devices - a hydraulic system for the excavator and a brake coupled to the farm tractor power takeoff.
Technical Paper

Simulation Study of Force Distribution in the Multiple Linkage System of a Spark Ignition Engine Operating in the Atkinson Cycle

2020-09-15
2020-01-2226
The tests were carried out on an 3D engine model with an unconventional multiple linkage system. Compared to a classic crankset, the mechanism consists of more elements. In this multiple linkage system the camshaft, the piston rod and the main rod are connected to one common element. The camshaft rotating during operation at twice the speed of the crankshaft makes possible to achieve different piston stroke lengths with each revolution. With proper synchronization of the camshaft revolution with the crankshaft, the suction and compression stroke is smaller in relation to the expansion and exhaust strokes. For this reason, the Atkinson cycle was obtained without interfering with the variable valve timing. The thermal cycle is characterized by increased theoretical thermal efficiency. Due to the unique mechanism, the piston movement has different characteristics compared to classic solutions. Therefore, work was undertaken to analyze the distribution of forces in the system.
Technical Paper

Short-Time Analysis of Combustion Engine Vibroacoustic Signals through Pattern Recognition Techniques

2005-05-16
2005-01-2529
The paper presents a method of analysis of vibroacoustic signals taken from Diesel engines based on short-time analysis. The main aim of the research is to distinguish between normal engine operation and that of misfire. The approach utilizes a time window sliding along a signal in time and observing the changes of given parameters. The set of parameter values creates a multidimensional parameter space where one can observe the time evolution. For recognition and detection of different system states a clustering in the parameter space is suggested. The first results show the possibility of distinguishing some different clusters within the parameter space which may correspond to different engine states.
Journal Article

Regulated and Unregulated Exhaust Emissions from CNG Fueled Vehicles in Light of Euro 6 Regulations and the New WLTP/GTR 15 Test Procedure

2015-04-14
2015-01-1061
The aim of this paper was to explore the influence of CNG fuel on emissions from light-duty vehicles in the context of the new Euro 6 emissions requirements and to compare exhaust emissions of the vehicles fueled with CNG and with gasoline. Emissions testing was performed on a chassis dynamometer according to the current EU legislative test method, over the New European Driving Cycle (NEDC). Additional tests were also performed on one of the test vehicles over the World Harmonized Light Vehicles Test Cycle (WLTC) according to the Global Technical Regulation No. 15 test procedure. The focus was on regulated exhaust emissions; both legislative (CVS-bag) and modal (continuous) analyses of the following gases were performed: CO (carbon monoxide), THC (total hydrocarbons), CH4 (methane), NMHC (non-methane hydrocarbons), NOx (oxides of nitrogen) and CO2 (carbon dioxide).
Technical Paper

Regulated Emissions, Unregulated Emissions and Fuel Consumption of Two Vehicles Tested on Various Petrol-Ethanol Blends

2014-10-13
2014-01-2824
Ethanol has a long history as an automotive fuel and is currently used in various blends and formats as a fuel for spark ignition engines in many areas of the world. The addition of ethanol to petrol has been shown to reduce certain types of emissions, but increase others. This paper presents the results of a detailed experimental program carried out under standard laboratory conditions to determine the influence of different quantities of petrol-ethanol blends (E5, E10, E25, E50 and E85) on the emission of regulated and unregulated gaseous pollutants and particulate matter. The ethanol-petrol blends were laboratory tested in two European passenger cars on a chassis dynamometer over the New European Driving Cycle, using a constant volume sampler and analyzers for quantification of both regulated and unregulated emissions.
Technical Paper

RDE-Compliant PEMS Testing of a Gasoline Euro 6d-TEMP Passenger Car at Two Ambient Temperatures with a Focus on the Cold Start Effect

2020-04-14
2020-01-0379
European Union RDE (real driving emissions) legislation requires that new vehicles be subjected to emissions tests on public roads. Performing emissions testing outside a laboratory setting immediately raises the question of the impact of ambient conditions - especially temperature - on the results. In the spirit of RDE legislation, a wide range of ambient temperatures are permissible, with mathematical moderation (correction) of the results only permissible for ambient temperatures <0°C and >+30°C. Within the standard range of temperatures (0°C to +30°C), no correction for temperature is applied to emissions results and the applicable emissions limits have to be met. Given the well-known link between the thermal state of an engine and its emissions following cold start, ambient temperature can be of great importance in determining whether a vehicle meets emissions requirements during an RDE test.
Technical Paper

RDE Testing of Passenger Cars: The Effect of the Cold Start on the Emissions Results

2019-04-02
2019-01-0747
This paper discusses the importance of the inclusion of emissions from the cold start event during legislative on-road tests on passenger cars (RDE - real driving emissions tests conducted under real-world driving conditions, as defined by EU legislation). Results from a recently-registered gasoline-powered vehicle are presented, with the main focus on the comparison of exhaust emission results: excluding/including the cold start during the initial phase of the RDE test. Cold start is the most challenging aspect of emissions control for vehicles with spark ignition engines and the inclusion of the cold start event in RDE test procedure has wide-ranging implications both for the testing process and compliance with RDE legislation via optimisation of aftertreatment systems and the engine calibration. In addition to some theoretical arguments, the results of an RDE-compliant test performed using the aforementioned procedures are presented.
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