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Vegetable oils are candidates for alternative fuels in diesel engines. These oils, such as soybean, sunflower, rapeseed, cottonseed, and peanut, consist of various triglycerides. The chemistry of the degradation of vegetable oils when used as alternate diesel fuels thus corresponds to that of triglycerides. To study the chemistry occurring during the precombustion phase of a vegetable oil injected into a diesel engine, a reactor simulating a diesel engine was constructed. Pure triglycerides were injected into the reactor in order to determine differences in the precombustion behavior of the various triglycerides. The reactor allowed motion pictures to be prepared of the injection event as the important reaction parameters, such as pressure, temperature, and atmosphere were varied. Furthermore, samples of the degradation products of precombusted triglycerides were collected and analyzed (gas chromatography / mass spectrometry).

The impingement of liquid fuel onto the surfaces of the combustion chamber (wall-wetting) has been shown to be an important source of HC emissions from direct-injected SI engines, and can even result in pool fires and diffusion flames. Some degree of wall wetting, particularly on the piston top, is believed to occur in every current DIG engine design, but the behavior of the wall-bound fuel throughout the engine cycle is poorly understood. The goal of this study was to gain a better understanding of the fundamental interaction between liquid fuel droplets and the piston under engine-like conditions, by observing the vaporization of individual fuel drops as the surface temperature and ambient pressures were varied in a controlled environment. The vaporization of several single-component fuels, binary mixtures, and multi-component fuels was examined in the range of surface temperatures between 50 and 300 °C and ambient pressures between 50 and 1270 kPa (abs).

High performance engine tuners have traditionally relied primarily on empirical techniques for intake flow optimization. This paper describes the use of a commercial Computational Fluid Dynamics (CFD) package to complement the traditional optimization strategies. This paper describes why some experimental methods are difficult to apply, including an example of Particle Image Velocimetry (PIV), and demonstrates the benefits of using computational analysis to investigate geometry changes to the intake or exhaust systems. This paper also illustrates the use of a Coordinate Measurement Machine (CMM) to digitize an existing cylinder head to develop a solid model suitable for CFD analysis. A comparison of results from a CFD prediction from a digitized solid model to a flow bench measurement demonstrates the validity and usefulness of this approach.

One of the major problems created by the use of methanol fuels in SI engines is the high cylinder bore and ring wear rates observed during operation at low engine temperatures. The objective of the work reported in this paper was to identify the processes controlling the corrosion/wear mechanism in methanol-fueled, spark-ignition engines. Basically, three different types of experiments were performed during this project. The experiments consisted of: 1. Combustion experiments designed to identify the combustion products of methanol at various locations within a confined methanol flame; 2. Exposure studies designed to define the specific role of each of the combustion products on the corrosion mechanism; 3. Lubricant screening experiments designed to identify the mode of penetration of the oil film, and the location, in the microscale, of the surface attack. Performic acid was identified as the corrosive agent.

Hybrids are fuels derived from combinations of different energy sources and which are generally formulated as solutions, emulsions, or slurries. The underlying objective of this program is to reduce the use of petroleum-derived fuels and/or to minimize the processing requirements of the finished hybrid fuels. Several hybrid fuel formulations have been developed and tested in a direct injection single-cylinder diesel engine. The formulations included solutions of ethanol and vegetable oils in diesel fuel, emulsions of methanol and of ethanol in diesel fuel; and slurries of starch, cellulose, and “carbon” in diesel fuel. Based on the progress to date, the solutions and emulsions appear to be viable diesel engine fuels if the economic factors are favorable and the storage and handling problems are not too severe. The slurries, on the other hand, are not to the same point of development as the solutions and emulsions.

It is now a fairly well established fact that excessive ring and cylinder bore wear can result from the operation of an S. I. engine on neat methanol. The mechanism leading to the excessive wear were investigated using both engine and bench tests. Engine tests using prevaporized superheated methanol indicated that the wear results from reactions between the combustion products and the cast iron cylinder liner, where the presence of liquid methanol in the combustion chamber appears to be an important part of the mechanism. These reactions were investigated using a spinning disc combustor. The spinning disc combustor was used to provide a source of burning methanol droplets which were subsequently quenched on a water-cooled cast iron surface. The condensate formed on the cast iron surface was collected and analyzed for chemical composition. Infrared analysis indicated the presence of large quantities of iron formate, a reaction product of iron and formic acid.

A constant volume bomb was used to determine basic combustion characteristics of isooctane, n-heptane, methanol, propane and methane. Results show that the laminar flame velocity of a quiescent homogeneous air/fuel mixture can be derived from pressure-time data in the bomb. The effects of pressure, temperature, and charge dilution on flame velocity and ignition are presented. A thermo-chemical kinetic model accurately predicted concentrations of nitric oxide during combustion and in the burned gas.

A technology path has been identified for development of a high efficiency, durable, gasoline engine, targeted at achieving performance and emissions levels necessary to meet heavy-duty, on-road standards of the foreseeable future. Initial experimental and numerical results for the proposed technology concept are presented. This work summarizes internal research efforts conducted at Southwest Research Institute. An alternative combustion system has been numerically and experimentally examined. The engine utilizes gasoline as the fuel, with a combination of enabling technologies to provide high efficiency operation at ultra-low emissions levels. The concept is based upon very highly-dilute combustion of gasoline at high compression ratio and boost levels. Results from the experimental program have demonstrated engine-out NOx emissions of 0.06 g/hp/hr, at single-cylinder brake thermal efficiencies (BTE) above thirty-four percent.

SwRI has developed a new technology concept involving the use of high EGR rates coupled with a high-energy ignition system in a gasoline engine to improve fuel economy and emissions. Based on a single-cylinder study [1], this study extends the concept of a high compression ratio gasoline engine with EGR rates > 30% and a high-energy ignition system to a multi-cylinder engine. A 2000 MY Isuzu Duramax 6.6 L 8-cylinder engine was converted to run on gasoline with a diesel pilot ignition system. The engine was run at two compression ratios, 17.5:1 and 12.5:1 and with two different EGR systems - a low-pressure loop and a high pressure loop. A high cetane number (CN) diesel fuel (CN=76) was used as the ignition source and two different octane number (ON) gasolines were investigated - a pump grade 91 ON ((R+M)/2) and a 103 ON ((R+M)/2) racing fuel.

The engine selected for this work was a Caterpillar 3176 engine. Engine exhaust emissions, performance, and heat release rates were measured as functions of engine configuration, engine speed and load. Two engine configurations were used, a standard 1994 design and a 1994 configuration with EGR designed to achieve a NOx emissions level of 2.5 gm/hp-hr. Measurements were performed at 7 different steady-state, speed-load conditions on thirteen different test fuels. The fuel matrix was statistically designed to independently examine the effects of the targeted fuel properties. Cetane number was varied from 40 to 55, using both natural cetane number and cetane percent improver additives. Aromatic content ranged from 10 to 30 percent in two different forms, one in which the aromatics were predominantly mono-aromatic species and the other, where a significant fraction of the aromatics were either di- or tri-aromatics.

Due to the cost and mobility advantages of diesel-powered mine vehicles over electric vehicles, it is anticipated that the diesel engine will become more widely used in underground mines in this country. Concern has arisen, however, over the impact of diesel exhaust emissions on the air quality in the underground mine environment. A literature search has been conducted to identify known effects of fuel properties on the reduction of diesel exhaust emissions. Reductions can be obtained by optimizing fuel properties and by considering alternative fuels to standard diesel fuel. However, the data base is relatively small and the results highly dependent on engine type and operating conditions. Engine studies on a typical mine diesel are necessary to draw quantitative conclusions regarding the reduction of emissions, especially particulates and NO2 which have not been generally addressed in previous studies.

A liquid-phase port injection system for liquefied petroleum gas (LPG) generally consists of a fuel storage tank with extended capability of operating up to 600 psi, a fuel pump, and suitable fuel lines to and from the LPG fuel injectors mounted in the fuel rail manifold. Port injection of LPG in the liquid phase is attractive due to engine emissions and performance benefits. However, maintaining the LPG in the liquid phase at under-hood conditions and re-starting after hot soak can be difficult. Multiphase behavior within a liquid-phase LPG injection system was investigated computationally and experimentally. A commercial chemical equilibrium code (ASPEN PLUS™) was used to model various LPG compositions under operating conditions.

The effect of combustion chamber wall-wetting on the emissions of unburned and partially-burned hydrocarbons (HCs) from gasoline-fueled SI engines was investigated experimentally. A spark-plug mounted directional injection probe was developed to study the fate of liquid fuel which impinges on different surfaces of the combustion chamber, and to quantify its contribution to the HC emissions from direct-injected (DI) and port-fuel injected (PFI) engines. With this probe, a controlled amount of liquid fuel was deposited on a given location within the combustion chamber at a desired crank angle while the engine was operated on pre-mixed LPG. Thus, with this technique, the HC emissions due to in-cylinder wall wetting were studied independently of all other HC sources. Results from these tests show that the location where liquid fuel impinges on the combustion chamber has a very important effect on the resulting HC emissions.

Specification (spec) race engines are intended to reduce costs and increase the competitiveness in many racing classes. However, engines prepared by the best race engine builders routinely outperform truly ‘standard’ engines or engines prepared by less experienced tuners. This paper describes how engines can be modified to increase their power output and discusses various spec engine preparation techniques. Experimental and computational evidence is used to quantify the potential benefits that can be expected from each of the modifications discussed. By combining several relatively small improvements, a well prepared engine may be expected to enjoy a 5-8 % power benefit over an ‘average’ race engine, and perhaps as much as a 14-17 % benefit in power versus a truly standard production engine off the assembly line. This analysis also reveals the claims of much larger power improvements by some high-performance engine tuners can not be substantiated unless further modifications are made.

Five different diesel fuel feedstocks were processed to two levels of aromatic (0.05 sulfur, and then 10 percent) content. These materials were distilled into 6 to 8 narrow boiling range fractions that were each characterized in terms of the properties and composition. The fractions were also tested at five different speed load conditions in a single cylinder engine where high speed combustion data and emissions measurements were obtained. Linear regression analysis was used to develop relationships between the properties and composition, and the combustion and emissions characteristics as determined in the engine. The results are presented in the form of the regression equations and discussed in terms of the relative importance of the various properties in controlling the combustion and emissions characteristics. The results of these analysis confirm the importance of aromatic content on the cetane number, the smoke and the NOx emissions.

Southwest Research Institute (SwRI) is exploring the feasibility of extending the performance and fuel efficiency of the spark ignition (SI) engine to match that of the emission constrained compression (CI) engine, whilst retaining the cost effective 3-way stoichiometric aftertreatment systems associated with traditional SI light duty engines. The engine concept, which has a relatively high compression ratio and uses heavy EGR, is called “HEDGE”, i.e. High Efficiency Durable Gasoline Engine. Whereas previous SwRI papers have been medium and heavy duty development focused, this paper uses results from simulations, with some test bed correlations, to predict multicylinder torque curves, brake thermal efficiency and NOx emissions as well as knock limit for light and medium duty applications.

An experimental investigation of the effects of partial premixed charge compression ignition (PCCI) combustion and EGR temperature was conducted on a Caterpillar C-12 heavy-duty diesel engine (HDDE). The addition of EGR and PCCI combustion resulted in significant NOx reductions over the AVL 8-mode test. The lowest weighted BSNOx achieved was 2.55 g/kW-hr (1.90 g/hp-hr) using cooled EGR and 20% port fuel injection (PFI). This represents a 54% reduction compared to the stock engine. BSHC and BSCO emissions increased by a factor of 8 and 10, respectively, compared to the stock engine. BSFC also increased by 7.7%. In general, BSHC, BSCO, BSPM, and BSFC increased linearly with the amount of port-injected fuel.

This paper explores the possibility of on-board fuel classification for fuel property adaptive compression-ignition engine control system. The fuel classifier is designed to on-board classify the fuel that a diesel engine is running, including alternative and renewable fuels such as bio-diesel. Based on this classification, the key fuel properties are provided to the engine control system for optimal control of in-cylinder combustion and exhaust treatment system management with respect to the fuel. The fuel classifier employs engine input-output response characteristics measured from standard engine sensors to classify the fuel. For proof-of-concept purposes, engine input-output responses were measured for three different fuels at three different engine operating conditions. Two neural-network-based fuel classifiers were developed for different classification scenarios. Of the three engine operating conditions tested, two conditions were selected for the fuel classifier to be active.

Methods to reduce direct injected diesel engine emissions in the combustion chamber will be discussed in this paper. The following NOx emission reduction technologies will be reviewed: charge air chilling, water injection, and exhaust gas recirculation (EGR). Emphasis will be placed on the development of an EGR system and the effect of EGR on NOx and particulates. The lower limit of NOx that can be obtained using conventional diesel engine combustion will be discussed. Further reductions in NOx may require changing the combustion process from a diffusion flame to a homogeneous charge combustion system.

This paper presents the results of an experimental investigation of the fuel-air mixing process in a port-fuel-injected, 4-valve, spark-ignited engine that was motored to simulate cold cranking and start-up conditions. An infrared fiber-optic instrumented spark plug probe was used to measure the local, crank angle resolved, fuel concentration in the vicinity of the spark gap of a single-cylinder research engine with a production head and fuel injector. The crank-angle resolved fuel concentrations were compared for various injection timings including open-intake-valve (OIV) and closed-intake-valve (CIV) injection, using federal certification gasoline. In addition, the effects of speed, intake manifold pressure, and injected fuel mass were examined.