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NOx emissions from diesel passenger vehicles affect the atmospheric environment. It is difficult to evaluate the NOx emissions influenced by environmental conditions such as humidity and temperature, traffic conditions, driving patterns, etc. In the authors’ previous study, real-driving experiments were performed on city and highway routes using a diesel passenger car with only an exhaust gas recirculation system. A statistical prediction model of NOx emissions was considered for simple estimations in the real world using instantaneous vehicle data measured by the portable emissions measurement system and global positioning system. The prediction model consisted of explanatory variables, such as velocity, acceleration, road gradient, and position of transmission gear. Using the explanatory variables, NOx emissions on the city and highway routes was well predicted using a diesel vehicle without NOx reduction devices.

The authors have explored the potential of fuel to control spray and its combustion processes in a diesel engine. Fuel has some potential for low emission and high thermal efficiency because its volatility and ignitability are one of the ultimate performing factors of the engines. In present study, the ignition process of mixed fuel spray was investigated in a constant volume combustion vessel and in a rapid compression and expansion machine, The ignition delay based on the diagram of rate of the heat release, the imaging of natural flame emissions and the numerical simulation were carried out to clarify the effect of the physical and chemical properties of mixed fuel on ignition characteristics.

N₂O is known to have a significantly high global warming potential. We measured N₂O emissions in engine-bench tests by changing the NO/NH₃ ratio and exhaust gas temperature at the oxidation catalyst inlet in a heavy-duty diesel engine equipped with a urea SCR (selective catalytic reduction) system. The results showed that the peak N₂O production ratio occurred at an exhaust gas temperature of around 200°C and the maximum value was 84%. Moreover, the N₂O production ratio increased with increasing NO/NH₃. Thus, we concluded that N₂O is produced via the NO branching reaction. Based on our results, two methods were proposed to decrease N₂O formation. At low temperatures ~200°C, NO should be reduced by controlling diesel combustion to lower the contribution of NO to N₂O production. This is essential because the SCR system cannot reduce NOx at low temperatures.

A variable valve timing (VVT) mechanism was applied to achieve premixed diesel combustion at higher load for low emissions and high thermal efficiency in a light duty diesel engine. By means of late intake valve closing (LIVC), compressed gas temperatures near the top dead center are lowered, thereby preventing too early ignition and increasing ignition delay to enhance fuel-air mixing. The variability of effective compression ratio has significant potential for ignition timing control of conventional diesel fuel mixtures. At the same time, the expansion ratio is kept constant to ensure thermal efficiency. Combining the control of LIVC, EGR, supercharging systems and high-pressure fuel injection equipment can simultaneously reduce NOx and smoke. The NOx and smoke suppression mechanism in the premixed diesel combustion was analyzed using the 3D-CFD code combined with detailed chemistry.

This study proposes a hybrid model which consists of modified TAB(Taylor Analogy Breakup) model and DVM(Discrete Vortex Method). In this study, the simulation process is divided into three steps. The first step is to analyze the breakup of droplet of injected fuel by using modified TAB model. The second step based on the theory of Siebers' liquid length is analysis of spray evaporation. The liquid length analysis of injected fuel is used for connecting both modified TAB model and DVM. The final step is to reproduce the ambient gas flow and inner vortex flow injected fuel by using DVM. In order to examine the hybrid model, an experiment of a free evaporating fuel spray at early injection stage of in-cylinder like conditions had been executed. The numerical results calculated by using the present hybrid model are compared with the experimental ones.

This paper presents an atomization mechanism of a spray injected into the low-pressure field, as the subject of injection system in a suction manifold of gasoline engine. Pure liquid fuel, which is n-Pentane or n-Hexane is injected into quiescent gaseous atmosphere at room-temperature and low- pressure through pintle type electronic control injector. Fuel sprays are observed by taking photographs for variation of the back pressure and the changes in spray characteristics with the back pressure below atmospheric pressure are examined in detail. In particular, in the case of the back pressure below the saturated vapor pressure of fuel, the atomization mechanism is discussed from a viewpoint of flash boiling phenomena, those are bubble growth rate and so on.

Reduction of exhaust emissions and BSFC has been studied using a high boost, a wide range and high-rate EGR in a Super Clean Diesel, six-cylinder heavy duty engine. In the previous single-turbocharging system, the turbocharger was selected to yield maximum torque and power. The selected turbocharger was designed for high boosting, with maximum pressure of about twice that of the current one, using a titanium compressor. However, an important issue arose in this system: avoidance of high boosting at low engine speed. A sequential and series turbo system was proposed to improve the torque at low engine speeds. This turbo system has two turbochargers of different sizes with variable geometry turbines. At low engine speed, the small turbocharger performs most of the work. At medium engine speed, the small turbocharger and large turbocharger mainly work in series.

Copper ion-exchanged ZSM-5 zeolite catalyst, which reduces nitrogen oxides (NOx) in the presence of oxygen and hydrocarbons, was applied to actual diesel engine exhaust. Copper ion-exchanged ZSM-5 zeolite effectively reduced NOx by 25% in normal engine operation, and by 80% when hydrocarbons in the exhaust were increased. Water in the exhaust gas decreased the NOx reduction efficiency, but oxygen and sulfur appeared to have only a small effect. Maximum NOx reduction was observed at 400°C irrespective of hydrocarbon species, and did not decrease with space velocity up to values of 20,000 1/h. THE PURPOSE of this paper is to evaluate the possibilities and problems in catalytic reduction of NOx in actual diesel engine exhaust. Here, a copper ion-exchanged ZSM-5 zeolite (Cu-Z) catalyst was applied to diesel engine exhaust to examine the dependency of the NOx reduction efficiency on temperature and space velocity. The effects of oxygen, water and hydrocarbons were also examined.

A transient gas jet seems to be a model of a diesel spray because it has no vaporization process. Recently, CNG is utilized in a diesel engine. In the case of diesel engine, sprays or jets have the free state in some cases, and they are impinging surely on the piston surface in the other cases. The 2-D image of acetylene gas with tracer particles was taken by high-speed photography. In both jets, the outer shape was measured on the images and the characteristics of the internal flow was obtained by particle image velocimetry. Then, the physical models of these jets were constructed by use of experimental results.

In a small high-speed DI diesel engine, injected fuel sprays impinge on the wall of piston cavity. Discussion and analysis of the combustion phenomena in the diesel engine demand the measurement of the characteristics of the impinging spray. In the experiments presented here, diesel fuel oil was injected into a high pressure chamber in which compressed air or CO2 gas at room temperature was charged. The single spray was impinged on a flat wall at a normal angle. The growth of the spray was photographed, not only with transmitted light but also with scattered light through a narrow slit. The temporal and spatial distribution of the droplets density in the impinging spray applying the concentric circle model was calculated using the data of the laser light extinction method. From these results, the detailed information concerning the droplets density in the impinging diesel spray was obtained.

It is unavoidable that a DI diesel engine exhausts a blue and white smoke at starting, especially in the cold atmosphere. In the experiments presented here, a small DI diesel engine started under the conditions of coolant and suction air whose minimum temperatures were 255 K and 268 K, respectively. The flame was photographed by high-speed photography, the temperature of flame and the soot concentration were measured by two-color method, and CO2 concentration was detected by luminous method. The engine cannot be started over several cycles when the coolant temperature is 255 K and suction air temperature is 268 K. As the temperature of coolant and suction air are decreasing, the maxima of the cylinder pressure, the flame temperature, the soot concentration and CO2 concentration are decreasing. Luminous small dots or small lumps of flame become scattered in the piston cavity.

Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

To find a clue to reduction techniques for Nitrous Oxide (N2O) emission from three-way catalyst equipped vehicles, four test samples of three-way catalysts with typical noble metal compositions were fabricated by way of experiment and their N2O formation characteristics have been experimentally studied. Then, these catalyst samples were conditioned artificially by aging with real automotive exhaust gas and the N2O formation characteristics after aging has been also observed. As results, catalyst temperature zones and concentration levels of N2O formation varies greatly by the catalyst composition. In general, a catalyst with lower metal content showed lower N2O mass emission at both fresh and after aging conditions. The tendency of the increase in N2O mass emission due to the deterioration is also different among the tested catalyst samples.

To establish NOx Storage Reduction(NSR) system, the effect of post fuel injection in exhaust pipe with rich spike on NOx conversion rate was investigated. With post fuel injection, a higher injection pressure and the rich spike close to the NSR catalyst (just before the NSR catalyst) shows better NOx reduction performance. Based on these results, exhaust emission was tested in transient driving mode (JE-05). In this driving mode test, it was possible to reduce NOx emission less than 0.5 g/kWh for only a 1% of fuel penalty controlling the rich spike injection precisely.

Recently, after-treatment techniques for diesel engine emission have made remarkable progress with the development of suitable De-NOx catalysts. The urea-injection SCR system is one of the candidates for a high efficiency De-NOx method for diesel engine emissions. This system reduces NOx through a reaction with ammonia (NH3) that is generated from injected urea. In this system, it is very important to control the amount and timing of the urea injection so as to minimize the NH3 gas slip. Therefore, NH3 gas measurement is becoming important during the development of NOx after-treatment systems even though NH3 is not a target component of the current emission regulations. In this paper, a new NH3 gas analyzer utilizing a chemi-luminescence detection (CLD) method has been developed. The new NH3 analyzer consists of dual detectors (DCLDs) and a furnace for a NH3 oxidization catalyst. Real-time concentration of NH3 can be calculated from the difference of NOx readings of two detectors.

Diesel sprays injected into a combustion chamber of a small sized high-speed CI engine impinge surely on a piston surface and a cylinder wall. As a consequence, their vaporization, mixture formation and combustion processes are affected by impingement phenomena. And the other important factors affecting on the processes is the injection pressure. Then, the distribution of the vapor concentration in a single diesel spray impinging on a flat and hot wall was experimented by the exciplex fluorescence method, as a simple case. The injection pressure was varied in the range from 55 MPa to 120 MPa. It is found that the distribution of the vapor concentration in this case is much leaner than that in the case of the low injection pressure of 17.8MPa.

In this paper, spray characteristics were examined to deduce the effect of ambient gas properties. Considered ambient properties were the viscosity μa and density ρa, and thus the kinematic viscosity νa. The objective of this paper is to reveal the effect of compressibility of the ambient gas to spray formation. In the experiments, the changed ranges were And a standard-sac volume nozzle of hole diameter dn =0.25 mm (ln/dn=3.0) was used at constant injection pressure difference (Δp=16.2 MPa). Also the injection pressure was varied in the range of 55 to 120 MPa with a mini-sac volume nozzle of hole diameter dn =0.20 mm (ln/dn =5.5). Several different gases were used to change the ambient viscosity at a room temperature. From the experiments, it is obtained that larger the viscosity, the more the spray spreads in the radial direction, thus the spray angle gets larger and the tip penetration became shorter.

In this study, a numerical experiment using a 2D convective equation and LES of an evaporative diesel spray for different convective schemes has been performed to examine effects of convective schemes on a fuel-air mixture formation of the diesel spray simulation and to determine the convective scheme used in KIVALES. In addition to KIVALES original schemes, such as QSOU, PDC and IDC, CIP was incorporated into KIVALES in order to calculate the convective terms with low numerical diffusion. The numerical experiment using the 2D convective equation showed that the numerical diffusion of CIP scheme was lowest in the convective schemes used in present study. However CIP scheme used was not a monotone scheme completely due to the overshoot and the undershoot of the scalar provided near the boundary. Hence, CIP scheme was employed for only the convective term of the LES momentum equation, while the other convective schemes were calculated using QSOU, which is a monotone scheme.

Reduction of exhaust emissions and BSFC was studied for high pressure, wide range, and high EGR rates in a Super-clean Diesel six-cylinder heavy duty engine. The GVW 25-ton vehicle has 10.52 L engine displacement, with maximum power of 300 kW and maximum torque of 1842 Nm. The engine is equipped with high-pressure fuel injection of a 200 MPa level common-rail system. A variable geometry turbocharger (VGT) was newly designed. The maximum pressure ratio of the compressor is about twice that of the previous design: 2.5. Additionally, wide range and a high EGR rate are achieved by high pressure-loop EGR (HP-EGR) and low pressure-loop EGR (LP-EGR) with described VGT and high-pressure fuel injection. The HP-EGR can reduce NOx concentrations in the exhaust pipe, but the high EGR rate worsens smoke. The HP-EGR system layout has an important shortcoming: it has great differences of the intake EGR gas amount into each cylinder, worsens smoke.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).