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This paper presents, chemistry, test data and processing procedures on a non toxic and environmentally friendly chrome-free conversion coating alternative with the same level of adhesion and secondary corrosion resistance as that found in chrome containing conversion coating systems. Test data from military and independent sources will be presented on secondary coating adhesion, electrical conductivity, filiform and neutral salt-spray corrosion resistance as compared to chromate based systems .on magnesium, aluminum and zinc and their respective alloys. The European “RoSH” initiative will not allow for the presence of any hexavalent chromium on imported electrical components as of July first of 2006. Trivalent chromium based systems generate hexavalent chromium due to the oxidation of the trivalent chromium and as such will not be allowed.

Carbon and rephosphorized pre-strained sheet steels for cold drawing forming operations were studied and the tensile, high cycle fatigue and fatigue crack propagation properties were determined. The fatigue limit was found to be higher for 20% than for 1% pre-strained condition. Threshold stress intensity factors (▵Ků) of 5.29 MPa. m1/2 for rephosphorized steel and 7.07 MPa. m1/2 for carbon steel. Critical crack lenghts were calculated by ▵Ků and fatigue limit data using the Lukas-Klesnil short-crack criterion. Through fractographic analysis it was possible to determine the general behavior of tested materials near threshold.

In today’s Automotive world, there is NO need to advocate “Light weighting”. Government policies for carbon footprint reduction combined with high safety standards are driving OEMs to adopt advanced manufacturing technologies. Steel hot forming is selected as most preferred way to reduce weight as it is easy to adopt and commercially known. It had many advantages compare to conventional cold stamping of standard and high tensile steel. The process consists of heating blank to nearly 1000 °C and quenching it in tool to for martensitic structure. Higher strength up to 2000 MPa can be achieved by this process. There are many examples where part weight is reduced by 15 to 20 % by this method. But Steel hot forming has limitation as specific density of steel is still high. Thus, there is limitation to its weight reduction capability. For further reduction, OEMs have started exploring Aluminium hot forming.

With the advent of low evaporative emission requirements there has been the rapid adoption of multilayer extrusion technology into the production of Fuel and Vapour tubing used on Fuel systems on automobiles. Multilayer extrusion technology enables a manufacturer of Fuel and Vapour tubing to simultaneously co-extrude dissimilar thermoplastic materials in tubular form. This allows the manufacturer to combine expensive and brittle high performance evaporative emission ‘barrier’ polymers with lower cost engineering polymers. However, it is a well-known characteristic of these multilayer tube constructions that the joints between them and connector ‘barbs’ have lower joint integrity. Joint integrity is most often quantified by ‘Pull-off’ and leakage tests. Recent developments in LEV-II requirements for 2004 and beyond indicate that joint integrity will become a focus area for study and improvement.

Φ-sensitivity is a fuel characteristic that has important benefits for the operation and control of low-temperature gasoline combustion (LTGC) engines. A fuel is φ-sensitive if its autoignition reactivity varies with the fuel/air equivalence ratio (φ). Thus, multiple-injection strategies can be used to create a φ-distribution that leads to several benefits. First, the φ-distribution causes a sequential autoignition that reduces the maximum heat release rate. This allows higher loads without knock and/or advanced combustion timing for higher efficiencies. Second, combustion phasing can be controlled by adjusting the fuel-injection strategy. Finally, experiments show that intermediate-temperature heat release (ITHR) increases with φ-sensitivity, increasing the allowable combustion retard and improving stability. A detailed mechanism was applied using CHEMKIN to understand the chemistry responsible for φ-sensitivity.

THE DEVELOPMENT of new polymers offering properties and new combinations of desirable characteristics, coupled with advances in manufacturing techniques, has expanded the plastics horizon. This paper describes some of these new materials and a few of their many possible applications in the automotive industry. The author emphasizes that greater use of plastics in the automotive field depends to a great degree on the imagination and ability applied in creating new products. Design features most overcome the fundamental limitations of the new materials. The basic weaknesses of plastics are listed. Production techniques will affect the future expansion of the industry. Three methods show particular promise: blow molding, fluidized polymer deposition, and potting compounds.*

Zinc-coatings with a substantial Magnesium content have been in use for over 30 years by now. Unlike the well-established Zn-Al-Mg coatings originating from Japan which have significant higher alloying contents applied mainly for building applications, this Zinc Magnesium Aluminum coating (ZM) is also specifically designed to meet the requirements of car manufacturers. The ZM coating introduced by voestalpine, corrender, is in the upper range of ZM-alloying compositions, which was set by VDA (German Association of the Automotive Industry) and SAE to be within 1.0 to 2.0 wt. % Mg and 1.0 to 3.0 wt. % Al. The properties of these “European” Zinc-Magnesium coatings are well comparable within this range. Compared to GI and GA ZM coatings exhibit significant advantages in the press shops with its excellent formability and reduced galling and powdering respectively which is a significant advantage for the forming of outer panels.

The critical component for maintaining uniform zinc phosphate coatings on aluminum is fluoride. The control of free fluoride is critical to the operation of the process, because aluminum is dissolved in a zinc phosphate bath as a step in the coating reaction. If the dissolved aluminum is not removed from the bath, it will inhibit the formation of coatings on all metals being treated. This paper presents the characteristics and composition of zinc phosphate coatings on aluminum and steel, and lists some practical considerations of the transition from steel to aluminum components. Some possible problem areas discussed are: galvanic corrosion, underpaint quality, surface finish, electro-painting, and new paint surfaces.

The extrusion of zinc alloys, with special reference to zinc-titanium alloys, is described. Parameters for this process are defined. The excellent tensile and creep properties obtained in a typical extruded zinc-titanium alloy are presented. Extruded zinc with a quality copper-nickel-chrome plated finish offers a new approach to the production of automotive trim and of similar products.

Press-hardening steels get more and more popular for body in white applications as an approach to meet the demands of passenger safety and CO2 reduction. Unlike the larger part of the structure that is typically zinc coated, the majority of the PHS parts is either uncoated or aluminum silicon coated. This paper shall give an overview of press-hardening steels with zinc coatings with detailed results for corrosion resistance, weldability and mechanical properties for strength levels of 490 to 1800 MPa. Furthermore as for zinc coated material maintaining a robust press-hardening process is of even higher importance than for uncoated or AlSi coated material. A range of different processes including indirect and direct process are shown in detail. Especially the topic of micro-cracks, mechanisms and avoidance of micro-cracks in the direct process will be discussed. Results from industrial and semi industrial production are shown.

Provision of a layer of zinc on aluminium to provide the fillets for soldering is well established but this usually necessitates a thick layer of zinc (>30μm) and soldering at temperatures below 450°C. New technology has been developed to enable sound joints to be made on aluminium heat exchangers using a much thinner layer of zinc (4 to 8 μm typically) on the aluminium component to provide the joint. By the correct combination of flux and zinc coating thickness, joints have been obtained over a wide range of heating conditions. Preferred temperature cycles are similar to those used by the industry today for brazing of Aluminium:Silicon braze-clad aluminium components which should facilitate tranfer by industry to the new technology.

This specification covers a zinc alloy in the form of die castings.

(From Standards Proposal No. 2358, formulated under the cognizance of the EIA Quality and Reliability Engineering (QRE) Committee.)

Conventional attribute sampling plans based upon nonzero acceptance numbers are no longer desirable. In addition, emphasis is now placed on the quality level that is received by the customer. This relates directly to the Lot Tolerance Percent Defective (LTPD) value or the Limiting Quality Protection of MIL-STD-105. Measuring quality levels in percent nonconforming, although not incorrect, has been replaced with quality levels measured in parts per million (PPM). As a result, this standard addresses the need for sampling plans that can augment MIL-STD-105, are based upon a zero acceptance number, and address quality (nonconformance) levels in the parts per million range. This document does not address minor nonconformances, which are defined as nonconformances that are not likely to reduce materially the usability of the unit of product for its intended purpose.

SIMILAR SPECIFICATIONS—UNS Z33521, former SAE 903, ingot is similar to ASTM B 240-79, Alloy AG40A; and UNS Z33520, former SAE 903, die casting is similar to ASTM B 86-76, Alloy AG40A. UNS Z35530, former SAE 925, ingot is similar to ASTM B 240-79, Alloy AC41A; and UNS Z35531, former SAE 925, die casting is similar to ASTM B 86-82a, Alloy AC41A.