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This paper covers the development of computer simulation models of the Vapor Compression Distillation (VCD) process, the Super Critical Water Oxidation (SCWO) process, and two versions of a Vapor Phase Catalytic Ammonia Reduction (VPCAR) process. These process level models have combined into two Integrated Water Reclamation Systems (IWRS). Results from these integrated models, in conjunction with other data sources, have been used to develop a preliminary comparison of the two systems. Also discussed in this paper is the development of a Vapor Phase Catalytic Ammonia Reduction teststand and the development of a new urine analog for use with the teststand and computer models.

Waste management is a critical component of life support systems for manned space exploration. Human occupied spacecraft and extraterrestrial habitats must be able to effectively manage the waste generated throughout the entire mission duration. The requirements for waste systems may vary according to specific mission scenarios but all waste management operations must allow for the effective collection, containment, processing, and storage of unwanted materials. NASA's Crew Exploration Vehicle usually referred to as the CEV, will have limited volume for equipment and crew. Technologies that reduce waste storage volume free up valuable space for other equipment. Waste storage volume is a major driver for the Orion waste compactor design. Current efforts at NASA Ames Research Center involve the development of two different prototype compactors designed to minimize trash storage space.

This paper presents the results of a program to develop the next generation Vapor Phase Catalytic Ammonia Removal (VPCAR) system. VPCAR is a spacecraft water recycling system designed by NASA and constructed by Water Reuse Technology Inc. The technology has been identified by NASA to be the next generation water recycling system [1]. It is designed specifically for a Mars transit vehicle mission. This paper provides a description of the process and an evaluation of the performance of the new system. The equivalent system mass (ESM) is calculated and compared to the existing state-of-the art. A description of the contracting mechanism used to construct the new system is also provided.

A half scale version of a device called the Plastic Melt Waste Compactor prototype is being developed at NASA Ames Research Center to deal with plastic based wastes that are expected to be encountered in future human space exploration scenarios such as Lunar or Martian Missions. The Plastic Melt Waste Compactor design was based on the types of wastes produced on the International Space Station, Space Shuttle, MIR and Skylab missions. The half scale prototype unit will lead to the development of a full scale Plastic Melt Waste Compactor prototype that is representative of flight hardware that would be used on near and far term space missions. This paper details the progress of the Plastic Melt Waste Compactor Development effort by the Solid Waste Management group at NASA Ames Research Center.

Future long-duration human space exploration missions will require increased system autonomy and reliability with fidelities beyond the present level of life support technology. Long-duration planetary missions will require Advanced Life Support (ALS) systems to provide methods for crop and food production, air and water recycling, and solid waste resource recovery. Among these principal life support functional areas, solid waste processing will need significant development. Because of this need, a solid waste processing and resource recovery (SWPRR) workshop was held in April 2000, to assess solid waste processing technologies. The purpose of the workshop was to gather data and provide input to the National Aeronautics and Space Administration (NASA) for a solid waste processing research and technology development (R&TD) strategy. This paper discusses the workshop assessment methodology and the results.

Solid Waste Management (SWM) requirements need to be defined prior to determining what technologies should be developed by the Advanced Life Support (ALS) Project. Since future waste streams will be highly mission-dependent, missions need to be defined prior to developing SWM requirements. The SWM Working Group has used the mission architectures outlined in the System Integration, Modeling and Analysis (SIMA) Element Reference Missions Document (RMD) as a starting point in the requirement development process. The missions examined include the International Space Station (ISS), a Mars Dual Lander mission, and a Mars Base. The SWM Element has also identified common SWM functionalities needed for future missions. These functionalities include: acceptance, transport, processing, storage, monitoring and control, and disposal. Requirements in each of these six areas are currently being developed for the selected missions.

Pyrolysis is a very versatile waste processing technology which can be tailored to produce a variety of solid, liquid and/or gaseous products. The pyrolysis processing of pure and mixed solid waste streams has been under investigation for several decades for terrestrial use and a few commercial units have been built for niche applications. Pyrolysis has more recently been considered for the processing of mixed solid wastes in space. While pyrolysis units can easily handle mixed solid waste streams, the dependence of the pyrolysis product distribution on the component composition is not well known. It is often assumed that the waste components (e.g., food, paper, plastic) behave independently, but this is a generalization that can usually only be applied to the overall weight loss and not always to the yields of individual gas species.

This paper describes work that has begun at Ames Research Center on development of a heat melt compactor that can be used on near term and future missions. The heat melt compactor can handle wastes with a significant plastic composition and minimize crew interaction. The current solid waste management system employed on the International Space Station (ISS) consists of compaction, storage, and disposal. Wastes such as plastic food packaging and trash are compacted manually and wrapped in duct taped “footballs” by the astronauts. Much of the waste is simply loaded into the empty Russian Progress spacecraft that is used to bring supplies to ISS. The progress spacecraft and its contents are intentionally burned up in the earth's atmosphere during reentry. This manual method of trash management on ISS is a wasteful use of crew time and does not transition well to far term missions.

Oxidation is one of a number of technologies that are being considered for waste management and resource recovery from waste materials generated on board space missions. Oxidation processes are a very effective and efficient means of clean and complete conversion of waste materials to sterile products. However, because oxidation uses oxygen there is an “oxygen penalty” associated either with resupply of oxygen or with recycling oxygen from some other source. This paper is a systems approach to the issue of oxygen penalty in life support systems and presents findings on the oxygen penalty associated with an integrated oxidation-Sabatier-Oxygen Generation System (OGS) for waste management in an Advanced Life Support System. The findings reveal that such an integrated system can be operated to form a variety of useful products without a significant oxygen penalty.

Management of human feces and wastes is a major challenge in space vehicles due to the potential biohazards and malodorous compounds emanating during collection and storage of feces and wastes. To facilitate safe, yet realistic human waste management research, we have previously developed human fecal simulants for research activities. The odoriferous compounds in feces and wastes reduce the quality of life for astronauts, can reduce performance, and can even cause health problems. The major odoriferous compounds of concern belong to four groups of chemicals, volatile fatty acids, volatile sulfurous compounds, nitrogenous compounds and phenols. This paper attempts to review the problem of odor detection and odor control with advanced technology. There has been considerable progress in odor detection and control in the animal industry and in the dental profession.

Dewatering of wet waste during space exploration missions is important for crew safety as it stabilizes the waste. It may also be used to recover water and serve as a preconditioning step for waste compaction. A thermoelectric cooler (TEC)- driven lyophilizer is under development at NASA Ames Research Center for this purpose. It has three major components: (i) an evaporator section where water vapor sublimes from the frozen waste, (ii) a condenser section where this water vapor deposits as ice, and (iii) a TEC section which serves as a heat pump to transfer heat from the condenser to the evaporator. This paper analyses the heat and mass transfer processes in the lyophilizer in an effort to understand the ice formation behavior in the condenser. The analysis is supported by experimental observations of ice formation patterns in two different condenser units.

Mixed liquid/solid wastes, including feces, water processor effluents, and food waste, can be lyophilized (freeze-dried) to recover the water they contain and stabilize the solids that remain. Our previous research has demonstrated the potential benefits of using thermoelectric heat pumps to build a lyophilizer for processing waste in microgravity. These results were used to build a working prototype suitable for ground-based human testing. This paper describes the prototype design and presents results of functional and performance tests.

This paper presents results of research on a solid waste dryer, based of the process of lyophilization, which recovers water and stabilizes solid waste. A lyophilizer has been developed and tested that uses thermoelectric heat pumps (TECs) to recycle heat during drying. The properties of TECs facilitate direct measurement of heat flow rates, and heat flow data are used to evaluate a heat and mass transfer model of the thermoelectric lyophilizer. Data are consistent with the theoretical model in most respects. Practical problems such as insulation and vacuum maintenance are minor in this system. However, the model’s assumption of a uniformly retreating ice layer during drying is valid only for the first 30% of water removed. Beyond this point, a shrinking core or lens model is more appropriate. Heat transfer to the shrinking core surrounded by dried material is slow.

An energy-efficient lyophilization technique is being developed to recover water from highly contaminated spacecraft waste streams. In the lyophilization process, water in an aqueous waste is frozen and then sublimed, separating the waste into a dried solid material and liquid water. This technology is ideally suited to applications such as the Mars Reference Mission, where water recovery rates approaching 100% are desirable but production of CO2 is not. Candidate wastes include feces, concentrated brines from water processors, and other solid wastes that contain water. To operate in microgravity, and to minimize power consumption, thermoelectric heat pumps can be used in place of traditional fluid cycle heat pumps. A mathematical model of a thermoelectric lyophilizer is described and used to generate energy use and processing rate estimates.

Of the many competing technologies for resource recovery from solid wastes for long duration manned missions such as a lunar or Mars base, incineration technology is one of the most promising and certainly the most well developed in a terrestrial sense. Various factors are involved in the design of an optimum fluidized bed incinerator for inedible biomass. The factors include variability of moisture in the biomass, the ash content, and the amount of fuel nitrogen in the biomass. The crop mixture in the waste will vary; consequently the nature of the waste, the nitrogen content, and the biomass heating values will vary as well. Variation in feed will result in variation in the amount of contaminants such as nitrogen oxides that are produced in the combustion part of the incinerator. The incinerator must be robust enough to handle this variability. Research at NASA Ames Research Center using the fluidized bed incinerator has yielded valuable data on system parameters and variables.

In February 2004 NASA released “The Vision for Space Exploration.” The important goals outlined in this document include extending human presence in the solar system culminating in the exploration of Mars. Unprocessed waste poses a biological hazard to crew health and morale. The waste processing methods currently under consideration include incineration, microbial oxidation, pyrolysis and compaction. Although each has advantages, no single method has yet been developed that is safe, recovers valuable resources including oxygen and water, and has low energy and space requirements. Thus, the objective of this project is to develop a low temperature oxidation process to convert waste cleanly and rapidly to carbon dioxide and water. In the Phase I project, TDA Research, Inc. demonstrated the potential of a low temperature oxidation process using ozone. In the current Phase II project, TDA and NASA Ames Research Center are developing a pilot scale low temperature ozone oxidation system.

One of the major problems associated with solid waste processing technologies is effluent contaminants that are released in gaseous forms from the processes. This is a concern in both biological as well as physicochemical solid waste processing. Carbon dioxide (CO2), the major gas released, does not present a serious problem and there are currently in place a number of flight-qualified technologies for CO2 removal. However, a number of other gases, in particular NOx, SO2, NH3, and various hydrocarbons (e.g. CH4) do present health hazards to the crew members in space habitats. In the present configuration of solid waste processing in the International Space Station (ISS), some of these gases are removed by the Trace Contaminant Control System (TCCS), demands a major resupply. Reduction of the resupply can be effective by using catalyst impregnated carbon nanotubes. For example, NO decomposition to N2 and O2 is thermodynamically favored.

We present a device for collecting and storing feces in microgravity that is user-friendly yet suitable for spacecraft in which cabin volume and mass are constrained. On Apollo missions, the commode function was served using disposable plastic bags, which proved time-consuming and caused odor problems. On Skylab, the space shuttle, and the International Space Station, toilets have used airflow beneath a seat to control odors and collect feces. We propose to incorporate airflow into a system of self-compacting, self-drying collection and stowage bags, providing the benefits of previous commodes while minimizing mass and volume. Each collection bag consists of an inner layer of hydrophobic membrane that is permeable to air but not liquid or solid waste, an outer layer of impermeable plastic, and a collapsible spacer separating the inner and outer layers. Filled bags are connected to space vacuum, compacting and drying their contents.

Pyrolysis processing of solid waste in space will inevitably lead to carbon formation as a primary pyrolysis product. The amount of carbon depends on the composition of the starting materials and the pyrolysis conditions (temperature, heating rate, residence time, pressure). Many paper and plastic materials produce almost no carbon residue upon pyrolysis, while most plant biomass materials or human wastes will yield up to 20-40 weight percent on a dry, as-received basis. In cases where carbon production is significant, it can be stored for later use to produce CO2 for plant growth. Alternatively it can be partly gasified by an oxidizing gas (e.g., CO2, H2O, O2) in order to produce activated carbon. Activated carbons have a unique capability of strongly absorbing a great variety of species, ranging from SO2 and NOx, trace organics, mercury, and other heavy metals.

Pyrolysis is a technology that can be used on future space missions to convert wastes to an inert char, water, and gases. The gases can be easily vented overboard on near term missions. For far term missions the gases could be directed to a combustor or recycled. The conversion to char and gases as well as the absence of a need for resupply materials are advantages of pyrolysis. A major disadvantage of pyrolysis is that it can produce tars that are difficult to handle and can cause plugging of the processing hardware. By controlling the heating rate of primary pyrolysis, the secondary (cracking) bed temperature, and residence time, it is possible that tar formation can be minimized for most biomass materials. This paper describes an experimental evaluation of two versions of pyrolysis reactors that were delivered to the NASA Ames Research Center (ARC) as the end products of a Phase II and a Phase III Small Business Innovation Research (SBIR) project.