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The effects of using n-butanol, n-octanol, fossil Diesel, hydrotreated vegetable oil (HVO), and blends of these fuels on spray penetration, flame and soot characteristics were investigated in a high-pressure high-temperature constant volume combustion chamber designed to mimic a heavy duty Diesel engine. Backlight illumination was used to capture liquid and vapor phase spray images with a high-speed camera. The flame lift-off length (LOL) and ignition delay were determined by analyzing OH* chemiluminescence images. Laser extinction diagnostics were used to measure the spatially and temporally resolved soot volume fraction. The spray experiments were performed by injecting fuels under non-combusting (623 K) and combusting (823 K) conditions at a fixed ambient air density of 26 kg/m3. A Scania 0.19 mm single straight hole injector and Scania XPI common rail fuel supply system were used to produce injection pressures of 120 MPa and 180 MPa.

Global warming driven by “greenhouse gas” emissions is an increasingly serious concern of both the public and legislators. A potentially potent way to reduce these emissions and conserve fossil fuel resources is to use n-butanol, iso-butanol or octanol (2-ethylhexanol) from renewable sources as alternative fuels in diesel engines. The effects of adding these substances to diesel fuel were therefore tested in a single-cylinder heavy duty diesel engine operated using factory settings. These alcohols have better calorific values, flash points, lubricity, cetane numbers and solubility in diesel than shorter-chain alcohols. However, they have lower cetane numbers than diesel, so either hydrotreated vegetable oil (HVO) or Di-tertiary-butyl peroxide (DTBP) was added to the diesel-alcohol mixtures to generate blends with the same Cetane Number (CN) as diesel.

Heavy alcohols can be mixed with fossil diesel to produce blended fuels that can be used in diesel engines. Alcohols can be obtained from fossil resources, but can also be produced more sustainably from renewable raw materials. The use of such biofuels can help to reduce greenhouse gas (GHG) emissions from the transport sector. This study examines four alcohol/diesel blends each containing one heavy alcohol: n-butanol, iso-butanol, 2-ethyl hexanol and n-octanol. All of the blends where prepared to function as drop-in fuels in existing engines with factory settings. To compensate for the alcohols′ low cetane numbers (CN), a third component with high CN was added to each blend, namely hydrotreated vegetable oil (HVO). The composition of each mixture was selected to give an overall CN equal to that of fossil diesel fuel.