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This paper describes the after-treatment technology that could be used to meet a future BS-VII standard, considering close-coupled SCR (cc-SCR) to help start NOx conversion earlier. Both active (Cu/Fe-SCR based) and passive (V-SCR based) systems have the potential to meet emission limits. V-SCR may be considered in the rear position because V-SCR shows a fast response with very low N2O formation. Next-gen V-SCR technology shows significantly improved performance and durability closer to Cu-SCR. The steady-state NOx conversions over Next-Gen V-SCR were better than BS-VI V-SCR in both fresh and aged-580°C/100h conditions. High durability was also observed after engine aging of 1000h (WHTC + high load). Another big challenge in BS VII could be the PN10 requirement. With enhanced filtration coating (EFC) technology, PN emissions drop drastically in comparison to Euro VI reference without EFC to meet a future BS VII.

The New York State Department of Environmental Conservation (DEC) and Environment Canada have jointly participated along with partners the New York City Metropolitan Transit Agency (MTA); Johnson Matthey, Environmental Catalysts & Technologies; Equilon Enterprises, LLC and Corning, Inc. in a project to evaluate the effect of various combinations of fuels and aftertreatment configurations on diesel emissions. Emissions measurements were performed during engine dynamometer testing of an International DT 466E heavy-duty diesel engine. Fuels tested in the study were Diesel Fuel 1 and 2, low sulfur diesel (150 ppm), two ultralow sulfur fuels (<30 ppm), Fischer-Tropsch, Biodiesel, PuriNOx™ and two Ethanol-Diesel blends. Configurations tested were: engine out, and diesel oxidation catalyst, continuously regenerating diesel filter, and exhaust gas recirculation aftertreatment. In general, the use of more aggressive aftertreatment (ie.

Future emissions regulations proposed for the Asian automotive industry (BS VI regulations for India and NS VI regulations for China) are strict and similar to EU VI regulations. As a result, they will require both advanced NOx control as well as advanced Particulate Matter (PM) control. This will drive implementation of full Catalyzed Diesel Particulate Filter (cDPF) and simultaneous NOx control using Selective Catalytic Reduction (SCR) technologies. In this work, we present the performance of various Diesel Oxidation Catalyst (DOC), cDPF, SCR and Ammonia slip catalyst (ASC) systems utilizing the World Harmonized Transient Cycle (WHTC). Aftertreatment Systems (ATS) required for both active and passive filter regeneration applications will be discussed. The sensitivity of key design parameters like catalyst technology, PGM loading, catalyst sizing to meet the regulation limits has been investigated.

For diesel emission control technologies, reduction efficiencies of Particulate Matter (PM) control systems have been traditionally reported based on mass-based criteria. However, particle number-based criteria are now receiving increased attention. In this paper, results of real-time particle size distribution and number based evaluation of the effectiveness of multiple PM control technologies are reported on an HDD engine. An Engine Exhaust Particle Sizer (EEPS) was used for comparative analysis. The technologies that were evaluated included diesel oxidation catalysts (DOC), a DOC with an uncatalyzed wall-flow filter as a continuously regenerating diesel particulate filter (CR-DPF) system, a DOC with a catalytically coated wall-flow filter as a catalyzed CR-DPF (CCR-DPF), and a DOC with a partial filter as a continuously regenerating partial filter (CR-PF).

Previous studies have shown that regenerating particulate filters are very effective at reducing particulate matter emissions from diesel engines. Some particulate filters are passive devices that can be installed in place of the muffler on both new and older model diesel engines. These passive devices could potentially be used to retrofit large numbers of trucks and buses already in service, to substantially reduce particulate matter emissions. Catalyst-type particulate filters must be used with diesel fuels having low sulfur content to avoid poisoning the catalyst. A project has been launched to evaluate a truck fleet retrofitted with two types of passive particulate filter systems and operating on diesel fuel having ultra-low sulfur content. The objective of this project is to evaluate new particulate filter and fuel technology in service, using a fleet of twenty Class 8 grocery store trucks. This paper summarizes the truck fleet start-up experience.

Emissions from heavy-duty vehicles may be reduced through the introduction of clean diesel formulations, and through the use of catalyzed particulate matter filters that can enjoy increased longevity and performance if ultra-low sulfur diesel is used. Twenty over-the-road tractors with Detroit Diesel Series 60 engines were selected for this study. Five trucks were operated on California (CA) specification diesel (CARB), five were operated on ARCO (now BP Amoco) EC diesel (ECD), five were operated on ARCO ECD with a Johnson-Matthey Continuously Regenerating Technology (CRT) filter and five were operated on ARCO ECD with an Engelhard Diesel Particulate Filter (DPX). The truck emissions were characterized using a transportable chassis dynamometer, full-scale dilution tunnel, research grade gas analyzers and filters for particulate matter (PM) mass collection. Two test schedules, the 5 mile route and the city-suburban (heavy vehicle) route (CSR), were employed.

The retrofitting of diesel engines with oxidation catalyst and particulate filter technology for the reduction of particulate matter (PM), hydrocarbons (HC) and carbon monoxide (CO) emissions has become an established practice. The design and performance of such systems have been commercially proven to the point that the application of these technologies is a cost effective means for states to effectively meet pollution reduction goals. One of the reasons that these technologies are so widely applied is because they can be sized and fitted based on easily measurable vehicle parameters and published engine emission information. These devices generally work passively with basic temperature and back pressure monitoring devices being used to alert the operator to upset conditions. The application of an effective NOx reduction technology in similar retrofit installation, is more complicated. There are no passive NOx reduction technologies that can be retrofit onto HDD vehicles.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. Typical 2013 Heavy Duty Diesel emission control systems include a DOC upstream of a catalyzed soot filter (CSF) which is followed by urea injection and the SCR sub-assembly. There is a strong desire to further increase the NOx conversion capability of such systems, which would enable additional fuel economy savings by allowing engines to be calibrated to higher engine-out NOx levels. One potential approach is to replace the CSF with a diesel particulate filter coated with SCR catalysts (SCRF® technology, hereafter referred to as SCR-DPF) while keeping the flow-through SCR elements downstream, which essentially increases the SCR volume in the after-treatment assembly without affecting the overall packaging.

Selective Catalytic Reduction (SCR) systems have been demonstrated as effective solutions for controlling NOx emissions from Heavy Duty diesel engines. Future HD diesel engines are being designed for higher engine out NOx to improve fuel economy, while discussions are in progress for tightening NOx emissions from HD engines post 2020. This will require increasingly higher NOx conversions across the emission control system and will challenge the current aftertreatment designs. Typical 2010/2013 Heavy Duty systems include a diesel oxidation catalyst (DOC) along with a catalyzed diesel particulate filter (CDPF) in addition to the SCR sub-assembly. For future aftertreatment designs, advanced technologies such as cold start concept (dCSC™) catalyst, SCR coated on filter (SCRF® hereafter referred to as SCR-DPF) and SCR coated on high porous flow through substrates can be utilized to achieve high NOx conversions, in combination with improved control strategies.

Selective Catalytic Reduction (SCR) systems have been demonstrated as effective solutions for controlling NOx emissions from Heavy Duty diesel engines. Future HD diesel engines are being designed for higher engine out NOx to improve fuel economy, which will require increasingly higher NOx conversion to meet emission regulations. For future aftertreatment designs, advanced technologies such as SCR coated on filter (SCRF®) and SCR coated on high porous flow through substrates can be utilized to achieve high NOx conversion. In this work, different options were evaluated for achieving high NOx conversion. First, high performance NOx control catalysts were designed by using SCRF unit followed by additional SCR on high porosity substrates. Second, different control strategies were evaluated to understand the effect of reductant dosing strategy and thermal management on NOx conversion. Tests were carried out on a HD engine under transient test cycles.

The EPA implemented the Urban Bus Retrofit/Rebuild (UBRR) Program for transit buses built before 1994 in an effort to lower the amount of PM emissions in densely populated urban areas. The objective of the program is to provide certified emission control technologies that reduce PM emissions from older buses by 25% or to below 0.1 g/bhp-hr. This paper reviews the development of a retrofit kit that has been certified under the UBRR program to meet the 0.1 g/bhp-hr PM emission requirements on DDC 6V92TA engines with both mechanical (MUI) and electronic (DDEC) fuel injection controls. The kit is a combination of specific and modified engine parts and a catalytic exhaust after-treatment device. The kit replaces existing parts with a new camshaft, a uniquely configured cylinder kit and specified turbocharger, blower and injector. For the MUI engines the cam timing, injector height and fuel modulator are set at specific values to achieve the lowest possible PM level.

Diesel oxidation catalyst and particulate filter technologies are well established and their applications are well known. However, there are certain limitations with both technologies due to their inherent technical characteristics. Both technologies get 75-90% reduction of HC and CO. A typical oxidation catalyst can be applied to almost any heavy duty diesel application and achieve 20 to 30% reduction in PM mass but no significant reduction in the number of PM particles. On the other hand, diesel particulate filters are very effective at removing >90% of the particles by mass and >99% by number. Unfortunately, passive DPF technology cannot be applied to all applications since the filter regeneration is limited by engine out NOx to PM ratio as well as exhaust temperature. For this reason, particulate filters can not universally be applied to older “dirtier” engines with high PM emissions.

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. Typical 2010 Heavy-Duty systems include a DOC along with a catalyzed soot filter (CSF) in addition to the SCR sub-assembly. There is a strong desire to further increase the NOx conversion capability of such systems, to enable additional fuel economy savings by allowing engines to be calibrated to higher engine-out NOx levels. One potential approach is to replace the CSF with a diesel particulate filter coated with SCR catalysts (SCR-DPF) while keeping the flow-through SCR elements downstream, which essentially increases the SCR volume in the after-treatment assembly without affecting the overall packaging. In this work, a system consisting of SCR-DPF was evaluated in comparison to the DOC + CSF components from a commercial 2010 DOC + CSF + SCR system on an engine with the engine EGR on (standard engine-out NOx) and off (high engine-out NOx).

Selective Catalytic Reduction (SCR) catalysts have been demonstrated as an effective solution for controlling NOx emissions from diesel engines. There is a drive to reduce the overall packaging volume of the aftertreatment system for these applications. In addition, more active SCR catalysts will be needed as the applications become more challenging: e.g. lower temperatures and higher engine out NOx, for fuel consumption improvements. One approach to meet the challenges of reduced volume and/or higher NOx reduction is to increase the active site density of the SCR catalyst by coating higher amount of SCR catalyst on high porosity substrates (HPS). This approach could enable the reduction of the overall packaging volume while maintaining similar NOx conversion as compared to 2010/2013 systems, or improve the NOx reduction performance for equivalent volume and NH3 slip.

Diesel Particulate Filters (DPFs) such as the Continuously Regenerating Technology (CRT®) particulate filters are known to be highly effective in reducing PM emissions from diesel engines. Passive DPFs such as the CRT filter operate by collecting soot in the filter and subsequently oxidizing this soot in the presence of NO2 generated by an upstream Diesel Oxidation Catalyst (DOC). Both the NO2 generation and subsequent soot oxidation reactions require a certain minimum exhaust temperature. In addition, the engine out NOx to PM ratio is also critical for continuous and successful regeneration of the filter. However, these criteria may not always be met, particularly on low temperature applications such as refuse vehicles and newer low NOx (2.5 g/bhp-hr NOx) engines. This paper discusses the development of an actively regenerating diesel particulate filter (ACR-DPF) system for retrofit applications on heavy duty diesel vehicles.

Honeycomb based diesel particulate filters have proven to be extremely effective in the removal of diesel soot. Under certain conditions, involving heavy soot loads and a shift of the engine into the idle mode during the early stages of the regeneration process, the current designs of cordierite filters have shown some tendency toward partial melting. A brief review of the SAE literature is presented, indicating that the temperatures reached during regeneration decrease substantially as the bulk heat capacity of the filter increases. Analysis of these literature data indicates that the top temperatures experienced during regeneration can be decreased by hundreds of degrees, by relatively modest increases in the bulk heat capacity of the bodies. New data are presented confirming how the top temperature varies with different filter designs in which the bulk heat capacity varies.

The modern Diesel engine is one of the most versatile power sources available for mobile applications. The high fuel economy and torque of the Diesel engine has long resulted in global application for heavy-duty applications. Moreover, the high power and excellent driveability of today's turbo-charged small high-speed Diesel engines, coupled with their low CO2 emissions, has resulted in an increasing demand for Diesel powered light-duty vehicles. However, the demand for Diesel vehicles can only be realised if their exhaust emissions meet the increasingly stringent emissions legislation being introduced around the world. In the USA, both HDD and LDD vehicles are meeting strict emissions legislations since 2007 with the introduction of particle filters which will be further restricted from 2010 with the use of additional NOx contr5ol systems. In Europe, similar strict requirements are being implemented with Euro IV, Euro V and finally through Euro VI legislations.

Particulate emission from diesel engines is one of the most important pollutants in urban areas. With increasing worldwide regulatory requirements to lower particulate matter (PM) standards for heavy duty diesel powered vehicles, the interest in diesel particulate filter based emission control solutions such as the Continuously Regenerating Technology (CRT®) have significantly increased. This system has been applied to thousands of heavy-duty diesel vehicles in Europe over the last six years to meet various local and governmental requirements, while recently introduced in the US. Among the numerous demonstration programs taking place in the US, one important one is the evaluation of CRT filter systems on urban transit buses in NY City. Here, several NY City transit buses with DDC Series 50 engines have been equipped with CRT filters and operating on ultra low sulfur diesel (< 30 ppm S) in transit service in Manhattan since February 2000.

Particulate emission control from diesel engines is one of the major concerns in the urban areas in California. Recently, regulations have been proposed for stringent PM emission requirements from both existing and new diesel engines. As a result, particulate emission control from urban diesel engines using advanced particulate filter technology is being evaluated at several locations in California. Although ceramic based particle filters are well known for high PM reductions, the lack of effective and durable regeneration system has limited their applications. The continuously regenerated diesel particulate filter (CRDPF) technology discussed in this presentation, solves this problem by catalytically oxidizing NO present in the diesel exhaust to NO2 which is utilized to continuously combust the engine soot under the typical diesel engine operating condition.

Since early 2010, most new medium- and heavy-duty diesel vehicles in the US rely on urea-based Selective Catalytic Reduction (SCR) technology for meeting the most stringent regulations on nitrogen oxides (NOx) emissions in the world today. Catalyst technologies of choice include Copper (Cu)- and Iron (Fe)-based SCR. In this work, the performances of Fe-SCR and Cu-SCR were investigated in the most commonly used DOC + CSF + SCR system configuration. Cu-SCR offered advantages over Fe-SCR in terms of low temperature conversion, NO₂:NOx ratio tolerance and NH₃ slip, while Fe-SCR demonstrated superior performance under optimized NO₂:NOx ratio and at higher temperatures. The Cu-SCR catalyst displayed less tolerance to sulfur (S) exposure. Reactor testing has shown that Cu-SCR catalysts deactivate at low temperature when poisoned by sulfur.