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The effects of hydrogen peroxide addition on iso-octane/air Homogeneous Charge Compression Ignition (HCCI) combustion have been investigated analytically. Particular attention was focused on the predications involving homogeneous gas-phase kinetics. Use was made of Peters' iso-octane mechanism in CHEMKIN and convective heat transfer was included in the analyses. This enabled the influences that H2O2 addition has on species concentration and ignition promotion and hence exhaust emissions to be determined. It was found that both CO and NOx emission levels could be ameliorated. The former effect is considered to be a result of the decomposition of H2O2 into OH intermediate species and hence reducing the time to ignition and the onset of combustion.

This work investigates the suitability of n-butanol for enabling PCCI, HCCI, and RCCI combustion modes to achieve clean and efficient combustion on a high compression ratio (18.2:1) diesel engine. Systematic engine tests are conducted at low and medium engine loads (6∼8 bar IMEP) and at a medium engine speed of 1500 rpm. Test results indicate that n-butanol is more suitable than diesel to enable PCCI and HCCI combustion with the same engine hardware. However, the combustion phasing control for n-butanol is demanding due to the high combustion sensitivity to variations in engine operating conditions where engine safety concerns (e.g. excessive pressure rise rates) potentially arise. While EGR is the primary measure to control the combustion phasing of n-butanol HCCI, the timing control of n-butanol direct injection in PCCI provides an additional leverage to properly phase the n-butanol combustion.

This study investigates neat n-butanol, as a cleaner power source, to directly replace conventional diesel fuels for enabling low temperature combustion on a modern common-rail diesel engine. Engine tests are performed at medium engine loads (6∼8 bar IMEP) with the single-shot injection strategy for both n-butanol and diesel fuels. As indicated by the experimental results, the combustion of neat n-butanol offers comparable engine efficiency to that of diesel while producing substantially lower NOx emissions even without the use of exhaust gas recirculation. The greater resistance to auto-ignition allows n-butanol to undergo a prolonged ignition delay for air-fuel mixing; the high volatility helps to enhance the cylinder charge homogeneity; the fuel-borne oxygen contributes to smoke reduction and, as a result, the smoke emissions of n-butanol combustion are generally at a near-zero level under the tested engine operating conditions.

Extensive experiments were conducted on a low emission DI diesel engine by using Dimethyl Carbonate (DMC) as an oxygenate fuel additive. The results indicated that smoke reduced almost linearly with fuel oxygen content. Accompanying noticeable reductions of HC and CO were attained, while a small increase in NOx was encountered. The effective reduction in smoke with DMC was maintained with intake charge CO2, which led to low NOx and smoke emissions by the combined use of oxygenated fuel and exhaust gas recirculation (EGR). Further experiments were conducted on an optically accessible combustion bomb and a thermal cracking set-up to study the mechanisms of DMC addition on smoke reduction.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

A number of cylinder-pressure derived parameters including the crank angles of maximum pressure, maximum rate of pressure rise, and 50% heat released are considered as among the desired feedback for cycle-by-cycle adaptive control of diesel combustion. For real-time computation of these parameters, the heat release analyses based on the first law of thermodynamics are used. This paper intends to identify the operating regions where the simplified heat release approach provides sufficient accuracy for control applications and also highlights those regions where its use can lead to significant errors in the calculated parameters. The effects of the cylinder charge-to-wall heat transfer and the temperature dependence of the specific heat ratio on the model performance are reported. A new computationally efficient algorithm for estimating the crank angle of 50% heat released with adequate accuracy is proposed for computation in real-time.

Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. The robustness and efficiency of LTC operation in diesel engines can be enhanced with improvements in the promptness and accuracy of combustion control. A set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations. The cylinder pressure traces were analyzed to update the heat release rate concurrently as the combustion process proceeds prior to completing an engine cycle. Engine dynamometer tests demonstrated that such prompt heat release analysis was effective to optimize the LTC and the split combustion events for better fuel efficiency and exhaust emissions.

The control of combustion phasing in homogeneous charge compression ignition (HCCI) combustion is investigated with neat n-butanol in this work. HCCI is a commonly researched combustion mode, owing to its improved thermal efficiency over conventional gasoline combustion, as well as its lower nitrogen oxide (NOx) and particulate matter emissions compared to those of diesel combustion. Despite these advantages, HCCI lacks successful widespread implementation with conventional fuels, primarily due to the lack of effective combustion phasing control. In this preliminary study, chemical kinetic simulations are conducted to study the auto-ignition characteristics of n-butanol under varied background pressures, temperatures, and dilution levels using established mechanisms in CHEMKIN software. Increasing the pressure or temperature lead to a shorter ignition delay, whereas increasing the dilution by the application of exhaust gas recirculation (EGR) leads to a longer ignition delay.

The pressure wave actions were investigated in the exhaust system of a single cylinder diesel engine through both experimental and simulation methods. The characteristics of the exhaust pressure waves under different engine operating conditions, such as engine load and exhaust backpressure, were examined. The results showed that the strength of the exhaust pressure wave was affected by both the in-cylinder pressure and the exhaust backpressure in the exhaust system during the period when the exhaust valves were open. The exhaust gas flow velocity was also estimated by the one dimensional simulation tool AVL BOOST™. The results suggested that the velocity of the exhaust gas fluctuated during the engine cycle, and followed trends similar to the exhaust pressure wave. The transient gas flow velocity was high when there was a strong compression wave, and it was reduced when the pressure fluctuations in the exhaust manifold were small.

Diesel engine exhausts commonly contain a high level of surplus oxygen and a significant amount of thermal energy. In this study the authors have theoretically investigated a way of utilizing the thermal energy and the surplus oxygen of exhaust gases to produce gaseous fuel in a rich combustor placed in an exhaust gas recirculation (EGR) loop. In the rich combustor, a small amount of diesel fuel will be catalytically reformed on a palladium/platinum based catalyst to produce hydrogen and carbon monoxide. Since the catalytic EGR reformer is incorporated in the EGR loop, it enables the partial recovery of exhaust heat. The gaseous fuel produced in the rich combustor can be brought back into the engine in a pre-mixed condition, potentially reducing soot formation. The preliminary energy efficiency analysis has been performed by using CHEMKIN and an in-house engine simulation software SAES.

Compression ignition internal combustion engines provide unmatched power density levels, making them suitable for numerous applications including heavy-duty freight trucks, marine shipping, and off-road construction vehicles. Fossil-derived diesel fuel has dominated the energy source for CI engines over the last century. To mitigate the dependency on fossil fuels and lessen anthropogenic carbon released into the atmosphere within the transportation sector, it is critical to establish a fuel source which is produced from renewable energy sources, all the while matching the high-power density demands of various applications. Dimethyl ether (DME) has been used in non-combustion applications for several decades and is an attractive fuel for CI engines because of its high reactivity, superior volatility to diesel, and low soot tendency. A range of feedstock sources can produce DME via the catalysis of syngas.

The development of the present day spark ignition (SI) engines has imposed higher demands for on-board ignition systems. Proper design of the ignition system circuit is required to achieve certain spark performances. In this paper, the authors studied the relationship between spark discharge characteristics and different inductive spark ignition circuit parameters with the help of a simplified circuit model. The circuit model catches the principle behavior of the spark discharge process. Simulation results obtained from the model were compared with experimental data for model verification. Different circuit model parameters were then tuned to study the effect of those on spark discharge current and spark energy properties. The parameters studied include the ignition coil coupling coefficient, ignition coil primary and secondary inductances, secondary circuit series resistance and spark plug gap width.

Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.

A novel catalytic converter technology, employing periodical reversal of gas flow through the oxidation catalyst monolith, is being developed for treatment of exhaust gas from diesel engines fueled by natural gas in combination with diesel fuel. This technology allows to trap heat energy inside the monolith and thus efficiently destroy methane at converter inlet temperature as low as ambient. This paper describes the results of the initial stage of the converter development, including development of the mathematical model, computer simulation, and prototype testing. Simulation results indicate that dual fuel engine equipped with the reverse-flow converter could exceed the required destruction standards for hydrocarbons, including methane.

Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.

Exhaust Gas Recirculation (EGR) valves have been used in diesel engine operation to reduce NOx emissions. In EGR valve operation, the amount of exhaust gas re-circulating back into the intake manifold is controlled through the open position of the valve plate to keep the combustion temperature lower for NOx emission reduction. Different methods have been proposed to control the EGR valve. However, most of the approaches do not have the desired accuracy and the response time, which is critical for the after-treatment performance in low temperature diesel combustion. In this paper, the model of a motor driven EGR valve is first identified through experiments and then the Generalized Predictive Control (GPC) method which is an effective Model Predictive Control (MPC) method is applied to control the plate position of the valve.

The dual-fuel application using ethanol and diesel fuels can substantially improve the classical trade-off between oxides of nitrogen (NOx) and smoke, especially at moderate-to-high load conditions. However, at low engine load levels, the use of a low reactivity fuel in the dual-fuel application usually leads to increased incomplete combustion products that in turn result in a significant reduction of the engine thermal efficiency. In this work, engine tests are conducted on a high compression ratio, single cylinder dual-fuel engine that incorporates the diesel direct-injection and ethanol port-injection. Engine load levels are identified, at which, diesel combustion offers better efficiency than the dual-fuel combustion while attaining low NOx and smoke emissions. Thereafter, a cycle-to-cycle based closed-loop controller is implemented for the combustion phasing and engine load control in both the diesel and dual-fuel combustion regimes.

Taking advantages of high speed RGB video cameras, the two-color method can be implemented with a relatively simple setup to obtain the temporal development of the two dimensional temperature and soot (KL) distributions in a reacting diesel jet. However, several issues such as the selection of the two wavelengths, the role of bandpass filters, and the proper optical settings, etc. should be known to obtain a reliable measurement. This paper, at first, discusses about the uncertainties in the measurement of temperature and KL distributions in the diesel flame by the two-color method using the high speed RGB video camera. Since n-butanol, as an alternative renewable fuel, has the potential application in diesel engines, the characteristic of spray combustion of diesel-butanol blends under the diesel-like ambient conditions in a pre-burning constant-volume combustion chamber is studied.

In order to meet the future carbon dioxide legislation, advanced clean combustion engines are tending to employ low temperature diluted combustion strategies along with intensified cylinder charge motion. The diluted mixtures are made by means of excess air admission or exhaust gas recirculation. A slower combustion speed during the early flame kernel development because of the suppressed mixture reactivity will reduce the reliability of the ignition process and the overall combustion stability. In an effort to address this issue, an ignition strategy using a multi-pole spark igniter is tested in this work. The igniter uses three electrically independent spark gaps to allow three spatially distributed spark discharges. The multi-pole spark strategy displayed more advanced combustion phasing and lower phasing variability compared to single spark discharges.

In this study, impacts of neat n-butanol fuel injection parameters on direct injection (DI) compression ignition (CI) engine performance were investigated to gain knowledge for understanding the fuel injection strategies for n-butanol. The engine tests were conducted on a four-stroke single-cylinder DI CI engine with a compression ratio of 18.2:1. The effects of fuel injection pressure (40, 60 and 90 MPa) and injection timing in a single injection strategy were investigated. The results showed that an increase in injection pressure significantly reduced nitrogen oxides (NOx) emissions which is the opposite trend seen in conventional diesel combustion. The parallel use of a higher injection pressure and retarded injection timing was a proposed method to reduce NOx and cylinder pressure rise rate simultaneously. NOx was further reduced by using exhaust gas recirculation (EGR) while keeping near zero soot emissions.