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The NO reduction in an ammonia SCR converter has been simulated by a 1D+1D model for a single representative channel to parametrically study the characteristics of the system under typical operating conditions. An appropriate model has been selected interpreting the chemical behavior of the system and the parameters are calibrated based on a comprehensive set of experiments with an Fe-Zeolite washcoated monolith for different feed concentrations, temperatures and flow rates. Physical and chemical properties are determined as well as kinetics and rate parameters and the model has been verified by experimental data at different operating conditions. Three different mechanisms for the surface kinetics to model NO reduction have been assessed and the results have been compared in the cases of steady DeNO performance and transient response of the system. Ammonia inhibition is considered in the model since it has a major effect specifically under transient operating conditions.

Cycle-to-cycle variations in internal combustion engines are known to lead to limitations in engine load and efficiency, as well as increases in emissions. Recent research has led to the identification of the source of cyclic variations of pressure, soot and NO emissions in direct injection common rail diesel engines, when employing a single block injection and operating under long ignition delay conditions. The variations in peak pressure arise from changes in the diffusion combustion rate, caused by randomly occurring in-cylinder pressure fluctuations. These fluctuations result from the excitation of the first radial mode of vibration of the cylinder gases which arises from the rapid premixed combustion after the long ignition delay period. Cycles with high-intensity fluctuations present faster diffusion combustion, resulting in higher cycle peak pressure, as well as higher measured exhaust NO concentrations.

Emissions and performance parameters of a medium size, medium speed D.I. diesel engine with increased charge air pressure and reduced but fixed inlet valve opening period have been measured and compared to the standard engine. While power output and fuel consumption are slightly improved, nitric oxide emissions can be reduced by up to 20%. The measurements confirm the results of simulations for both performance and emissions, for which a quasidimensional model including detailed chemistry for nitric oxide prediction has been developed.

Simulations for a pressure-assisted multi-stream injector designed for urea-dosing in a selective catalytic reduction (SCR) exhaust gas system have been carried out and compared to measurements taken in an optically accessible high-fidelity flow test rig. The experimental data comprises four different combinations of mass flow rate and temperature for the gas stream with unchanged injection parameters for the spray. First, a parametric study is carried out to determine the importance of various spray sub-models, including atomization, spray-wall interaction, buoyancy as well as droplet coalescence. Optimal parameters are determined using experimental data for one reference operating condition.

Combustion engines for decentralized power generation or cogeneration in general, are subject to increasingly stringent pollutant emissions regulations. Motivated by the Europe-;wide lowest allowable NOx levels in Switzerland - particularly in the Zurich metropolitan area with 50 mg/Nm3 at 5% O2 - and in close cooperation with industry, the I.C. Engines and Combustion Laboratory (LVV) of the Swiss Federal Institute of Technology Zurich (ETHZ) has investigated some new operating concepts and engine processes in order to overcome the dilemma between low emissions and high efficiency, which is usually encountered in engine optimization. Our final approach thereby involves the Exhaust Gas Recirculation (EGR) combined with stoichiometric mixture (λ = 1) and a 3-way catalytic converter. The engine is supercharged and the intake mixture aftercooled for high power density and thermal efficiency.

State of the art high-pressure fuel injectors offer the ability to inject multiple times per cycle, and can reach very low fuel amounts per injection event. This behaviour allows the application of pilot injections in diesel engine applications or dual fuel engines. In both diesel and dual fuel engines, the amount of pilot fuel affects the engine efficiency. The understanding of the underlying ignition mechanism of the pilot fuel is required to optimize injection parameters and the engines’ fuel consumption. The present work focuses on the differences of ignition mechanisms between long and short injections. The investigation has been performed numerically, using CFD with a well-proven combustion model. The setup used employs a well characterized single orifice injector, injecting into a high temperature, pressurized environment with a composition of 15% oxygen.

In this paper we investigate the effect of the introduction of water in the combustion chamber of a DI-diesel engine on combustion characteristics and pollutant formation, by using water-diesel fuel emulsions with three distinct water amounts (13%, 21% and 30%). For the measurements we use a modern 4-cylinder DI-diesel engine with high-pressure common rail fuel injection and EGR system. The engine investigations are conducted at constant speed in different operating points of the engine map with wide variations of injection setting parameters and EGR rate. The main concern refers to the interpretation of both measured values and relevant thermodynamic variables, which are computed with analytical instruments (heat release rate, ignition delay, reciprocal characteristic mixing time, etc). The analysis of the measured and computed data shows clear trends and detailed evaluations on the behavior of water-diesel fuel emulsions in the engine process are possible.

In this study, the influence of injector diameter on the combustion of diesel sprays in an optically accessible combustion chamber of marine engine dimensions and conditions has been investigated experimentally as well as numerically. Five different orifice diameters ranging between 0.2 and 1.2 mm have been considered at two different ambient temperatures: a “cold” case with 800 K and a “warm” case with 900 K, resulting in a total of ten different test conditions. In the experiment, the reactive spray flames were characterized by means of high-speed OH* chemiluminescence imaging. The measurements revealed a weak impact of the injector diameter on ignition delay (ID) time and flame lift-off length (LOL) whereas the influence of ambient temperature was found to be more pronounced, consistent with former studies in the literature for smaller orifice diameters.

The addition of hydrogen-rich gas to gasoline in an Internal Combustion Engine seems to be particularly suitable to arrive at a near-zero emission Otto engine, which would be able to easily meet the most stringent regulations. In order to simulate the output of an on-board reformer that partially oxidizes gasoline, providing the hydrogen-rich gas, a bottled gas has been used. Detailed results of our measurements are here shown, such as fuel consumption, engine efficiency, exhaust emissions, analysis of the heat release rates and combustion duration, for both pure gasoline and blends with reformer gas. Additionally simulations have been performed to better understand the engine behaviour and NOx formation.

In the field of heavy-duty applications almost all engines apply the compression ignition principle, spark ignition is used only in the niche of CNG engines. The main reason for this is the high efficiency advantage of diesel engines over SI engines. Beside this drawback SI engines have some favorable properties like lower weight, simple exhaust gas aftertreatment in case of stoichiometric operation, high robustness, simple packaging and lower costs. The main objective of this fundamental research was to evaluate the limits of a SI engine for heavy-duty applications. Considering heavy-duty SI engines fuel consumption under full load conditions has a high impact on CO₂ emissions. Therefore, downsizing is not a promising approach to improve fuel consumption and consequently the focus of this work lies on the enhancement of thermal efficiency in the complete engine map, intensively considering knocking issues.

Knock is often the main limiting factor for brake efficiency in spark ignition engines and is mostly attributed to auto-ignition of the unburned mixture in front of the flame. In order to study knock in a systematic way, spark angle sweeps with ethanol and iso-octane have been carried out on single cylinder spark ignition engine with variable intake temperatures at wide open throttle and stoichiometric premixed fuel/air mixtures. Much earlier and stronger knock can be observed for iso-octane compared to ethanol at otherwise same engine operating conditions due to the cooling effect and higher octane number of ethanol, leading to different cycle-to-cycle variation behavior. Detailed chemical kinetic mechanisms are used to compute ignition delay times at conditions relevant to the measurements and are compared to empirical correlations available in literature. The different correlations are used in a knock model approach and are tested against the measurement data.

The injection process of urea-water solution (AdBlue) determines initial conditions for reactions and catalysis and is fundamentally responsible for optimal operation of selective catalytic reduction (SCR) systems. The spray characteristics of four, commercially available, injectors (one air-assisted and three pressure-driven with different nozzle-hole configurations) are investigated with non-intrusive measuring techniques. Injection occurred in the crossflow of a channel blowing preheated air in an exhaust duct similar configuration. The effect of several gas temperatures and flows on the spray propagation and entrainment has been extensively studied by shadow imaging. Shadow images, in addition, show that the spray of the pressure-driven injectors is only marginally affected by the gas crossflow. In contrast, the air assisted spray is strongly deflected by the gas, the effect increasing with increasing gas flow.

New emission legislations applicable in the near future to sea-going vessels, off-road and off-highway vehicles require drastic nitric oxides emission reduction. A promising approach to achieve part of this decrease is charge air temperature reduction using Miller timing. However, it has been shown in literature that the reduction potential is limited, achieving a minimum in NOx emissions at a certain end-of-compression temperature. Further temperature reduction has shown to increase NOx emissions again. Some studies have shown that this increase is correlated to an increased amount of premixed combustion. In this work, the effects of pilot injection on engine out NOx emissions for very early intake valve closure (i.e. extreme Miller), high boost pressures and cold end-of-compression in-cylinder conditions are investigated. The experiments are carried out on a 3.96L single cylinder heavy-duty common-rail Diesel engine operating at 1000 rpm and at constant global air-to-fuel ratio.

The current trend in automobiles is towards electrical vehicles, but for the most part these vehicles still require an internal combustion engine to provide additional range and flexibility. These engines are under stringent emissions regulations, in particular, for the reduction of CO2. Gas engines which run lean burn combustion systems provide a viable route to these emission reductions, however designing these engines to provide sustainable and controlled combustion under lean conditions at λ=2.0 is challenging. To address this challenge, it is possible to use a scavenged Pre-Chamber Ignition (PCI) system which can deliver favorable conditions for ignition close to the spark plug. The lean charge in the main combustion chamber is then ignited by flame jets emanating from the pre-chamber nozzles. Accurate prediction of flame kernel development and propagation is essential for the analysis of PCI systems.

The behavior of spray auto-ignition and combustion of a diesel spray in a lean premixed methane/air charge was investigated. A rapid compression expansion machine with a free-floating piston was employed to reach engine-relevant conditions at start of injection of the micro diesel pilot. The methane content in the lean ambient gas mixture was varied by injecting different amounts of methane directly into the combustion chamber, the ambient equivalence ratio for the methane content ranged from 0.0 (pure air) to 0.65. Two different nozzle tips with three and six orifices were employed. The amount of pilot fuel injected ranged between 0.8 and 1.8 percent of the total energy in the combustion chamber. Filtered OH chemiluminescence images of the combustion were taken with a UV-intensified high-speed camera through the optical access in the piston.

Direct injection of natural gas in engines is considered a promising approach toward reducing engine out emissions and fuel consumption. As a consequence, new gas injection strategies have to be developed for easing direct injection of natural gas and its mixing processes with the surrounding air. In this study, the behavior of a hollow cone gas jet generated by a piezoelectric injector was experimentally investigated by means of tracer-based planar laser-induced fluorescence (PLIF). Pressurized acetone-doped nitrogen was injected in a constant pressure and temperature measurement chamber with optical access. The jet was imaged at different timings after start of injection and its time evolution was analyzed as a function of injection pressure and needle lift.

Future engine emission legislation regulates soot from Diesel engines strictly and requires improvements in engine calibration, fast response sensor equipment and exhaust gas aftertreatment systems. The in-cylinder phenomena of soot formation and oxidation can be analysed using a pyrometer with optical access to the combustion chamber. The pyrometer collects the radiation of soot particles during diffusion combustion, and allows the calculation of soot temperature and a proportional value for the in-cylinder soot density (KL). A four-cylinder heavy-duty Diesel engine was equipped in all cylinders with prototype pyrometers and state of the art pressure transducers. The cylinder specific data was recorded crank angle-resolved for a set of steady-state and transient operating conditions, as well as exhaust gas recirculation (EGR) addition and over a wide range of soot emissions.

Ignition systems for large lean burn gas engines are challenged by large energy deposition requirements to ensure stable and reliable inflammation of the premixed charge. In this study, two different ignition systems are investigated experimentally: ignition by means of injecting a small amount of diesel spray and its subsequent autoignition is compared to the ignition with an un-scavenged pre-chamber spark plug over a wide range of engine relevant conditions such as methane equivalence ratios and thermomechanical states. The ignition behavior as well as the combustion phase of the two systems is investigated using an optically accessible Rapid Compression Expansion Machine (RCEM). Filtered OH-chemiluminescence images of the ignition and combustion were taken with a UV intensified high speed camera through the piston window.

Emission and performance parameters of a medium size, and medium speed D.I. diesel engine equipped with a Miller System, a new developed High Pressure Exhaust Gas Recirculation System (HPEGR), a Common Rail (CR) system and a Turbocharger with Variable Turbine Geometry (VTG) have been measured and compared to the standard engine. While power output, fuel consumption, soot and other emissions are kept constant, nitric oxide emissions could be reduced by 30 to 50% depending on load and for the optimal combination of methods. Heat release rate analysis provides the reasons for the optimised engine behaviour in terms of soot and NOx emissions: The variable Nozzle Turbocharger helps deliver more oxygen to the combustion process (less soot) and lower the peak gas temperature (less NOx).

The goal of the Clean Engine Vehicle project (CEV) was the conversion of a gasoline engine to dedicated natural gas operation in order to achieve a significant reduction in CO2 emissions. The targeted reduction was 30% compared with a gasoline vehicle with similar performance. Along with the reduction in emissions, the second major requirement of the project, however, was compliance of the results with Euro-4 and SULEV emission limits. The project entailed modifications to the engine and the pre-existing model-based engine control system, the introduction of an enhanced catalytic converter and downsizing and turbocharging of the engine. As required by the initiators of the project, all components used were commonly available, some of them just being optimized or modified for natural gas operation.