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It is thought that the synthetic gas, including hydrogen and carbon monoxide, has a potential to be an alternative fuel for internal combustion engines, because a heating value of the synthetic gas is higher than one of hydrogen or natural gas. A purpose of this study is to acquire stable auto-ignition and combustion of the synthetic gas which is supposed to be applied into a direct-injection compression ignition engine. In this study, the effects of ambient gas temperatures and oxygen concentrations on auto-ignition characteristics of the synthetic gas with changing percentage of hydrogen (H2) or carbon monoxide (CO) concentrations in the synthetic gas. An electronically-controlled, hydraulically-actuated gas injector was used to control a precise injection timing and period of gaseous fuels, and the experiments were conducted in an optically accessible, constant-volume combustion chamber under simulated quiescent diesel engine conditions.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

This paper provides new insights on the mechanism of the smokeless diesel combustion with oxygenated fuels, based on a combination of soot kinetic modeling and optical diagnostics. The chemical effects of fuel compositions, including aromatics - paraffins blend, neat oxygenated fuels and oxygenate additives, on sooting equivalence ratio ‘ϕ’ - temperature ‘T’ dependence were numerically examined using a detailed soot kinetic model. To better understand the physical factors affecting soot formation in oxygenated fuel sprays, the effects of injection pressure and ambient gas temperature on the flame lift-off length and relative soot concentration in oxygenated fuel jets were experimentally investigated. The computational results show that the leaner mixture side of soot formation peninsula on the ϕ - T map, rather than the lower temperature one, should be utilized to suppress the formation of PAHs and ultra-fine particles together with the large reduction in particulate mass.

One of the effective ways to cope with the very severe future regulation of soot exhausted through a CI engine is the use of oxygenated fuel. This paper describes the experimental results of the soot generation of six kinds of oxygenated fuel and n-heptane whose cetane number is the almost the same as that of the gas oil by means of time resolved LII (TIRE-LII) and the classical two color method. The experiments were carried out in a constant volume chamber. The main result is that the oxygen content of the fuel is the much significant factor to decrease in the soot.

This paper describes the results of on-board measurement of engine performance and emissions in diesel vehicle operated with bio-diesel fuels. Here, two waste-cooking oils were investigated. One fuel is a waste-cooking oil methyl esters. This fuel is actually applied to a garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is a fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. Then, these 3 bio-diesel fuels were applied to the on-board experiments and the results were compared with gas oil operation case.

It is expected that the analysis of the evaporation process for multicomponent fuels such as actual fuels like gasoline and diesel gas oil could be performed to assess more accurately the mixture preparation field inside the cylinder of D.I.S.I engines and diesel engines. In this paper, we suggested the importance of this multicomponent fuel consideration relating to the mixture formation and combustion characteristics from the basis of their own fuel physical and chemical properties. Then, we introduce a treatment for the phase change of a multicomponent solution through the formation of two-phase regions with the basis of chemical-thermodymical liquid-vapor equilibrium. Next, we analyze the distillation properties of a multicomponent fuel as well as the evaporation process of a multicomponent single droplet by use of the chemical-thermodymical analysis.

In previous multi-dimensional modeling on spray dynamics and vapor formation, single component fuel with pure substance has been analyzed to assess the mixture formation. Then it should be expected that the evaporation process could be performed for the multicomponent fuel such as actual Gasoline and Diesel gas oil. In this study, vapor-liquid equilibrium prediction was conducted for multicomponent fuels such as 3 and 10 components mixed solution with ideal solution analysis and non-ideal solution analysis. And the computation of distillation characteristics was conducted for the steady state fuel condition fuel condition to understand the evaporation process. As a result, calculated distillation characteristics are consistent well with experiment results. And the evaporation process of a multicomponent droplet in the combustion chamber has been calculated with the variation of ambient pressure and temperature.

A transient gas jet and its flame are the most fundamental phenomena of a transient spray and its flame breaking out in a CI engine and an SI engine with the direct injection system. In the case of CNG and LNG engines, the fuel itself is just gaseous state. The 2-LIF technique was applied to the transient gas jet to obtain the mixing process between the surroundings and it, and the simultaneous application of LII and LIS techniques were applied to the transient gas jet flame to obtain the soot formation process.

In an SI engine with direct injection of gasoline (DGI), many small droplets disperse in premixed gas in the cylinder. In a CI engine, diesel spray is injected a cylinder, thus, the situation at the spray periphery is almost the same as that of DGI SI engine. From the standpoint it is useful for understanding the combustion phenomena in both engines to experiment the combined combustion of premixed gas where many small droplets exist. This paper describes this kind of combustion and it seems to be able to apply the results to the simulation of combustion in these engines.

We propose a new concept on simultaneous reduction of NO and soot emissions in Diesel engine exhaust by use of the diesel fuel oil (n-Tridecane) with liquefied CO2 dissolved. The CO2 dissolved component is expected to undergo flash boiling or gas separation when being injected into the combustion chamber, and improve spray atomization and mixing process both of which are primary factors to govern soot formation. Further, the internal EGR effect caused by CO2 component injected with the fuel is expected for NO formation. In order to assess this concept, spray dynamics measurement was conducted in the constant volume vessel with a variation of ambient pressure and temperature. Further, combustion experiments were carried out by using a rapid compression and expansion machine. Here, characteristics of the evaporative mixed fuel spray were examined by shadowgraph photography.

In this study, a rapid compression and expansion machine(RCEM) with a pancake combustion chamber was designed to investigate fundamentally on the knocking phenomena in spark ignition(S.I) engines. This RCEM is intended to simulate combustion in an actual engine. The homogeneous pre-mixture of n-pentane and air was charged into a quiescent atmosphere of the chamber. Then, the combustion field become simpler in this machine than it in a real S.I. engine. Also, the combustion phenomena, that is a cylinder pressure history, the behavior of flame propagation and so on, with high reproducibility are realized in this machine. The phenomena caught in this experiment were so-called low speed knocking. And, this knocking characteristics such as a knock intensity and a knock mass fraction were revealed by the cylinder pressure analysis varying the charge pressure and the equivalence ratio of the mixture, a compression ratio and an ignition timing.

As authors reported in SAE Trans. 800968, entitled “Investigation on the Characteristics of Diesel Fuel Spray”, the flame never proceeds into the initial-part of the spray during injection. The length of the initial part-lies within 10 to 15 mm regardless of the conditions of the injection systems and of the ambient conditions. The ignition delay does not decrease but becomes constant when the ambient temperature or the pressure exceed a discrete value. The authors would like to propose a new concept of “Spray Formation Delay” during which the field is generated where the physical and chemical delay can exist. The spray formation delay is one of the major factors which control the above mentioned limitation of ignition delay. The characteristics of the spray formation delay are investigated and clarified.

The authors carried out a basic and systematic investigation on diesel combustion processes using three different experimental apparatuses. This paper summarized the experimental results obtained from the three devices. Among the data contained in this paper are; (1) The structure and shape of diesel spray, the air movement around diesel spray and the spatial and temporal distributions of the size of droplets in diesel spray injected into the high pressure and room temperature charge. (2) The shape of diesel spray injected into the high pressure and high tempertaure charge. (3) The characteraistics of flame, and illumination delay, and ignition delay in the high pressure and high temperature charge.

The Flame structure and combustion characteristics for two waste-cooking oils were investigated in detail. One fuel is the waste-cooking oil methyl esters. This fuel is actually applied to the garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is the fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. In the experiments, the used fuels were gas oil, i-BDF, B100 and B20. Spray characteristics and basic combustion properties were measured inside a rapid compression and an expansion machine (RCEM).

This work presents the ignition delay time characteristics of oxygenated fuel sprays under simulated diesel engine conditions. A constant volume combustion vessel is used for the experiments. The fuels used in the experiments were three oxygenated fuels: diethylene glycol dibutyl ether, diethylene glycol diethyl ether, and diethylene glycol dimethyl ether. JIS 2nd class gas oil was used as the reference fuel. The ambient gas temperature and oxygen concentration were ranging from 700 to 1100K and from 21 to 9%, respectively. The results show that the ignition delay of each oxygenated fuel tested in this experiments exhibits shorter than that of gas oil fuel for the wide range of ambient gas conditions. Also, NTC (negative temperature coefficient) behavior which appears under shock tube experiment for homogenous fuel-air mixture was observed on low ambient gas oxygen concentration for each fuel. And at the condition, the ignition behavior exhibits two-stage phase.

The spray structure under the pressurized atmosphere at a room temperature was examined by the various photographic methods. The fuel flow inside the nozzle was investigated by the transparent model nozzles. The experimental analysis of sprays yielded the spray dispersing angle, the distribution of fuel droplets inside the spray and the jet intact core length. The obtained results of those spray characteristics showed that the spray structure is divided into two spatial regimes due to their formation mechanisms. Within 10 mm from the nozzle, the spray dispersion is dominated by the turbulent states of fuel which are initiated inside the nozzle. At distance from the nozzle z > 20 - 40 mm, the spray consists of an induced gas vortex street whose length is about half of the spray width. It is proposed that the kinematic viscosity of ambient gas is a important factor which rules the process of momentum exchange form the fuel jet to the ambient gas.

In this paper, spray characteristics were examined to deduce the effect of ambient gas properties. Considered ambient properties were the viscosity μa and density ρa, and thus the kinematic viscosity νa. The objective of this paper is to reveal the effect of compressibility of the ambient gas to spray formation. In the experiments, the changed ranges were And a standard-sac volume nozzle of hole diameter dn =0.25 mm (ln/dn=3.0) was used at constant injection pressure difference (Δp=16.2 MPa). Also the injection pressure was varied in the range of 55 to 120 MPa with a mini-sac volume nozzle of hole diameter dn =0.20 mm (ln/dn =5.5). Several different gases were used to change the ambient viscosity at a room temperature. From the experiments, it is obtained that larger the viscosity, the more the spray spreads in the radial direction, thus the spray angle gets larger and the tip penetration became shorter.

Some papers on the combustion in a diesel engine have been already presented to discuss the effect of the additive called ADOIL TAC. A bottom view DI diesel engine driven at 980rpm with no load was used in the experiment presented here, in order to make clear this effect. JIS second class light diesel fuel oil was injected through a hole nozzle at the normal test run. The additive was intermixed 0.01 vol. % in this fuel oil, in the experiments to compare with the normal combustion. The flame was taken by direct high-speed photography. Profiles of flame temperature and KL were detected on the film by image processing, applying the two-color method. Soot was visualized by high-speed laser shadowgraphy, and the heat release rate was calculated using the cylinder pressure diagram. Discussion on the effect of the additive on the combustion phenomena was made by using all the data.

Diesel sprays injected into a combustion chamber of a small sized high-speed CI engine impinge surely on a piston surface and a cylinder wall. As a consequence, their vaporization, mixture formation and combustion processes are affected by impingement phenomena. And the other important factors affecting on the processes is the injection pressure. Then, the distribution of the vapor concentration in a single diesel spray impinging on a flat and hot wall was experimented by the exciplex fluorescence method, as a simple case. The injection pressure was varied in the range from 55 MPa to 120 MPa. It is found that the distribution of the vapor concentration in this case is much leaner than that in the case of the low injection pressure of 17.8MPa.

This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.