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The effects of hydrogen peroxide addition on iso-octane/air Homogeneous Charge Compression Ignition (HCCI) combustion have been investigated analytically. Particular attention was focused on the predications involving homogeneous gas-phase kinetics. Use was made of Peters' iso-octane mechanism in CHEMKIN and convective heat transfer was included in the analyses. This enabled the influences that H2O2 addition has on species concentration and ignition promotion and hence exhaust emissions to be determined. It was found that both CO and NOx emission levels could be ameliorated. The former effect is considered to be a result of the decomposition of H2O2 into OH intermediate species and hence reducing the time to ignition and the onset of combustion.

Research studies have suggested that changes to the ignition system are required to generate a more robust flame kernel in order to secure the ignition process for the future advanced high efficiency spark-ignition (SI) engines. In a typical inductive ignition system, the spark discharge is initiated by a transient high-power electrical breakdown and sustained by a relatively low-power glow process. The electrical breakdown is characterized as a capacitive discharge process with a small quantity of energy coming mainly from the gap parasitic capacitor. Enhancement of the breakdown is a potential avenue effectively for extending the lean limit of SI engine. In this work, the effect of high-power capacitive spark discharge on the early flame kernel growth of premixed methane-air mixtures is investigated through electrical probing and optical diagnosis.

The majority of transportation systems have continued to be powered by the internal combustion engine and fossil fuels. Heavy-duty applications especially are reliant on diesel engines for their high brake efficiency, power density, and robustness. Although engineering developments have advanced engines towards significantly fewer emissions and higher efficiency, the use of fossil-derived diesel as fuel sets a fundamental threshold in the achievable total net carbon reduction. Dimethyl ether can be produced from various renewable feedstocks and has a high chemical reactivity making it suitable for heavy-duty applications, namely compression ignition direct injection engines. Literature shows the successful use of DME fuels in diesel engines without significant hardware modifications.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

A number of cylinder-pressure derived parameters including the crank angles of maximum pressure, maximum rate of pressure rise, and 50% heat released are considered as among the desired feedback for cycle-by-cycle adaptive control of diesel combustion. For real-time computation of these parameters, the heat release analyses based on the first law of thermodynamics are used. This paper intends to identify the operating regions where the simplified heat release approach provides sufficient accuracy for control applications and also highlights those regions where its use can lead to significant errors in the calculated parameters. The effects of the cylinder charge-to-wall heat transfer and the temperature dependence of the specific heat ratio on the model performance are reported. A new computationally efficient algorithm for estimating the crank angle of 50% heat released with adequate accuracy is proposed for computation in real-time.

Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. The robustness and efficiency of LTC operation in diesel engines can be enhanced with improvements in the promptness and accuracy of combustion control. A set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations. The cylinder pressure traces were analyzed to update the heat release rate concurrently as the combustion process proceeds prior to completing an engine cycle. Engine dynamometer tests demonstrated that such prompt heat release analysis was effective to optimize the LTC and the split combustion events for better fuel efficiency and exhaust emissions.

The diesel fuel reforming process in an exhaust gas recirculation (EGR) loop of a diesel engine is capable of utilizing the engine exhaust energy to support the endothermic process of hydrogen gas generation. However, the EGR stream commonly needs to be heated to enable the operation of the reformer and thus to sustain higher yield of hydrogen. A central-fuelling and flow-reversal embedment that is energy-efficient to raise the central temperatures of the catalytic flow-bed is therefore devised and tested to drastically reduce the supplemental heating to the EGR reformer. One-dimensional modeling analyses are conducted to evaluate the fuel delivery strategies and temperature profiles of the reformer at various reforming gas flow rates and engine-out exhaust temperatures and compositions. This research attempts to quantify the energy saving by the catalytic flow-reversal and central-fuelling embedment in comparison to a unidirectional flow EGR reformer.

Compression ignition internal combustion engines provide unmatched power density levels, making them suitable for numerous applications including heavy-duty freight trucks, marine shipping, and off-road construction vehicles. Fossil-derived diesel fuel has dominated the energy source for CI engines over the last century. To mitigate the dependency on fossil fuels and lessen anthropogenic carbon released into the atmosphere within the transportation sector, it is critical to establish a fuel source which is produced from renewable energy sources, all the while matching the high-power density demands of various applications. Dimethyl ether (DME) has been used in non-combustion applications for several decades and is an attractive fuel for CI engines because of its high reactivity, superior volatility to diesel, and low soot tendency. A range of feedstock sources can produce DME via the catalysis of syngas.

The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines.

A novel catalytic converter technology, employing periodical reversal of gas flow through the oxidation catalyst monolith, is being developed for treatment of exhaust gas from diesel engines fueled by natural gas in combination with diesel fuel. This technology allows to trap heat energy inside the monolith and thus efficiently destroy methane at converter inlet temperature as low as ambient. This paper describes the results of the initial stage of the converter development, including development of the mathematical model, computer simulation, and prototype testing. Simulation results indicate that dual fuel engine equipped with the reverse-flow converter could exceed the required destruction standards for hydrocarbons, including methane.

Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.

The dual-fuel application using ethanol and diesel fuels can substantially improve the classical trade-off between oxides of nitrogen (NOx) and smoke, especially at moderate-to-high load conditions. However, at low engine load levels, the use of a low reactivity fuel in the dual-fuel application usually leads to increased incomplete combustion products that in turn result in a significant reduction of the engine thermal efficiency. In this work, engine tests are conducted on a high compression ratio, single cylinder dual-fuel engine that incorporates the diesel direct-injection and ethanol port-injection. Engine load levels are identified, at which, diesel combustion offers better efficiency than the dual-fuel combustion while attaining low NOx and smoke emissions. Thereafter, a cycle-to-cycle based closed-loop controller is implemented for the combustion phasing and engine load control in both the diesel and dual-fuel combustion regimes.

Taking advantages of high speed RGB video cameras, the two-color method can be implemented with a relatively simple setup to obtain the temporal development of the two dimensional temperature and soot (KL) distributions in a reacting diesel jet. However, several issues such as the selection of the two wavelengths, the role of bandpass filters, and the proper optical settings, etc. should be known to obtain a reliable measurement. This paper, at first, discusses about the uncertainties in the measurement of temperature and KL distributions in the diesel flame by the two-color method using the high speed RGB video camera. Since n-butanol, as an alternative renewable fuel, has the potential application in diesel engines, the characteristic of spray combustion of diesel-butanol blends under the diesel-like ambient conditions in a pre-burning constant-volume combustion chamber is studied.

The fatty acid alkyl esters derived from plants, rendered fats/oils and waste restaurant greases, commonly known as biodiesel, are renewable alternative fuels that may fulfill the demand gap caused by the depleting fossil diesel fuels. The combustion and emission characteristics of neat biodiesel fuels were investigated on a single cylinder of a 4-cylinder Ford common-rail direct injection diesel engine, which cylinder has been configured to have independent exhaust gas recirculation (EGR), boost and back pressures and exhaust gas sampling. The fatty acid methyl esters derived from Canola oil, soybean oil, tallow and yellow grease were first blended. Biodiesel engine tests were then conducted under the independent control of the fuel injection, EGR, boost and back pressure to achieve the low temperature combustion mode. Multi-pulse early-injections were employed to modulate the homogeneity history of the cylinder charge.

Compression ignition engines used in heavy-duty applications are typically powered by diesel fuel. The high energy density and feedstock abundance provide a continuing source for the immense energy demand. However, the heavy-duty transportation sector is challenged with lowering greenhouse gas and combustion by-product emissions, including carbon dioxide, nitrogen oxides, and particulate matter. The continuing development of engine management and combustion strategies has proven the ability to meet current regulations, particularly with higher fuel injection pressure. Nonetheless, a transition from diesel to a renewable alternative fuel source will play a significant role in reducing greenhouse gases while maintaining the convenience and energy density inherent in liquid fuels. Dimethyl ether is a versatile fuel that possesses combustion properties suitable for compression ignition engines and physical properties helpful for clean combustion.

The combustion and emission characteristics of dual-fuel combustion were investigated using dimethyl ether direct injection and premixed low-carbon fuels. Dimethyl ether was used as the direct injection fuel for its high reactivity and low propensity to form particulate matter. Ethanol and Propane, two fuels of low reactivity, were premixed in the intake port. An injection timing sweep of varying premixed energy shares and engine loads was tested. Combustion analysis was conducted based on in-cylinder pressure measurements while detailed speciation of engine-out emissions was performed via FTIR. The proper injection advance and premixed energy share can realize low NOx and high combustion efficiency. Ethanol showed stronger impact to DME ignition delay as compared with propane.

The exhaust emission and performance characteristics of a 100% biodiesel fuel was evaluated on a single cylinder direct injection diesel engine that had been modified to allow multi-pulse diesel fuel injection at the intake port and independent control of intake heating, exhaust gas recirculation and throttling. Firstly, conventional single-shot direct injection tests were conducted and comparisons made between the use of an ultra-low sulphur diesel fuel and the biodiesel fuel. Secondly, tests for the premixed combustion of neat biodiesel were performed. Exhaust gas recirculation was applied extensively to initiate the low temperature combustion for the conventional in-cylinder single injection operation and to moderate the timing of the homogeneous charge compression ignition for the intake-port sequential injection. Because of the high viscosity and low volatility of the biodiesel, pilot-ignited homogeneous charge compression ignition was used.

In order to improve the fuel economy for future high-efficiency spark ignition engines, the use of advanced combustion strategies with an overall lean and/or exhaust gas recirculation diluted cylinder charge is deemed to be beneficial, provided a reliable ignition process available. In this paper, experimental results of igniting methane-air mixture by means of capacitive coupled ignition and multi-coil distributed spark ignition are presented. It is found that with a conventional spark plug electrode configuration, increase of spark energy does not proportionally enhance the ignition flame kernel development. The use of capacitive coupled ignition to enhance the initial transient power resulted in faster kernel growth compared to the conventional system. The distribution of the spark energy across a number of spark gaps shows considerable benefit.

Dual fuel applications of alcohol fuels such as ethanol or butanol through port injection with direct injection of diesel can be effective in reduction of NOx. However, these dual fuel applications are usually associated with an increase in the incomplete combustion products such as hydrocarbons (HC), carbon monoxide (CO), and hydrogen (H2) emissions. An analysis of these products of incomplete combustion and the resulting combustion efficiency penalty was made in the diesel ignited alcohol combustion modes. The effect of EGR application was evaluated using ethanol and butanol as the port injected fuel, with varying alcohol fractions at the mid-load condition (10 -12 bar IMEP). The impact of varying the engine load (5 bar to 19 bar IMEP) in the diesel ignited ethanol mode on the incomplete combustion products was also studied. Emission measurements were taken and the net fuel energy loss as a result of the incomplete combustion was estimated.

Heat-release and cylinder pressure based adaptive fuel-injection control tests were performed on a modern common-rail diesel engine to improve the engine operation in the low-temperature combustion (LTC) region. A single shot injection strategy with heavy amount of exhaust gas recirculation (EGR) was used to modulate the in-cylinder charge conditions to achieve the low-temperature combustion. Adaptive fuel-injection techniques were used to anchor the cylinder pressure characteristics in the desired crank angle window and thereby stabilize the engine operation. The response of the adaptive control to boost, fueling, and engine speed variations was also tested. A combination of adaptive fuel-injection and automatic boost/back-pressure controls had helped to make the transient emissions comparable to the steady-state LTC emissions.