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Research into increased capacity solid amine sorbents has found a candidate (SA9T) that will provide enough increase in cyclic carbon dioxide removal capacity to produce a fully redundant Regenerative Carbon Dioxide Removal System (RCRS). This system will eliminate the need for large quantities of backup LiOH, thus gaining critical storage space on board the shuttle orbiter. This new sorbent has shown an ability to package two fully redundant (four) sorbent beds together with their respective valves, fans and plumbing to create two operationally independent systems. The increase in CO2 removal capacity of the new sorbent will allow these two systems to fit within the envelope presently used by the RCRS. This paper reports on the sub-scale amine testing performed in support of the development effort. In addition, this paper will provide a preliminary design schematic of a fully redundant RCRS.

Metabolic heat regenerated temperature swing adsorption (MTSA) technology is being developed for removal and rejection of carbon dioxide (CO2) and heat from a portable life support system (PLSS) to the Martian environment. Previously, hardware was built and tested to demonstrate using heat from simulated, dry ventilation loop gas to affect the temperature swing required to regenerate an adsorbent used for CO2 removal. New testing has been performed using a moist, simulated ventilation loop gas to demonstrate the effects of water condensing and freezing in the heat exchanger during adsorbent regeneration. Also, the impact of MTSA on PLSS design was evaluated by performing thermal balances assuming a specific PLSS architecture. Results using NASA's Extravehicular Activity System Sizing Analysis Tool (EVAS_SAT), a PLSS system evaluation tool, are presented.

As the United States makes plans to return astronauts to the moon and eventually send them on to Mars, designing the most effective, efficient, and robust spacesuit life support system that will operate successfully in dusty environments is vital. Some knowledge has been acquired regarding the contaminants and level of infiltration that can be expected from lunar and Mars dust, however, risk mitigation strategies and filtration designs that will prevent contamination within a spacesuit life support system are yet undefined. A trade study was therefore initiated to identify and address these concerns, and to develop new requirements for the Constellation spacesuit element Portable Life Support System. This trade study investigated historical methods of controlling particulate contamination in spacesuits and space vehicles, and evaluated the possibility of using commercial technologies for this application. The trade study also examined potential filtration designs.

Metabolic heat regenerated temperature swing adsorption (MTSA) that is incorporated into a Portable Life Support System (PLSS) is being explored as a viable means of removing and rejecting carbon dioxide (CO2) from an astronaut's ventilation loop. Sorbent pellets, which were used in previous work, are inherently difficult to heat and cool quickly. Further, their use in packed beds creates a large, undesirable pressure drop. Work has thus been done to assess the application and performance of aluminum foam that has been washcoated with a layer of sorbent. A to-scale sorbent bed, which is envisioned for use by a Martian PLSS, was designed, built, and tested. Performance of the assembly in regards to CO2 adsorption and pressure drop was assessed, and the results are presented here.

Carbon dioxide removal on the Shuttle is performed either by flowing cabin ventilation air through single use LiOH beds or by using the Regenerable CO2 Removal System (RCRS) (Ref 1,2,3). The RCRS was designed for single string mechanical operation with redundancy only on electrical components. It therefore can become disabled by a number of possible single point failures such as fan failure, actuator failure or a large internal leak through the beds. Because of these possible failures, LiOH must be flown on all RCRS missions to provide contingency CO2 removal. These LiOH canisters occupy valuable stowage space onboard the shuttle orbiter. The development of a new sorbent material called HS-X with significantly more CO2 removal capacity per unit volume has made much smaller sorbent bed sizes possible. With significantly smaller beds each of the single point failures can be addressed and a fully redundant RCRS can be built to fit within the existing RCRS envelope.

The NASA objective of expanding the human experience into the far reaches of space will require the development of regenerable life support systems. On-board carbon dioxide (CO2) removal units play a key role in such systems ensuring high quality cabin air for crew members. Similar but more compact units are needed for extravehicular activities (space suit). The use of monolithic (e.g., honeycomb-shaped) rather than granular sorbents has the potential to result in a CO2-removal system that possesses substantial weight, size, and power-requirement advantages over current systems (improved CO2 adsorption and lower pressure drop). The subject of this study was the use and manufacture of lightweight, porous carbon monoliths with controlled pore characteristics that will serve as support for the sorbent material (e.g., liquid amines). The objective was to demonstrate the technical feasibility of the above approach.

Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed to address carbon dioxide (CO2) and heat removal/rejection in a Mars Portable Life Support System (PLSS). The technology utilizes an adsorbent that when cooled with liquid CO2 to near sublimation temperatures (∼195 K) removes metabolically-produced CO2 in the ventilation loop. Once fully loaded, the adsorbent is then warmed (∼300 K) externally by the ventilation loop, rejecting the captured CO2 to Mars ambient. Two beds are used to provide a continuous cycle of CO2 removal/rejection as well as facilitate heat exchange out of the ventilation loop. To investigate the feasibility of the technology, a series of model calibration experiments were conducted which lead to the selection and partial characterization of an appropriate adsorbent.

Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is being developed for thermal and carbon dioxide (CO2) control for a Portable Life Support System (PLSS), as well as water recycling. CO2 removal and rejection is accomplished by driving a sorbent through a temperature swing starting at below freezing temperatures. The swing is completed by warming the sorbent with a separate condensing ice heat exchanger (CIHX) using metabolic heat from moist ventilation gas. The condensed humidity in the ventilation gas is recycled at the habitat. Designing a heat exchanger to efficiently transfer this energy to the sorbent bed and allow the collection of the water is a challenge since the CIHX will operate in a temperature range from 210 K to 280 K. The ventilation gas moisture will first freeze and then thaw, sometimes existing in three phases simultaneously.

As part of NASA's initiative to develop an advanced portable life support system (PLSS), a baseline schematic has been chosen that includes gaseous oxygen in a closed circuit ventilation configuration. Supply oxygen enters the suit at the back of the helmet, passes over the astronaut's body, and is extracted at the astronaut's wrists and ankles through the liquid cooling and ventilation garment (LCVG). The extracted gases are then treated using a rapid cycling amine (RCA) system for carbon dioxide and water removal and activated carbon for trace gas removal before being mixed with makeup oxygen and reintroduced into the helmet. Thermal control is provided by a suit water membrane evaporator (SWME). As an extension of the original schematic development, NASA evaluated several Helmet Exhalation Capture System (HECS) configurations as alternatives to the baseline.

As development of the Constellation spacesuit element progresses, designing the most effective and efficient life support systems is critical. The baseline schematic analysis for the Portable Life Support System indicates that the ventilation loop will need some method of heat exchange and humidification prior to entering the helmet. A trade study was initiated to identify the challenges that are associated with conditioning the spacesuit breathing gas stream for temperature and water vapor control; to survey technological literature and resources on heat exchanger and humidifiers to provide solutions to the problems of conditioning the spacesuit breathing gas stream; and to propose potential candidate technologies to perform the heat exchanger and humidifier functions. This paper summarizes the results of this trade study, and also describes the conceptual designs that NASA developed to address these issues.

A number of amine-based carbon dioxide (CO2) removal systems have been developed for atmosphere revitalization in closed loop life support systems. Most recently, Hamilton Sundstrand has developed an amine-based sorbent, designated SA9T, possessing approximately 2-fold greater capacity compared to previous formulations. This new formulation has demonstrated applicability for controlling CO2 levels within vehicles and habitats as well as during extravehicular activity (EVA). Our current data demonstrates an amine-based system volume which is competitive with existing technologies which use metal oxides (Metox) and lithium hydroxide sorbents. Further enhancements in system performance can be realized by incorporating humidity and trace contaminant control functions within an amine-based atmosphere revitalization system. A 3-year effort to develop prototype hardware capable of removing CO2, H2O, and trace contaminants from a cabin atmosphere has been initiated.

The National Aeronautics and Space Administration's (NASA) planned future missions set stringent demands on the design of the Portable Life Support System (PLSS), requiring dramatic reductions in weight, decreased reliance on supplies and greater flexibility for Extravehicular Activity (EVA) duration and objectives. Use of regenerable systems that reduce weight and volume of the space suit life support system is of critical importance to NASA, both for low orbit operations and for long duration manned missions. The carbon dioxide and humidity control unit in the existing PLSS design is relatively large, since it has to remove and store eight hours worth of carbon dioxide (CO2). If the sorbent regeneration can be carried out during the EVA with a relatively high regeneration frequency, the size of the sorbent canister and weight can be significantly reduced.

Under a NASA sponsored technology development activity, Hamilton Sundstrand has designed, fabricated, tested and delivered a prototype solid amine-based carbon dioxide (CO2) and water (H2O) vapor removal system sized for Extravehicular Activity (EVA) operation. The prototype system employs two alternating and thermally-linked solid amine sorbent beds to continuously remove CO2 and H2O vapor from a closed environment. While one sorbent bed is exposed to the vent loop to remove CO2 and water vapor, the other bed is exposed to a regeneration circuit, defined as either vacuum or an inert sweep gas stream. A linear spool valve, coupled directly to the amine canister assembly, is utilized to simultaneously divert the vent loop flow and regeneration circuit flow between the two sorbent beds.

Patent-pending Metabolic heat regenerated Temperature Swing Adsorption (MTSA) technology is currently being investigated for removal and rejection of carbon dioxide (CO2) and heat from a Portable Life Support System (PLSS) to a Martian environment. The metabolically-produced CO2 present in the ventilation loop gas is collected using a CO2 selective adsorbent that has been cooled via a heat exchanger to near CO2 sublimation temperatures (∼195 K) with liquid CO2 (LCO2) obtained from Martian resources. Once the adsorbent is fully loaded, used, warm (∼300 K), moist ventilation loop gas is used to heat the adsorbent via another heat exchanger to reject the collected CO2 to the Martian ambient. Two beds are used to achieve continuous CO2 removal by cycling between the cold and warm conditions for adsorbent loading and regeneration, respectively.

Carbon dioxide (CO2) removal technology development for portable life support systems (PLSS) has traditionally concentrated in the areas of solid and liquid chemical sorbents and semi-permeable membranes. Most of these systems are too heavy in gravity environments, require prohibitive amounts of consumables for operation on long term planetary missions, or are inoperable on the surface of Mars due to the presence of a CO2 atmosphere. This paper describes the effort performed to mature an innovative CO2 removal technology that meets NASA's planetary mission needs while adhering to the important guiding principles of simplicity, reliability, and operability. A breadboard cryogenic carbon dioxide scrubber for an ejector-based cryogenic PLSS was developed, designed, and tested. The scrubber freezes CO2 and other trace contaminants out of expired ventilation loop gas using cooling available from a liquid oxygen (LOX) based PLSS.

The partial electrochemical reduction of carbon dioxide (CO2) using ceramic oxygen generators (COGs) is well known and widely studied. Conventional COGs use yttria-stabilized zirconia (YSZ) electrolytes and operate at temperatures greater than 700 °C. Operating at a lower temperature has the advantage of reducing the mass of the ancillary components such as insulation and heat exchangers (to reduce the COG oxygen output temperature for comfortable inhalation). Moreover, complete reduction of metabolically produced CO2 (into carbon and oxygen) has the potential of reducing oxygen storage weight if the oxygen can be recovered. Recently, the University of Florida developed novel ceramic oxygen generators employing a bilayer electrolyte of gadolinia-doped ceria and erbia-stabilized bismuth oxide (ESB) for NASA's future exploration of Mars.

Pyrolysis processing is one of several options for solid waste resource recovery in space. It has the advantage of being relatively simple and adaptable to a wide variety of feedstocks and it can produce several usable products from typical waste streams. The overall objective of this study was to produce a prototype mixed solid waste pyrolyzer for spacecraft applications. A two-stage reactor system was developed which can process a maximum of about 0.5 kg of waste per cycle. The reactor includes a pyrolysis chamber where the waste is heated to temperatures above 600 °C for primary pyrolysis. The volatile products (liquids, gases) are transported by a N2 purge gas to a second chamber which contains a catalyst bed for cracking the tars at temperatures of about 1000-1100 °C. The tars are cracked into carbon and additional gases. Most of the deposited carbon is subsequently gasified by oxygenated volatiles (CO2, H2O) from the first stage.

This project investigates methods to capture an astronaut's exhaled carbon dioxide (CO2) before it becomes diluted with the high volumetric oxygen flow present within a space suit. Typical expired breath contains CO2 partial pressures (pCO2) in the range of 20-35 mm Hg (.0226-.046 atm). This research investigates methods to capture the concentrated CO2 gas stream prior to its dilution with the low pCO2 ventilation flow. Specifically this research is looking at potential designs for a collection cup for use inside the space suit helmet. The collection cup concept is not the same as a breathing mask typical of that worn by firefighters and pilots. It is well known that most members of the astronaut corps view a mask as a serious deficiency in any space suit helmet design. Instead, the collection cup is a non-contact device that will be designed using a detailed Computational Fluid Dynamic (CFD) analysis of the ventilation flow environment within the helmet.