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In order to meet the requirements in the stringent emission regulations, more and more research work has been focused on homogeneous charge compression ignition (HCCI) and partially premixed combustion (PPC) or partially premixed compression ignition (PCCI) as they have the potential to produce low NOx and soot emissions without adverse effects on engine efficiency. The mixture formation and charge stratification influence the combustion behavior and emissions for PPC/PCCI, significantly. An ultra-high speed burst-mode laser is used to capture the mixture formation process from the start of injection until several CADs after the start of combustion in a single cycle. To the authors’ best knowledge, this is the first time that such a high temporal resolution, i.e. 0.2 CAD, PLIF could be accomplished for imaging of the in-cylinder mixing process. The capability of resolving single cycles allows for the influence of cycle-to-cycle variations to be eliminated.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

The effects of injection pressure and swirl ratio on the in-cylinder soot oxidation are studied using simultaneous PLIF imaging of OH and LII imaging of soot in an optical diesel engine. Images are acquired after the end of injection in the recirculation zone between two adjacent diesel jets. Scalars are extracted from the images and compared with trends in engine-out soot emissions. The soot emissions decrease monotonically with increasing injection pressure but show a non-linear dependence on swirl ratio. The total amount of OH in the images is negatively correlated with the soot emissions, as is the spatial proximity between the OH and soot regions. This indicates that OH is an important soot oxidizer and that it needs to be located close to the soot to perform this function. The total amount of soot in the images shows no apparent correlation with the soot emissions, indicating that the amount of soot formed is a poor predictor of the emission trends.

As engine efficiency targets continue to rise, additional improvements must consider reduction of heat transfer losses. The development of advanced heat transfer models and realistic boundary conditions for simulation based engine design both require accurate in-cylinder wall temperature measurements. A novel dual wavelength infrared diagnostic has been developed to measure in-cylinder surface temperatures with high temporal resolution. The diagnostic has the capability to measure low amplitude, high frequency temperature variations, such as those occurring during the gas exchange process. The dual wavelength ratio method has the benefit of correcting for background scattering reflections and the emission from the optical window itself. The assumption that background effects are relatively constant during an engine cycle is shown to be valid over a range of intake conditions during motoring.

PM in diesel exhaust has been given much attention due to its adverse effect on both climate and health. As the PM emission levels are tightened, the portion of particles originating from the lubrication oil is likely to increase. In this study, exhausts from a biodiesel-fueled Euro 5 engine were examined to determine how much of the carbonaceous particles that originated from the fuel and the lubrication oil, respectively. A combination of three methods was used to determine the PM origin: chain length analysis of the hydrocarbons, determination of organic and elemental carbon (OC and EC), and the concentration of 14C found in the exhausts. It was found that the standard method for measuring hydrocarbons in PM on a filter (chain length analysis) only accounted for 63 % of the OC, meaning that it did not account for all non-soot carbon in the exhausts.

Dimethyl Ether (DME) has proved to be a promising fuel for diesel engines. It virtually eliminates particulate emissions and reduces the formation of nitrogenous oxides, without negatively affecting engine efficiency. Obtaining a deeper understanding of the mechanisms behind these properties is thus highly desirable. Various authors have suggested that the low NO emissions associated with DME are an effect of the mixing conditions, which are thought to differ from those of diesel sprays. To examine this, laser-Rayleigh imaging was employed for quantitative measurement of the local equivalence ratios in DME sprays. The quantitative images were analyzed using a statistical approach, in which probability distributions of ϕ-values for burning and for non-reacting sprays were compared. It was concluded that the diffusion flame is established in the stoichiometeric or slightly lean regions of the spray.

This study evaluates the performance of an indirect injection (IDI) diesel engine fueled with cotton seed biodiesel while assessing the engine's multi-fuel capability. Millions of tons of cotton seeds are available in the south of the US every year and approximately 10% of oil contained in the seeds can be extracted and transesterified. An investigation of combustion, emissions, and efficiency was performed using mass ratios of 20-50% cotton seed biodiesel (CS20 and CS50) in ultra-low sulfur diesel #2 (ULSD#2). Each investigation was run at 2400 rpm with loads of 4.2 - 6.3 IMEP and compared to the reference fuel ULDS#2. The ignition delay ranged in a narrow interval of 0.8-0.97ms across the blends and the heat release rate showed comparable values and trends for all fuel blends. The maximum volume averaged cylinder temperature increased by approximately 100K with each increase in 1 bar IMEP load but the maximum remained constants across the blends.

Soot emissions from diesel engines are the net result of two competing processes: soot formation and soot oxidation. Previous studies have shown poor correlation between soot formation rates and the soot emissions. This article presents a systematic study of a number of parameters affecting soot oxidation rate and how it correlates with the soot emissions. An optical heavy-duty engine is used in conjunction with a laser extinction setup in order to collect time resolved data of the soot concentration in the cylinder during the expansion stroke. Laser extinction is measured using a red (685 nm) laser beam, which is sent vertically through the cylinder and modulated to produce 10 pulses per crank angle degree. Information is obtained about the amount of soot formed and the soot oxidation rate. The parameters studied are the motored density at top dead center (TDC), motored temperature at TDC, injection pressure, engine speed, swirl level and injector orifice diameter.

The influence of soy- and palm-based biofuels on the in-cylinder sources of unburned hydrocarbons (UHC) and carbon monoxide (CO) was investigated in an optically accessible research engine operating in a partially premixed, low-temperature combustion regime. The biofuels were blended with an emissions certification grade diesel fuel and the soy-based biofuel was also tested neat. Cylinder pressure and emissions of UHC, CO, soot, and NOx were obtained to characterize global fuel effects on combustion and emissions. Planar laser-induced fluorescence was used to capture the spatial distribution of fuel and partial oxidation products within the clearance and bowl volumes of the combustion chamber. In addition, late-cycle (30° and 50° aTDC) semi-quantitative CO distributions were measured above the piston within the clearance volume using a deep-UV LIF technique.

Methanol is not a fuel typically used in compression ignition engines due to the high resistance to auto-ignition. However, conventional diesel combustion and PPC offer high engine efficiency along with low HC and CO emissions, albeit with the trade-off of increased NOx and PM emissions. This trade-off balance is mitigated in the case of methanol and other alcohol fuels, as they bring oxygen in the combustion chamber. Thus methanol compression ignition holds the potential for a clean and effective alternative fuel proposition. Most existing research on methanol is on SI engines and very little exists in the literature regarding methanol auto-ignition engine concepts. In this study, the spray characteristics of methanol inside the optically accessible cylinder of a DI-HD engine are investigated. The liquid penetration length at various injection timings is documented, ranging from typical PPC range down to conventional diesel combustion.

Yearly 3.3 million premature deaths occur worldwide due to air pollution and NOx pollution counts for nearly one seventh of those [1]. This makes exhaust after-treatment a very important research and has caused the permitted emission levels for NOx to decrease to very low levels, for EURO 6 only 0.4 g/kWh. Recently new legislation on ammonia slip with a limit of 10 ppm NH3 has been added [2], which makes the SCR-technology more challenging. This technology injects small droplets of an aqueous Urea solution into the stream of exhaust gases and through a catalytic reaction within the SCR-catalyst, NOx is converted into Nitrogen and Water. To enable the catalytic reaction the water content in the Urea solution needs to be evaporated and the ammonia molecules need to have sufficient time to mix with the gases prior to the catalyst.

The paper presents a large eddy simulation investigation on the effect of fuel injection pressure on mixing, in an optical heavy-duty diesel engine. Recent investigation on impinging wall jets at constant-volume and quiescent conditions exhibited augmented air entrainment in wall jets with increasing injection pressure, when compared with a free jet. The increased mixing rates were explained as owing to enhanced turbulence and vortex formation in the jet-tip in the recirculation zone. A recent investigation carried out in an optical heavy-duty diesel engine indicated however a negligible effect of injection pressure on the mixing in the engine environment. The effect of enhanced turbulence and vortex formation of the jet-tip in the recirculation zone is believed weaker than the effect of engine confinement, due to the presence of fuel from adjacent jets limiting the mixing the fuel with the ambient gas.

Small closely-coupled post injections of fuel in diesel engines are known to reduce engine-out soot emissions, but the relative roles of various underlying in-cylinder mechanisms have not been established. Furthermore, the efficacy of soot reduction is not universal, and depends in unclear ways on operating conditions and injection schedule, among other factors. Consequently, designing engine hardware and operating strategies to fully realize the potential of post-injections is limited by this lack of understanding. Following previous work, several different post-injection schedules are investigated using a single-cylinder 2.34 L heavy-duty optical engine equipped with a Delphi DFI 1.5 light-duty injector. In this configuration, adding a closely-coupled post injection with sufficiently short injection duration can increase the load without increasing soot emissions.

The influence of the ignition quality of diesel-and gasoline-like fuels on the lift-off length of the jet were investigated in an optical heavy duty engine. The engine was operated at a load of 22 bar IMEPg and 1200 rpm. A production type injector with standard holes were used. The lift-off length was recorded with high speed video Different injection pressures and inlet temperatures were used to affect conditions that consequently affect the lift-off length. No matter which fuel used nor injection pressure or inlet temperature, all lift-off lengths showed equal or close to equal lift-off length when stabilized. The higher octane fuel had a longer ignition delay and therefore the fuel penetrate the combustion chamber before auto ignition. This gave a longer lift-off length at the initial stage of combustion before reaching the same stabilized lift-off length. These results indicate that the hot combustion gases are a dominant factor to the lift-off length.

The influence of jet-flow and jet-jet interactions on the lift-off length of diesel jets are investigated in an optically accessible heavy-duty diesel engine. High-speed OH chemiluminescence imaging technique is employed to capture the transient evolution of the lift-off length up to its stabilization. The engine is operated at 1200 rpm and at a constant load of 5 bar IMEP. Decreasing the inter-jet spacing shortens the liftoff length of the jet. A strong interaction is also observed between the bulk in-cylinder gas temperature and the inter-jet spacing. The in-cylinder swirl level only has a limited influence on the final lift-off length position. Increasing the inter-jet spacing is found to reduce the magnitude of the cycle-to-cycle variations of the lift-off length.

High-speed OH chemiluminescence imaging is used to measure the lift-off length of diesel sprays in an optical heavy-duty diesel engine of 2 L displacement operated at 1200 rpm and 5 bar IMEP. Stereoscopic images are acquired at two different wavelengths (310 and 330 nm). Subtraction of pairwise images helps reducing the background coming from natural soot incandescence in the OH chemiluminescence images. Intake air temperature (343 to 403 K), motored top dead center density (18 to 22 kg/m3), fuel injection pressure (150 to 250 MPa), intake oxygen concentration (17 to 21 %vol) and nozzle diameter (0.1 and 0.14 mm) are varied and a nonlinear regression model is derived from the experimental results to describe stabilized lift-off length as function of the experimental factors. The lift-off length follows the general trends that are known from spray vessel investigations, but the strength of the dependence on certain variables deviates strongly from those studies.

Laser-Rayleigh imaging has been employed to measure the relative fuel concentration in the gaseous jet region of DME sprays. The measurements were performed in an optically accessible diesel truck engine equipped with a common rail injection system. A one-hole nozzle was used to guarantee that the recorded pressure history was associated with the heat release in the imaged spray. To compensate for the low compression ratio in the modified engine the inlet air was preheated. Spray development was studied for two levels of preheating, from the start of injection to the point where all fuel was consumed. The results indicate that there is a strong correlation between the amount of unburned fuel present in the cylinder and the rate of heat release at a given time. The combustion can not be described as purely premixed or purely mixing-controlled at any time, but always has an element of both. After all fuel appears to have vanished there is still an extended period of heat release.

An HSDI Diesel engine was fuelled with standard Swedish environmental class 1 Diesel fuel (MK1), Soy methyl ester (B100) and n-heptane (PRF0) to study the effects of both operating conditions and fuel properties on engine performance, resulting emissions and spray characteristics. All experiments were based on single injection diesel combustion. A load sweep was carried out between 2 and 10 bar IMEPg. For B100, a loss in combustion efficiency as well as ITE was observed at low load conditions. Observed differences in exhaust emissions were related to differences in mixing properties and spray characteristics. For B100, the emission results differed strongest at low load conditions but converged to MK1-like results with increasing load and increasing intake pressures. For these cases, spray geometry calculations indicated a longer spray tip penetration length. For low-density fuels (PRF0) the spray spreading angle was higher.