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The overall program objectives were three fold: assess the benefits and limitations of oxygenated diesel fuels on engine performance and emissions identify oxygenates most suitable for potential use in future diesel formulations based on physico-chemical properties (e.g. flash point), toxicity, biodegradability and estimated cost of production perform limited emissions and performance testing of the oxygenated diesel blends select at least two oxygenated compounds for advanced engine testing In Part 1 of this program which is described in this paper, an extensive literature review was conducted to identify potential oxygenates for blending into diesel fuels. As many as 71 oxygenates were identified for the initial screening process. Based on a set of physical and chemical properties, a screening methodology was developed to select the 8 oxygenates that will be eligible for engine testing.

Cycle-resolved analysis of velocity data obtained in the re-entrant bowl of a fired high-;speed, direct-injection diesel engine, demonstrates an unambiguous, approximately 100% increase in late-cycle turbulence levels over the levels measured during motored operation. Model predictions of the flow field, obtained employing RNG k-ε turbulence modeling in KIVA-3V, do not capture this increased turbulence. A combined experimental and computational approach is taken to identify the source of this turbulence. The results indicate that the dominant source of the increased turbulence is associated with the formation of an unstable distribution of mean angular momentum, characterized by a negative radial gradient. The importance of this source of flow turbulence has not previously been recognized for engine flows. The enhanced late-cycle turbulence is found to be very sensitive to the flow swirl level.

The objective of this study was to quantify the effect of pilot fuel injection on engine-out emissions of potentially toxic compounds from a modern diesel engine operated with different fuels including 15% v/v dimethoxy methane in a low-sulfur diesel fuel. Five diesel fuels were examined: a low-sulfur (∼1 ppm), low aromatic, hydrocracked fuel, the same low-sulfur fuel containing 15% v/v dimethoxy methane, a Fischer-Tropsch fuel, a California reformulated fuel, and a EPA number 2 certification fuel. A DaimlerChrysler OM611 CIDI engine was controlled with a SwRI Rapid Prototyping Electronic Control system. The pilot fuel injection was either turned off or turned on with engine control by either Location of Peak Pressure (LPP) of combustion or the original equipment manufacturer (OEM) calibration strategy. These three control strategies were compared over 2 speed-load modes run in triplicate. Thirty-three potentially toxic compounds were measured.

The objective of this study was to quantify engine-out emissions of potentially toxic compounds from a modern diesel engine operated with different fuels including 15% v/v dimethoxy methane in a low sulfur diesel fuel. Five diesel fuels were examined: a low-sulfur, low-aromatic hydrocracked (∼1 ppm) fuel, the same low sulfur fuel containing 15% v/v dimethoxy methane, a Fischer-Tropsch fuel, a CARB fuel, and an EPA number 2 certification fuel. A DaimlerChrysler OM611 CIDI engine was controlled with a SwRI Rapid Prototyping Electronic Control system. The engine was operated over 4 speed-load modes. Each operating mode and fuel combination was run in triplicate. Thirty three potentially toxic compounds were measured for each fuel and mode.

The physical in-cylinder processes and ignition during cold starting have been studied using computational models, with particular attention to the influences of blowby, heat transfer during the compression stroke, spray development, vaporization and fuel/air mixture formation and ignition. Two different modeling approaches were used. A thermodynamic zero dimensional cycle analysis program in which the fuel injection effects were not modeled, was used to determine overall and gas exchange effects. The three-dimensional KIVA-II code was used to determine details of the closed cycle events, with modified atomization, blowby and spray/wall impingement models, and a simplified model for ignition. The calculations were used to obtain an understanding of the cold starting process and to identify practical methods for improving cold starting of direct injection diesel engines.

A detailed comparison of cylinder pressure derived combustion performance and engine-out emissions is made between an all-metal single-cylinder light-duty diesel engine and a geometrically equivalent engine designed for optical accessibility. The metal and optically accessible single-cylinder engines have the same nominal geometry, including cylinder head, piston bowl shape and valve cutouts, bore, stroke, valve lift profiles, and fuel injection system. The bulk gas thermodynamic state near TDC and load of the two engines are closely matched by adjusting the optical engine intake mass flow and composition, intake temperature, and fueling rate for a highly dilute, low temperature combustion (LTC) operating condition with an intake O2 concentration of 9%. Subsequent start of injection (SOI) sweeps compare the emissions trends of UHC, CO, NOx, and soot, as well as ignition delay and fuel consumption.