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In order to deeply investigate and improve the complete path from biofuel production to combustion, the cluster of excellence “Tailor-Made Fuels from Biomass” was installed at RWTH Aachen University in 2007. Recently, new pathways have been discovered to synthesize octanol [1] and di-n-butylether (DNBE). These molecules are identical in the number of included hydrogen, oxygen and carbon atoms, but differ in the molecular structure: for octanol, the oxygen atom is at the end of the molecule, whereas for DNBE it is located in the middle. In this paper the utilization of octanol and DNBE in a state-of-the-art single cylinder diesel research engine will be discussed. The major interest has been on engine emissions (NOx, PM, HC, CO, noise) compared to conventional diesel fuel.

When considered along with Phase 2 Greenhouse Gas (GHG) requirements, the proposed Air Resource Board (ARB) nitrogen oxide (NOx) emission limit of 0.02 g/bhp-hr will be very challenging to achieve as the trade-off between fuel consumption and NOx emissions is not favorable. To meet any future ultra-low NOx emission regulation, the NOx conversion efficiency during the cold start of the emission test cycles needs to be improved. In such a scenario, apart from changes in aftertreatment layout and formulation, additional heating measures will be required. In this article, a physics-based model for an advanced aftertreatment system comprising of a diesel oxidation catalyst (DOC), an SCR-catalyzed diesel particulate filter (SDPF), a stand-alone selective catalytic reduction (SCR), and an ammonia slip catalyst (ASC) was calibrated against experimental data.

Stringent global emissions legislation demands effective NOx reduction strategies, particularly for the aftertreatment, and current typical liquid urea SCR systems achieve efficiencies greater than 90% [1]. However, with such high-performing systems comes the trade-off of requiring a tank of reductant (urea water solution) to be filled regularly, usually as soon as the fuel fillings or as far as oil changes. Advantages of solid reductants, particularly ammonium carbamate, include greater ammonia densities, enabling the reductant refill interval to be extended several multiples versus a given reductant volume of urea, or diesel exhaust fluid (DEF) [2]. An additional advantage is direct gaseous ammonia dosing, enabling reductant injection at lower exhaust temperatures to widen its operational coverage achieving greater emissions reduction potential [3], as well as eliminating deposits, reducing mixing lengths, and avoiding freeze/thaw risks and investments.

Fuel properties are always considered as one of the main factors to diesel engines concerning performance and emission discussions. There are still challenges for researchers to identify the most correlating and non-correlating fuel properties and their effects on engine behavior. Statistical analyses have been applied in this study to derive the most un-correlating properties. In parallel, sensitivity analysis was performed for the fuel properties as well as to the emission and performance of the engine. On one hand, two different analyses were implemented; one with consideration of both, non-aromatic and aromatic fuels, and the other were performed separately for each individual fuel group. The results offer a different influence on each type of analysis. Finally, by considering both methods, most common correlating and non-correlating properties have been derived.

Substitution of diesel fuel with natural gas in heavy-duty diesel engines offers significant advantages in terms of operating cost, as well as NOx, PM emissions and greenhouse gas emissions. However, the challenges of high THC and CO emissions, combustion stability, exhaust temperatures and pressure rise rates limit the substitution levels across the engine operating map and necessitate an optimized combustion strategy. Reactivity controlled compression ignition (RCCI) combustion has shown promise in regard to improving combustion efficiency at low and medium loads and simultaneously reducing NOx emissions at higher loads. RCCI combustion exploits the difference in reactivity between two fuels by introducing a less reactive fuel, such as natural gas, along with air during the intake stroke and igniting the air-CNG mixture by injecting a higher reactivity fuel, such as diesel, later in the compression stroke.

The Environmental Protection Agency (EPA) and California Air Resources Board (CARB) have recently announced rulemakings focused on tighter emission limits for oxides of nitrogen (NOx) from heavy-duty trucks. As part of the new rulemaking CARB has proposed a Low Load Cycle (LLC) to specifically evaluate NOx emission performance over real-world urban and vocational operation typically characterized by low engine loads, thereby demanding the implementation of continuous active thermal management of the engine and aftertreatment system. This significant drop in NOx levels along with continued reduction in the Green House Gas (GHG) limits poses a more significant challenge for the engine developer as the conventional emission reduction approaches for one species will likely result in an undesirable increase in the other species.

Measures to improve the thermal efficiency of heavy- duty commercial vehicle engines with compression ignition continue to be an important topic in research and development. Increasing the compression ratio (CR) of the engine is a direct way to increase the process efficiency. However, to ensure an optimum combustion and emission behavior at very high compression ratio is challenging. In addition, the combustion and emission behavior of heavy-duty compression ignition (CI) engines with compression ratios beyond 21:1 has hardly been reported in the literature. In this study, a combination of the experimental and 3D-CFD based numerical methods were applied to a high compression ratio heavy duty engine to analyze the combustion process and emissions so as to evaluate the thermal efficiency improvement potential.

Due to experimental challenges, combustion of diesel-like jets has rarely been characterized by laser-based quantitative multiscalar measurements. In this work, recently developed laser diagnostics for combustion temperature and the concentrations of CO, O2, and NO are applied to a diesel-like jet, using a highly oxygenated fuel. The diagnostic is based on spontaneous Raman scattering (SRS) and laser-induced fluorescence (LIF) methods. Line imaging yields multiscalar profiles across the jet cross section. Measurements turn out to be particularly accurate, because near-stoichiometric combustion occurs in the central region of the jet. Thereby, experimental cross-influences by light attenuation and interfering emissions are greatly reduced compared to the combustion of conventional, sooting diesel fuel jets. This is achieved by fuel oxygenation and enhanced premixing.