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With the constant increase of fossil fuel prices and resources depletion, the researchers look beyond the usual alternative fuels for diesel engines. A lot of research is going on the employment of plastic polymers as fuels since they have a high potential to reduce diesel oil consumption and many of the aspects of their operation in diesel engines are not clarified yet. The major advantage of plastic polymers is the high calorific value, a widespread availability, and lower prices if they come from recycling. The paper presents the results from the research on a novel polyethylene blended diesel fuel and its use as alternative fuel for combustion in diesel generation plants. The authors investigated the formulation, injection, combustion and emissions of a new polyethylene-diesel fuel, obtained by an original process. The low density polyethylene (LDPE) has been mixed 5-40% by wt. with diesel by a new technology at 200 deg.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

Diesel engines provide the necessary power for accomplishing heavy tasks across the industries, but are known to produce high levels of noise. Additionally, each type of fuel possesses unique combustion characteristics that lead to different sound and vibration signatures. Noise is an indication of vibration, and components under excessive vibration may wear prematurely, leading to repair costs and downtime. New fuels that are sought to reduce emissions, and promote sustainability and energy independence must be investigated for compatibility from a sound and vibrations point-of-view also. In this research, the sound and vibration levels were analyzed for an omnivorous, single cylinder, CI research engine with alternative fuels and an advanced combustion strategy, RCCI. The fuels used were ULSD#2 as baseline, natural gas derived synthetic kerosene, and a low reactivity fuel n-Butanol for the PFI in the RCCI process.

This study presents the combustion and emissions characteristics of Reactivity Controlled Combustion Ignition (RCCI) produced by early port fuel injection (PFI) of low reactivity n-butanol (normal butanol) coupled with in cylinder direct injection (DI) of cottonseed biodiesel in a diesel engine. The combustion and emissions characteristics were investigated at 5.5 bars IMEP at 1400 RPM. The baseline was taken from the combustion and emissions of ULSD #2 which had an ignition delay of 13° CAD or 1.5ms. The PFI of n-butanol and DI of cottonseed biodiesel strategy showed a shorter ignition delay of 12° CAD or 1.45ms, because of the higher CN of biodiesel. The combustion proceeded first by the ignition of the pilot (cottonseed biodiesel) BTDC that produced a premixed combustion phase, followed by the ignition of n-butanol that produced a second spike in heat release at 2° CAD ATDC.

As engine efficiency targets continue to rise, additional improvements must consider reduction of heat transfer losses. The development of advanced heat transfer models and realistic boundary conditions for simulation based engine design both require accurate in-cylinder wall temperature measurements. A novel dual wavelength infrared diagnostic has been developed to measure in-cylinder surface temperatures with high temporal resolution. The diagnostic has the capability to measure low amplitude, high frequency temperature variations, such as those occurring during the gas exchange process. The dual wavelength ratio method has the benefit of correcting for background scattering reflections and the emission from the optical window itself. The assumption that background effects are relatively constant during an engine cycle is shown to be valid over a range of intake conditions during motoring.

With increasing interest to reduce the dependency on gasoline and diesel, alternative energy source like compressed natural gas (CNG) is a viable option for internal combustion engines. Spark-ignited (SI) CNG engine is the simplest way to utilize CNG in engines, but direct injection (DI) Diesel-CNG dual-fuel engine is known to offer improvement in combustion efficiency and reduction in exhaust gases. Dual-fuel engine has characteristics similar to both SI engine and diesel engine which makes the combustion process more complex. This paper reports the computational fluid dynamics simulation of both DI dual-fuel compression ignition (CI) and SI CNG engines. In diesel-CNG dual-fuel engine simulations and comparison to experiments, attention was on ignition delay, transition from auto-ignition to flame propagation and heat released from the combustion of diesel and gaseous fuel, as well as relevant pollutants emissions.

A means of validating numerical simulations has been developed which utilizes chemiluminescence measurements from an internal combustion engine. By incorporating OH*, CH2O* and CO2* chemiluminescence sub-mechanisms into a detailed n-heptane reaction mechanism, excited species concentration and chemiluminescence light emission were calculated. The modeled line-of-sight chemiluminescence emission allows a direct comparison of simulation results to experimentally measured chemiluminescence images obtained during combustion in an optically accessible compression ignition engine using neat n-heptane fuel. The spray model was calibrated using in-cylinder liquid penetration length Mie scattering measurements taken from the jets of the high-pressure piezo injector.

In this study, a direct injection (DI) compression ignition engine fueled with biodiesel was supplemented with n-butanol port fuel injection (PFI) in order to simultaneously reduce in cylinder nitrogen oxides formation, decrease soot and favorable modify their trade-off. The combustion and emission characteristics were investigated for regimes of 1-5 bars IMEP at 1400 rpm. By applying this methodology, for the regimes in which the n-butanol PFI was applied, the premixed charge combustion has been split into two regions of high temperature heat release, an early one, BTDC, and a second stage ATDC, oxidizing the soot formed from biodiesel combustion and therefore modifying favorable the soot-NOx trade-off. With n-butanol injection, the soot emissions showed a significant decrease as much as 90%, concomitantly with a 50% NOx reduction at higher PFI rates. Non-regulated emissions measurements showed increases in acetaldehyde with n-butanol PFI.

Recent legislation entitled “The Single Fuel Forward Policy” mandates that all vehicles deployed by the US military be operable with aviation fuel (JP-8). Therefore, the authors are conducting an investigation into the influence of JP-8 on a diesel engine's performance. The injection, combustion, and performance of JP-8, 20-50% by weight in ULSD (diesel no.2) mixtures (J20-J50) produced at room temperature, were investigated in a small indirect injection, high compression ratio (24.5), 77mm separate combustion chamber diesel engine. The effectiveness of JP8 for application in an auxiliary power unit (APU) at continuous operation (100% load) of 4.78bar bmep/2400rpm was investigated. The blends had an ignition delay of approximately 1.02ms that increased slightly in relation to the amount of JP-8 introduced. J50 and diesel no.2 exhibited similar characteristics of heat release, the premixed phase being combined with the diffusion combustion.

This paper investigates the performance of an indirect injection (IDI) diesel engine fueled with Bu25, 75% ultra-low sulfur diesel (ULSD#2) blended with 25% n-butanol by mass. N-butanol, derivable from biomass feedstock, was used given its availability as an alternative fuel that can supplement the existing limited fossil fuel supply. Combustion and emissions were investigated at 2000 rpm across loads of 4.3-7.2 bar indicated mean effective pressure (IMEP). Cylinder pressure was collected using Kistler piezoelectric transducers in the precombustion (PC) and main combustion (MC) chambers. Ignition delays ranged from 0.74 - 1.02 ms for both operated fuels. Even though n-butanol has a lower cetane number, the high swirl in the separate combustion chamber would help advance its premixed combustion. The heat release rate of Bu25 became initially 3 J/crank-angle-degree (CAD) higher than that of ULSD#2 as load increased to 7.2 bar IMEP.

Ultraviolet chemiluminescence has been observed in a diesel engine cyclinder during compression, but prior to fuel injection under engine starting conditions. During a portion of the warm-up sequence, the intensity of this emission exhibits a strong correlation to the phasing of the subsequent combustion. Engine exhaust measurements taken from a continuously misfiring, motored engine confirm the generation of formaldehyde (HCHO) in such processes. Fractions of this compound are expected to be recycled as residual to participate in the following combustion cycle. Spectral measurements taken during the compression period prior to fuel injection match the features of Emeleus' cool flame HCHO bands that have been observed during low temperature heat release reactions occurring in lean HCCI combustion. That the signal from the OH* bands is weak implies a buildup of HCHO during compression.

The authors investigated the injection and combustion characteristics of a methyl oleate (Methyl 9(Z)-octadecenoate C19H36O2; Mw 296.495), in blends with diesel No. 2 of 20-50% (wt./wt.) in order to evaluate the possibility of using it as an additive to full-bodied biodiesel for performance improvement. The FAME test fuel has been injected in an experimental single-cylinder separate combustion chamber engine with 77 mm bore, with a compression ratio of 23.5:1 at a pressure of 147 bars that proved capable of atomizing the higher viscosity fuel. The diesel fuel was blended with Methyl Oleate up to 50%, (O50) and the mixtures have shown favorable ignition characteristics, with the ignition delay of about 1.03 ms for petroleum diesel (D100) and slightly decreased for O50 at 2000 rpm with about 1% or 0.01 ms.

With the growing prices of fossil fuels and the concerns of global warming, the need to seek alternative fuels in the transportation sector is rapidly gaining momentum. This need of change has lead researchers to look beyond the typical alternative fuels for diesel engines and focus on Fatty Acids Methyl Esters (FAME), due to their high calorific value, widespread availability, and relative low cost. The authors investigated the injection and combustion of poultry fat FAME 20-50% by weight in diesel no. 2 mixtures. The dynamic viscosity of the FAME-diesel mixture has been investigated between 25-45°C and ranged from 3-5cSt increasing in correlation with the amount of FAME and lowered by the temperature increase. The new fuel containing up to 50% poultry fat FAME by weight in diesel fuel (B-50) has been injected by a piston-plunger type pump injection system. The injector had a 1x0.200 mm nozzle with a pintle tip needle and the injection pressure was 147 bar.

Low cetane JP-8 fuels have been identified as being difficult to use under conventional diesel operation. However, recent focus on low-temperature combustion (LTC) modes has led to an interest in distillate hydrocarbon fuels having high volatility and low autoignition tendency. An experimental study is performed to evaluate low-temperature combustion processes in a small-bore optically-accessible diesel engine operated in a partially-premixed combustion mode using low-cetane Sasol JP-8 fuel. This particular fuel has a cetane number of 25. Both single and dual injection strategies are tested. Since long ignition delay is a consequence of strong autoignition resistance, under the conditions examined, low cetane Sasol JP-8 combustion can only take place with a double injection strategy: one pilot injection event in the vicinity of exhaust TDC and one main injection event near firing TDC.

In this study, a Premixed Charge Compression Ignition (PCCI) obtained by sequential dual fueling strategy of n-butanol port fuel injection (PFI) and direct injection of ULSD#2 was investigated against binary mixtures combustion (defined as premixed in the tank) of n-butanol and ultra-low sulfur diesel (ULSD#2) with the same n-butanol to diesel ratios (35%, 50%, 65% by mass) in an omnivorous compression ignition engine. The hypothesis of the study is that combustion phasing (respectively CA50) can be successfully controlled by the above named strategies. Both fueling strategies controlled the high reactivity of the ULSD#2 and slowed down the chemical reactions with the low cetane number fuel, n-butanol. These processes led to fuel reactivity stratification and an increase in the ignition delay observed as the amount of n-butanol increased.

Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

Biodiesel is a desirable alternative fuel for the diesel engine due to its low engine-out soot emission tendency. When blended with petroleum-based diesel fuels, soot emissions generally decrease in proportion to the volume fraction of biodiesel in the mixture. This paper presents an experimental investigation of biodiesel impact on in-cylinder soot temperature and concentrations in a single-cylinder, small-bore, optical access, compression ignition engine. While in-cylinder soot measurements have been widely performed with two-color thermometry implemented on digital cameras, their finite dynamic range limits the observation of soot due to its dramatically different radiation intensities. To expand the dynamic range of two-color measurements, this investigation utilizes three cameras. A high-speed CMOS color camera with a wide-band Bayer filter is used to obtain simultaneous measurements of soot temperature and KL factor for high intensity soot clouds within one cycle.

Three jet fuel surrogates were compared against their target fuels in a compression ignited optical engine under a range of start-of-injection temperatures and densities. The jet fuel surrogates are representative of petroleum-based Jet-A POSF-4658, natural gas-derived S-8 POSF-4734 and coal-derived Sasol IPK POSF-5642, and were prepared from a palette of n-dodecane, n-decane, decalin, toluene, iso-octane and iso-cetane. Optical chemiluminescence and liquid penetration length measurements as well as cylinder pressure-based combustion analyses were applied to examine fuel behavior during the injection and combustion process. HCHO* emissions obtained from broadband UV imaging were used as a marker for low temperature reactivity, while 309 nm narrow band filtered imaging was applied to identify the occurrence of OH*, autoignition and high temperature reactivity.

In this study, the combustion and emissions characteristics of n-butanol/GTL and n-butanol/ultra-low sulfur diesel (ULSD) blends are compared in a single-cylinder experimental diesel engine. The n-butanol was blended with a Fischer-Tropsch (FT) gas-to-liquid (GTL) fuel, at 25% and 50% mass. N-butanol was also blended with ULSD at the same mass ratios. FT fuels are an attractive alternative to petroleum based fuels because they can be used as a drop-in fuel with existing infrastructure. N-butanol is renewable fuel capable of being produced from waste biomass sources. The investigations were conducted at 1500 rpm and three loads of 2.75, 4.75, and 6.75 IMEP, representative for the research engine. 15% exhaust gas recirculation was utilized along with a supercharger to increase the intake pressure to 1.2 bar absolute. Neat ULSD and GTL, respectively, were investigated as a baseline.