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Alumina (Al2O3) thin film coatings are applied on Al alloys using Plasma Electrolytic Oxidation (PEO) method to reduce the wear and corrosion problems. Plasma Electrolytic Aluminating (PEA) is a technique which could generate Alumina coatings on cast iron, mild steel and copper alloys. In this study, the aim is to explore the anti-wear and anti-corrosion behaviours of PEA Alumina coatings on gray cast iron. The dry sliding tribology test data was obtained from Pin-on-Disk (POD) tests against SAE 52100 steel and Tungsten Carbide (WC) counterfaces. Comparing with the PEO Alumina coatings, the PEA Alumina coating has much lower Coefficient of Friction (COF) and less wear. The microstructure, chemical composition and phase composition of this coating were investigated with Scanning Electron Microscope (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX) and X-Ray Diffraction (XRD), respectively. There was FeO (or FeAl2O4) found on the PEA Alumina coating.

Gray cast iron brake rotor experiences substantial wear during braking and contributes largely to the wear debris emissions. Surface coating on the gray cast iron rotor represents a trending approach dealing with the problems. In this research, a new plasma electrolytic aluminating (PEA) process was used for preparing an alumina-based ceramic coating with metallurgical bonding to the gray cast iron. Three different types of brake pads (ceramic, semi-metallic and non asbestos organic (NAO)) were used for tribotests. Performances of PEA coatings vs. different brake pad materials were comparatively investigated with respect to their coefficients of friction (COFs) and wear. The PEA-coated brake rotor has a dimple-like surface which promotes the formation of a thin transferred film to protect the rotor from wear. The transferred film materials come from the wear debris of the pads. The secondary plateaus are regenerated on the brake pads through compacting wear debris of the pads.

Modern diesel engines employ a multitude of strategies for oxides of nitrogen (NOx) emission abatement, with exhaust gas recirculation (EGR) being one of the most effective technique. The need for a precise control on the intake charge dilution (as a result of EGR) is paramount since small fluctuations in the intake charge dilution at high EGR rates may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency, especially at low to mid-engine loads. The control problem becomes more pronounced during transient engine operation; currently the trend is to momentarily close the EGR valve during tip-in or tip-out events. Therefore, there is a need to understand the transient EGR behaviour and its impact on the intake charge development especially under unstable combustion regimes such as low temperature combustion.

Research studies have suggested that changes to the ignition system are required to generate a more robust flame kernel in order to secure the ignition process for the future advanced high efficiency spark-ignition (SI) engines. In a typical inductive ignition system, the spark discharge is initiated by a transient high-power electrical breakdown and sustained by a relatively low-power glow process. The electrical breakdown is characterized as a capacitive discharge process with a small quantity of energy coming mainly from the gap parasitic capacitor. Enhancement of the breakdown is a potential avenue effectively for extending the lean limit of SI engine. In this work, the effect of high-power capacitive spark discharge on the early flame kernel growth of premixed methane-air mixtures is investigated through electrical probing and optical diagnosis.

In order to reduce the weight of an automotive engine, an aluminum (Al) alloy engine block with cast iron liner has been successfully used to replace the gray cast iron engine. For newly emerging Al linerless engine in which the low surface hardness of the aluminum alloy has to be overcome, a few surface processing technologies are used to protect the surface of cylinders. Among them, plasma transferred wire arc (PTWA) thermal spraying coating is becoming popular. Plasma electrolytic oxidation (PEO) coating is also proposed for increasing the wear resistance of aluminum alloy and reducing the friction between the cylinder and piston. In this work, a PEO coating with a thickness of ∼20 μm was prepared, and a high speed pin-on-disc tribometer was used to study the tribological behavior of the coating at oil lubricant conditions. Different surface roughness of the coating and a large range of the sliding speeds were employed for the tests.

In this work, an innovative piston bowl design that physically divides the combustion chamber into a central zone and a peripheral zone is employed to assist the control of the ethanol-diesel combustion process via heat release shaping. The spatial combustion zone partition divides the premixed ethanol-air mixture into two portions, and the combustion event (timing and extent) of each portion can be controlled by the temporal diesel injection scheduling. As a result, the heat release profile of ethanol-diesel dual-fuel combustion is properly shaped to avoid excessive pressure rise rates and thus to improve the engine performance. The investigation is carried out through theoretical simulation study and empirical engine tests. Parametric simulation is first performed to evaluate the effects of heat release shaping on combustion noise and engine efficiency and to provide boundary conditions for subsequent engine tests.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.

Low temperature combustion (LTC) in diesel engines can be enabled using a multitude of fuel injection strategies, coupled with the elevated use of exhaust gas recirculation and intake boost. The common modes of LTC include the single-injection LTC with heavy EGR and the homogeneous charge compression ignition (HCCI), implemented with multiple early-injections during the compression stroke. Previous research indicates that the single-injection LTC is more suitable at low engine loads while the HCCI combustion can be targeted towards mid-load operation. To extend the load range of the LTC cycles, there is an urgent need to enable switching on-the-fly between the two combustion modes. The mode-switching is complicated by the fact that the challenges of enabling and ensuring stable engine operation under these two LTC modes are notably different.

The fatty acid alkyl esters derived from plants, rendered fats/oils and waste restaurant greases, commonly known as biodiesel, are renewable alternative fuels that may fulfill the demand gap caused by the depleting fossil diesel fuels. The combustion and emission characteristics of neat biodiesel fuels were investigated on a single cylinder of a 4-cylinder Ford common-rail direct injection diesel engine, which cylinder has been configured to have independent exhaust gas recirculation (EGR), boost and back pressures and exhaust gas sampling. The fatty acid methyl esters derived from Canola oil, soybean oil, tallow and yellow grease were first blended. Biodiesel engine tests were then conducted under the independent control of the fuel injection, EGR, boost and back pressure to achieve the low temperature combustion mode. Multi-pulse early-injections were employed to modulate the homogeneity history of the cylinder charge.

Low temperature combustion (LTC) strategies such as homogeneous charge compression ignition (HCCI), smokeless rich combustion, and reactivity controlled compression ignition (RCCI) provide for cleaner combustion with ultra-low NOx and soot emissions from compression-ignition engines. However, these strategies vary significantly in their implementation requirements, combustion characteristics, operability limits as well as sensitivity to boundary conditions such as exhaust gas recirculation (EGR) and intake temperature. In this work, a detailed analysis of the aforementioned LTC strategies has been carried out on a high-compression ratio, single-cylinder diesel engine. The effects of intake boost, EGR quantity/temperature, engine speed, injection scheduling and injection pressure on the operability limits have been empirically determined and correlated with the combustion stability and performance metrics.

A linerless aluminum (Al) engine block has potential to reduce the weight of an automotive engine and improve the fuel economy. However, the Al cylinder surface of an aluminum engine block is not usually strong enough to withstand the sliding wear against piston rings. A few surface processing technologies are used to protect the surface of cylinders. Among them, a thermal spraying coating, such as plasma transferred wire arc (PTWA) is already popular. Plasma electrolytic oxidation (PEO) coating is also proposed for increasing the wear resistance of aluminum-silicon (Al-Si) alloys and reducing the friction between the cylinder and piston. In this work, two different PEO coatings with a thickness of around 23 μm were prepared on an Al-Si alloy A356, and a high speed pin-on-disc tribometer was used to study the tribological behavior of the coatings at oil lubricant conditions. A cast iron sample was also used to do similar tribological tests for comparison.

This study investigated neat n-butanol combustion, emissions and thermal efficiency characteristics in a compression ignition (CI) engine by using two fuelling techniques - port fuel injection (PFI) and direct injection (DI). Diesel fuel was used in this research for reference. The engine tests were conducted on a single-cylinder four-stroke DI diesel engine with a compression ratio of 18.2 : 1. An n-Butanol PFI system was installed to study the combustion characteristics of Homogeneous Charge Compression Ignition (HCCI). A common-rail fuel injection system was used to conduct the DI tests with n-butanol and diesel. 90 MPa injection pressure was used for the DI tests. The engine was run at 1500 rpm. The intake boost pressure, engine load, exhaust gas recirculation (EGR) ratio, and DI timing were independently controlled to investigate the engine performance.

Ultra-high strength steel (UHSS) and magnesium (Mg) alloy have found their importance in response to automotive strategy of light weighting. UHSS to be metal-formed by hot stamping usually has a hot-dipped aluminum-silicon alloy layer on its surface to prevent the high temperature scaling during the hot stamping and corrosion during applications. In this paper, a plasma electrolytic oxidation (PEO) process was used to produce ceramic oxide coatings on aluminized UHSS and Mg with intention to further improve their corrosion resistances. A potentiodynamic polarization corrosion test was employed to evaluate general corrosion properties of the individual alloys. Galvanic corrosion of the aluminized UHSS and magnesium alloy coupling with and without PEO coatings was studied by a zero resistance ammeter (ZRA) test. It was found that the heating-cooling process simulating the hot stamping would reduce anti-corrosion properties of aluminized UHSS due to the outward iron diffusion.

This research work investigates the control strategies of fuel burn rate of neat n-butanol combustion to improve the engine load capability. Engine tests of homogeneous charge compression ignition (HCCI) and partially premixed combustion (PPC) with neat n-butanol show promising NOx and smoke emissions; however, the rapid burn rate of n-butanol results in excessive pressure rise rates and limits the engine load capability. A multi-event combustion strategy is developed to modulate the fuel burn rate of the combustion cycle and thus to reduce the otherwise high pressure rise rates at higher engine load levels. In the multi-event combustion strategy, the first combustion event is produced near TDC by the compression ignition of the port injected butanol that resembles the HCCI combustion; the second combustion event occurs near 7~12 degrees after TDC, which is produced by butanol direct injection (DI) after the first HCCI-like combustion event.

In this work, empirical investigations of the diesel-ethanol Premixed Pilot-Assisted Combustion (PPAC) are carried out on a high compression ratio (18.2:1) single-cylinder diesel engine. The tests focus on determining the minimum ethanol fraction for ultra-low NOx & soot emissions, effect of single-pilot vs. twin-pilot strategies on emissions and ignition controllability, reducing the EGR requirements, enabling clean combustion across the load range and achieving high efficiency full-load operation. The results show that both low NOx and almost zero soot emissions can be achieved but at the expense of higher unburned hydrocarbons. Compared to a single-pilot injection, a twin-pilot strategy reduces the soot emissions significantly and also lowers the NOx emissions, thereby reducing the requirements for EGR. The near-TDC pilot provides excellent control over the combustion phasing, further reducing the need of a higher EGR quantity for phasing control.

The use of low temperature combustion (LTC) in diesel engines tends to suppress the NOx and dry soot emissions from diesel engines. However, due to the limitations of conventional diesel fuel properties, such as the high reactivity and low volatility, implementation of LTC is highly dependent on the application of exhaust gas recirculation (EGR). While the replacement of some of the fresh air intake with the burnt exhaust gas using EGR prevents premature combustion, it also results in a reduction in thermal efficiency. In this work, the use of two different alcohol fuels, ethanol and butanol, in a high compression ratio diesel engine has been investigated to examine their potential as substitutes for conventional diesel fuel when operating under low temperature combustion mode. The effect of diesel injection timing, alcohol fuel ratios, and EGR on engine emissions and efficiency were studied at indicated mean effective pressures in the range 0.8 to 1.2 MPa.

An experimental investigation of low temperature combustion (LTC) cycles is conducted with diesel and ethanol fuels on a high compression ratio (18.2:1), common-rail diesel engine. Two LTC modes are studied; near-TDC injection of diesel with up to 60% exhaust gas recirculation (EGR), and port injected ethanol ignited by direct injection of diesel with moderate EGR (30-45%). Indicated mean effective pressures up to 10 bar in the diesel LTC mode and 17.6 bar in the dual-fuel LTC mode have been realized. While the NOx and smoke emissions are significantly reduced, a thermal efficiency penalty is observed from the test results. In this work, the efficiency penalty is attributed to increased HC and CO emissions and a non-conventional heat release pattern. The influence of heat release phasing, duration, and shape, on the indicated performance is explained with the help of parametric engine cycle simulations.

Experimental testing was done with a modern compression ignition engine to study the effect of the engine load and the effect of different fuels on the post injection characteristics. Two different fuels were utilized; ultra-low sulphur diesel and n-butanol. The results showed that a post injection can be an effective method for increasing the operating range of the engine load. Engine operation at high load can be limited by the peak cylinder pressure but the test results showed that an early post injection can increase the engine load without increasing the peak in-cylinder pressure. Neat butanol combustion may have a very high peak in-cylinder pressure and a very high peak pressure rise rate even at low load conditions. The test results showed that a butanol post injection can contribute to engine power without significantly affecting the peak pressure rise rate and the peak in-cylinder pressure.

The study investigated the characteristics of the combustion, the emissions and the thermal efficiency of a direct injection diesel engine fuelled with neat n-butanol. Engine tests were conducted on a single cylinder four-stroke direct injection diesel engine. The engine ran at 6.5 bar IMEP and 1500 rpm engine speed. The intake pressure was boosted to 1.0 bar (gauge), and the injection pressure was controlled at 60 or 90 MPa. The injection timing and the exhaust gas recirculation (EGR) rate were adjusted to investigate the engine performance. The effect of the engine load on the engine performance was also investigated. The test results showed that the n-butanol fuel had significantly longer ignition delay than that of diesel fuel. n-Butanol generally led to a rapid heat release pattern in a short period, which resulted in an excessively high pressure rise rate. The pressure rise rate could be moderated by retarding the injection timing and lowering the injection pressure.