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There is a growing consensus that there will not be a single alternative to fossil fuels, but rather different fuels, fuel feedstocks, engine types and operating strategies. For stationary diesel engines, straight vegetable oils are an interesting alternative to fossil diesel, because of their potential for lower life cycle greenhouse gas emissions. Using animal fats is also compelling, as it does not imply the cultivation of oil-bearing seeds and related emissions, not to mention the ‘food versus fuel’ debate. The aim of the present work is to correlate engine performance and durability with the properties (composition) of these alternative fuels, to provide a basis from which standards can be formulated for the properties of oils and fats to be used as engine fuel. Tests on different oils and fats are reported.

Partially premixed combustion (PPC) with gasoline fuels is a new promising combustion concept for future internal combustion engines. However, many researchers have argued the capabilities of research octane number (RON) and Motor Octane Number (MON) to describe the autoignition behaviour of gasoline fuels in advanced combustion concepts like PPC. The objective of this study is to propose a new method, called PPC number, to characterize the auto ignition quality of gasoline fuels in a light-duty direct injected compression ignition engine under PPC conditions. The experimental investigations were performed on a 4-cylinder Volvo D4 2 litre engine. The ignition delay which was defined as the crank angle degrees between the start of injection (SOI) and start of combustion (SOC) was used to represent the auto ignition quality of a fuel.

The internal combustion engine with compression ignition is still the most important power plant for heavy duty transport, railway transport, marine applications and generator sets. Fuel cost and emission regulations drive manufacturers to switch to alternative fuels. The understanding and prediction of these fuels in the spray and combustion process will be very important for these issues. In the past, lot of research was done for conventional diesel fuel by optically analyzing both spray and combustion. However comparison between different groups is difficult since qualitative results and accuracies are depending in the used definitions and methods. The goal of present research is to verify the behavior pure oils compared to more standard fuels while paying lot of attention to the interpretation of the measurement results.

Low temperature combustion concepts used in compression ignition engines have shown to be able to produce simultaneous reduction of oxides of nitrogen and soot as well as generating higher gross indicated efficiencies compared to conventional diesel combustion. This is achieved by a combination of premixing, dilution and optimization of combustion phasing. Low temperature combustion can be complemented by moving away from fossil fuels in order to reduce the net output of CO2 emissions. Alternative fuels are preferably liquid and of sufficient energy density. As such methanol is proposed as a viable option. This paper reports the results from a simulation based investigation on a heavy-duty multi-cylinder direct injection compression ignition engine with standard compression ratio. The engine was simulated using two different fuels: methanol and gasoline with an octane number of 70.

Non-Road Mobile Machinery (NRMM) incorporates a wide variety of machines not intended for the transport of passengers or goods on the road. This includes small gardening equipment, construction, mining, agricultural, and forestry machinery up to locomotives and inland waterway vessels, mostly using an internal combustion engine. NRMM was often overlooked and neglected in the past when considering pollutant and greenhouse gas emissions. Due to their high diversity, they are hard to categorize, resulting in a lack of available data. As emissions from road transport are being tackled by regulations, the emissions of NRMM become an increasing part of total transport emissions. An alternative to fossil fuels will be required for the energy supply of NRMM to fully commit to the CO2 reduction goals, and to fulfil the future requirements of legislators and public opinion.

In 2004 the European Parliament ratified the Euro III and IV standards limiting the pollutant emission of, among others, rail and marine diesel engines. In these sectors, it is particularly important to keep any fuel consumption penalty, when reducing emissions, to a strict minimum. Furthermore, exhaust gas after treatment is mostly avoided for cost reasons. Thus, manufacturers are looking to pretreatment of fuels, alternative fuels, and limiting engine-out emissions as ways to attain the required emission levels. This paper discusses the experimental work done on a 1324 kW, 1000 rpm six cylinder marine diesel engine equipped with mechanical unit injectors. The aim was to determine the influence of compression ratio and fuel injection parameters on engine-out emissions, with emphasis on NOx emissions. A range of fuel injection parameters were examined, varying the start of injection, pump plunger diameter, injection pressure, and injector nozzle geometry.

Using liquid alcohols, such as methanol and ethanol, in spark-ignition engines is a promising approach to decarbonize transport and secure domestic energy supply. Methanol and ethanol are compatible with the existing fuelling and distribution infrastructure and are easily stored in a vehicle. They can be used in internal combustion engines with only minor adjustments and have the potential to increase the efficiency and decrease noxious emissions compared to gasoline engines. In addition, methanol can be synthesized from a wide variety of sources, including renewably produced hydrogen in combination with atmospheric CO₂. Presently, during the production of ethanol or methanol a dehydration step is always applied. This step accounts for a significant part of the entire production process' energy consumption and thus, from an economical point of view, methanol and ethanol could become more interesting alternative fuels if the costs related with dehydration could be reduced.

The use of renewable fuels such as hydrogen and methanol in marine engines is a promising way to reduce greenhouse gas emissions from maritime transport. Hydrogen and methanol can be used as the main fuel in dual-fuel engines. However, the co-combustion of hydrogen-diesel and methanol-diesel needs to be carefully studied. In the present work, the ignition delay (ID) and laminar burning velocity (LBV) for pilot-ignited dual fuel engine operation with hydrogen or methanol are studied. A constant volume batch reactor numerical setup is used in the open source Cantera code to calculate the effect of the premixed fuel on the ID of the pilot fuel. Also, Cantera is used to simulate a freely-propagating, adiabatic, 1-D flame to estimate the laminar flame speed of either hydrogen or methanol and how it is affected by the presence of pilot fuel. First, suitable chemical kinetic schemes are selected based on experimental data collected from the literature.

Methanol is a promising fuel for future spark-ignition engines. Its properties enable increased engine efficiency. Moreover, the ease with which methanol can be reformed, using waste exhaust heat, potentially offers a pathway to even higher efficiencies. The primary objective of this study was to build and validate a model for a methanol fueled direct-injection spark-ignition engine with on-board fuel reforming for future investigation and optimization. The second objective was to understand the combustion characteristics, energy losses and engine efficiency. The base engine model was developed and calibrated before adding a reformed-exhaust gas recirculation system (R-EGR). A newly developed laminar burning velocity correlation with universal dilution term was implemented into the model to predict the laminar burning velocity with the presence of hydrogen in the reforming products.

Methanol has recently emerged as a promising fuel for internal combustion engines due to its multiple carbon-neutral production routes and advantageous properties when combusting. Methanol is intrinsically more suitable for spark-ignition (SI) operation thanks to its high octane number, but its potential in heavy-duty applications also encourages engine manufacturers in this field to retrofit their existing compression-ignition products into methanol/diesel dual-fuel (DF) operation. For both SI operation and DF operation, injecting methanol into the engine’s intake path at low pressure is a relatively simple and robust method to introduce methanol into the cylinders. However, the much higher heat of vaporization (HoV) of methanol compared to conventional SI fuels like gasoline can be a double-edged sword.

Despite the increasing number of electrified vehicles the transportation system still largely depends on the use of fossil fuels. One way to more rapidly reduce the dependency on fossil fuels in transport is to replace them with biofuels. Evaluating the potential of different biofuels in different applications requires knowledge of their physicochemical properties. In chemistry, message passing neural networks (MPNNs) correlating the atoms and bonds of a molecule to properties have shown promising results in predicting the properties of individual chemical components. In this article a machine learning approach, developed from the message passing neural network called Chemprop, is evaluated for the prediction of multiple properties of organic molecules (containing carbon, nitrogen, oxygen and hydrogen). A novel approach using transfer learning based on estimated property values from theoretical estimation methods is applied.

The use of methanol and ethanol in spark-ignition (SI) engines forms a promising approach to decarbonizing transport and securing domestic energy supply. The physico-chemical properties of these fuels enable engines with increased performance and efficiency compared to their fossil fuel counterparts. An engine cycle code valid for alcohol-fuelled engines could help to unlock their full potential. However, the development of such a code is currently hampered by the lack of a suitable correlation for the laminar flame speed of alcohol-air-diluent mixtures. A literature survey showed that none of the existing correlations covers the entire temperature, pressure and mixture composition range as encountered in spark-ignition engines. For this reason, we started working on new correlations based on simulations with a one-dimensional chemical kinetics code. In this paper the properties of methanol and ethanol are first presented, together with their application in modern SI engines.

In order to reduce the carbon footprint of the Internal Combustion Engine (ICE), biofuels have been in use for a number of years. One of the problems with first-generation (1G) biofuels however is their competition with food production. In search of second-generation (2G) biofuels, that are not in competition with food agriculture, a novel biorefinery process has been developed to produce biofuel from woody biomass sources. This novel technique, part of the Belgian federal government funded Ad-Libio project, uses a catalytic process that operates at low temperature and is able to convert 2G feedstock into a stable light naphtha. The bulk of the yield consists out of hydrocarbons containing five to six carbon atoms, along with a fraction of oxygenates and aromatics. The oxygen content and the aromaticity of the hydrocarbons can be varied, both of which have a significant influence on the fuel’s combustion and emission characteristics when used in Internal Combustion Engines.

The increasing need to reduce greenhouse gas emissions and shift away from fossil fuels has raised an interest for methanol. Methanol can be produced from renewable sources and can drastically lower soot emissions from compression ignition engines (CI). As a result, research and development efforts have intensified focusing on the use of methanol as a replacement for diesel in CI engines. The issue with methanol lies in the fact that methanol is challenging to ignite through compression alone, particularly at low-load and cold starts conditions. This challenge arises from methanol's high octane number, low heating value, and high heat of vaporization, all of which collectively demand a substantial amount of heat for methanol to ignite through compression.

Partially premixed combustion (PPC) is one of several advanced combustion concepts for the conventional diesel engine. PPC uses a separation between end of fuel injection and start of combustion, also called ignition dwell, to increase the mixing of fuel and oxidizer. This has been shown to be beneficial for simultaneously reducing harmful emissions and fuel consumption. The ignition dwell can be increased by means of exhaust gas recirculation or lower intake temperature. However, the most effective means is to use a fuel with high research octane number (RON). Methanol has a RON of 109 and a recent study found that methanol can be used effectively in PPC mode, with multiple injections, to yield high brake efficiency. However, the early start of injection (SOI) timings in this study were noted as a potential issue due to increased combustion sensitivity. Therefore, the present study attempts to quantify the changes in engine performance for different injection strategies.

A modern diesel engine is a reliable and efficient mean of producing power. A way to reduce harmful exhaust and greenhouse gas (GHG) emissions and secure the sources of energy is to develop technology for an efficient diesel engine operation independent of fossil fuels. Renewable diesel fuels are compatible with diesel engines without any major modifications. Rapeseed oil methyl esters (RME) and other fatty acid methyl esters (FAME) are commonly used in low level blends with diesel. Lately, hydrotreated vegetable oil (HVO) produced from vegetable oil and waste fat has found its way into the automotive market, being approved for use in diesel engines by several leading vehicle manufacturers, either in its pure form or in a mixture with the fossil diesel to improve the overall environmental footprint. There is a lack of data on how renewable fuels change the semi-volatile organic fraction of exhaust emissions.

Stricter CO2 and emissions regulations are pushing spark ignition engines more and more towards downsizing, enabled through direct injection and turbocharging. The advantages which come with direct injection, such as increased charge density and an elevated knock resistance, are even more pronounced when using low carbon number alcohols instead of gasoline. This is mainly due to the higher heat of vaporization and the lower air-to-fuel ratio of light alcohols such as methanol, ethanol and butanol. These alcohols are also attractive alternatives to gasoline because they can be produced from renewable resources. Because they are liquid, they can be easily stored in a vehicle. In this respect, the performance and engine-out emissions (NOx, CO, HC and PM) of methanol, ethanol and butanol were examined on a 4 cylinder 2.4 DI production engine and are compared with those on neat gasoline.

The growing demand to lower greenhouse gas emissions and transition from fossil fuels, has put methanol in the spotlight. Methanol can be produced from renewable sources and has the property of burning almost soot-free in compression ignition (CI) engines. Consequently, there has been a notable increase in research and development activities directed towards exploring methanol as a viable substitute for diesel fuel in CI engines. The challenge with methanol lies in the fact that it is difficult to ignite through compression alone, particularly in low-load and cold start conditions. This difficulty arises from methanol's high octane number, relatively low heating value, and high heat of vaporization, collectively demanding a considerable amount of heat for methanol to ignite through compression. Previous studies have addressed the use of a pilot injection in conjunction with a larger main injection to lower the required intake air temperature for methanol to combust at low loads.

The worldwide adoption of renewable energy mandates, together with the widespread utilization of biofuels has created a sharp increase in the production of biodiesel (fatty acid alkyl esters). As a consequence, the production of glycerol, the main by-product of the transesterification of fatty acids, has increased accordingly, which has led to an oversupply of that compound on the markets. Therefore, in order to increase the sustainability of the biodiesel industry, alternative uses for glycerol need to be explored and the production of fuel additives is a good example of the so-called glycerol valorization. The goal of this study is therefore to evaluate the suitability of a number of glycerol-derived compounds as diesel fuel additives. Moreover, this work concerns the assessment of low-concentration blends of those glycerol derivatives with diesel fuel, which are more likely to conform to the existing fuel standards and be used in unmodified engines.

The use of light alcohols as SI engine fuels can help to increase energy security and offer the prospect of carbon neutral transport. These fuels enable improvements in engine performance and efficiency as several investigations have demonstrated. Further improvements in efficiency can be expected when switching from throttled stoichiometric operation to strategies using mixture richness or exhaust gas recirculation (EGR) to control load while maintaining wide open throttle (WOT). In this work the viability of throttleless load control using EGR (WOT EGR) or mixture richness (WOT lean burn) as operating strategies for methanol engines was experimentally verified. Experiments performed on a single-cylinder engine confirmed that the EGR dilution and lean burn limit of methanol are significantly higher than for gasoline. On methanol, both alternative load control strategies enable relative indicated efficiency improvements of about 5% compared to throttled stoichiometric operation.