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Abstract The ASTM D130 was first issued in 1922 as a tentative standard for the detection of corrosive sulfur in gasoline. A clean copper strip was immersed in a sample of gasoline for three hours at 50°C with any corrosion or discoloration taken to indicate the presence of corrosive sulfur. Since that time, the method has undergone many revisions and has been applied to many petroleum products. Today, the ASTM D130 standard is the leading method used to determine the corrosiveness of various fuels, lubricants, and other hydrocarbon-based solutions to copper. The end-of-test strips are ranked using the ASTM Copper Strip Corrosion Standard Adjunct, a colored reproduction of copper strips characteristic of various degrees of sulfur-induced tarnish and corrosion, first introduced in 1954. This pragmatic approach to assessing potential corrosion concerns with copper hardware has served various industries well for a century.

The Body Division of the Automotive Corrosion and Prevention Committee of SAE (ACAP) concluded that an automotive body corrosion survey for public consumption was needed. The committee proceeded to develop a survey methodology and conducted an initial survey in the Detroit area. Similar surveys can be conducted at regular biyearly intervals for comparison to track the results of industry wide improvements in corrosion protection. Over two hundred 1980 and 1981 model year vehicles were surveyed covering a wide range of domestic models and some foreign models. Twenty six panel or partial panel categories were developed and evaluated for a closed car parking lot survey. Each panel was checked for perforation, blistering and surface rust.

This paper deals with some recent advances in the field of 1D fluid dynamic modeling of unsteady reacting flows in complex s.i. engine pipe-systems, involving a catalytic converter. In particular, a numerical simulation code has been developed to allow the simulation of chemical reactions occurring in the catalyst, in order to predict the chemical specie concentration in the exhaust gas from the cylinder to the tailpipe outlet, passing through the catalytic converter. The composition of the exhaust gas, discharged by the cylinder and then flowing towards the converter, is calculated by means of a thermodynamic two-zone combustion model, including emission sub-models. The catalytic converter can be simulated by means of a 1D fluid dynamic and chemical approach, considering the laminar flow in each tiny channel of the substrate.

Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

This paper describes some recent advances of the research work concerning the 1D fluid dynamic modeling of unsteady reacting flows in s.i. engine pipe-systems, including pre-catalysts and main catalysts. The numerical model GASDYN developed in previous work has been further enhanced to enable the simulation of the catalyst. The main chemical reactions occurring in the wash-coat have been accounted in the model, considering the mass transfer between gas and solid phase. The oxidation of CO, C3H6, C3H8, H2 and reduction of NO, the steam-reforming reactions of C3H6, C3H8, the water-gas shift reaction of CO have been considered. Moreover, an oxygen-storage sub-model has been introduced, to account for the behavior of Cerium oxides. A detailed thermal model of the converter takes into account the heat released by the exothermic reactions as a source term in the heat transfer equations. The influence of the insulating mat is accounted.

A theoretical model is presented for predicting springback of wide sheet metal subjected to 2D-stretch-bending operation. The material is assumed to be normal anisotropic with n-th power hardening law, σ = Fεn. Two types of stretch-bending experiment, bending with simultaneous stretching and stretch-bending followed by consecutive re-stretching, is conducted using AK sheet steel and sheet aluminum alloy A5182-O. The measured values of springback are in good agreement with analytical ones for a wide range of bending radii, stretching forces, and loading conditions. Furthermore, a calculation method for predicting springback configurations of 2D sheet metal parts with arbitrary cross-sections which include both stretch-bending and stretch-bending-unbending deformation is proposed.

Ford GT 2005 vehicle was designed for performance, timing, cost, and styling to preserve Ford GT40 vintage look. In this vehicle program, many advanced manufacturing processes and light materials were deployed including aluminum and magnesium. This paper briefly explains one unique design concept for a Ford GT instrument panel comprised of a structural magnesium cross-car beam and other components, i.e. radio box and console top, which is believed to be the industry's first structural I/P from vehicle crash load and path perspectives. The magnesium I/P design criteria include magnesium casting properties, cost, corrosion protection, crashworthiness assessments, noise vibration harshness performance, and durability. Magnesium die casting requirements include high pressure die cast process with low casting porosity and sound quality, casting dimensional stability, corrosion protection and coating strategy, joining and assembly constraints.

The High Voltage Power Distribution Unit (PDU) is constructed of magnesium in support of Fuel Cell Electric Vehicle (FCEV) weight reduction efforts. The PDU distributes and controls a nominal 75 kilowatts of power generated by the Fuel Cell, the primary source of High Voltage power, to all the vehicle loads and accessories. The constraints imposed on the design of the PDU resulted in a component highly susceptible to general and galvanic corrosion. Corrosion abatement was the focus of the PDU redesign. This paper describes the redesign efforts undertaken by Ford personnel to improve the part robustness and corrosion resistance.

Various techniques are constantly being devised to accelerate model generation leading to shorter product development cycle. This work proposes and implements a reduced synthetic gas bench (SGB) test protocol for a commercial Pt-Pd diesel oxidation catalyst (DOC) that can be used to develop global reaction kinetics. The kinetics thus developed were implemented in a 1D model to predict DOC emissions accurately over a wide operating window. Hydrocarbons (HCs) in the exhaust were categorized as Propylene (C3H6) representing partially oxidized hydrocarbons and n-Decane (C10H22) representing unburnt fuel. Test protocols were defined using the order of inhibition of the various species present in the exhaust, namely, CO, NOx (NO+NO2) and HC for the specific reaction under consideration. The oxidation reactions for CO and HCs were found to be inhibited competitively by CO and HCs; both the NOx species inhibited these reactions to the same extent.

Coated refractory metals, coated and alloyed graphites, hafnium-tantalum alloys, refractory borides, and stabilized zirconias are considered for the 3600–4000 F high-velocity air environment. Only refractory borides and stabilized zirconias are indicated as offering long duration and reuse capabilities for such high-temperature utilization. Iridium, as coatings on substrates of either graphites or refractory metals, appears attractive for shorter times (less than 1 hr). Environmental evaluation and the need for a theoretical framework to enable the prediction of performance data for such materials are indicated to be major problems facing users and suppliers.

This paper discusses work performed in research, design, and development of sensors for measurement of local dynamic surface temperatures on re-entry vehicles. Included are discussions of the basic requirements and related system design factors, the transducer concepts and sensor assembly configurations considered, and the materials investigations and engineering tests conducted. Design requirements are presented for the twin-lead thermocouple probe temperature sensor chosen as the most feasible concept for early implementation. The most promising thermocouple materials and fabrication processes are defined and the additional precision testing and development requirements for final design are outlined. Information not previously reported in available literature includes preliminary data from tests up to4300°F showing (1) excellent oxidation resistance of Iridium, and (2) oxidation protection of thermocouple elements in “gas tight” sheaths of thoria and zirconia.

Titanium alloy for forging and pure titanium material for exhaust systems have been developed. The forging alloy will be applied to production of lightweight motorcycle frames and the pure titanium will be applied to improve engine performance. The materials have been made inexpensive by the use of off-grade sponge that includes many impurities for production of titanium ingot. Stable characteristics have been obtained by controlling oxygen equivalent after setting the volume of tolerable impurities by considering mechanical properties and production engineering. In spite of low-cost, the material provides the same design strength compared to conventional material, and enables parts production with existing equipment. A review of manufacturing and surface treatment processes indicated a reduction in the price of titanium parts produced with this new material.

The new small and lightweight 2-cylinder liquid-cooled OHC gasoline engines were developed. These new engines are featuring high output, low vibration and noise radiation and so able to improve the comfortableness and amenity of applied utility machines. In this paper, the features of the new engines and the process to realize development targets are introduced. The basic structure adopted on the new engines is a liquid-cooled, inline 2-cyilinder layout with 360-degree firing intervals, twin balancer shafts, and an overhead camshaft that is driven by a cogged belt. Also various parts made of aluminum alloy and plastics could make the engine lighter. By these measures, the new engines could satisfy their hardest development targets, and realize their easy installation, higher versatility, and have the excellent features such as compact size, lightweight, high output, low exhaust gas emission and low vibration and noise radiation.

SIGNIFICANT REDUCTION IN THE TRANSPORTATION COST PER TON MILE OF BULK PRODUCTS IS ATTAINABLE BY THE PROPER ADAPTATION OF A TRUCK TRAIN TRANSPORT. IMPROVED HAUL ROADS, GREATER DISTANCES, AND INCREASED DEMAND FOR MINE PRODUCTS AT COMPETITIVE PRICES ARE RESULTING IN A RE-EVALUATION OF ALL COST ASPECTS OF MATERIAL MOVEMENT. THE TRUCK TRAIN CONCEPT USING RELATIVELY SMALLER TIRES THAN LARGE PIT TRUCKS OPENS THE DOOR TO REDUCED OPERATING COSTS BY LOWERING CYCLE TIMES AND COST PER MILE OF TIRES AND CAPITAL INVESTMENT.

Shortly after World War II, as aircraft became more sophisticated and power-assist, flight-control functions became a requirement, hydraulic system operating pressures rose from the 1000 psi level to the 3000 psi level found on most aircraft today. Since then, 4000 psi systems have been developed for the U.S. Air Force XB-70 and B-1 bombers and a number of European aircraft including the tornado multirole combat aircraft and the Concorde supersonic transport. The V-22 Osprey incorporates a 5000 psi hydraulic system. The power levels of military aircraft hydraulic systems have continued to rise. This is primarily due to higher aerodynamic loading, combined with the increased hydraulic functions and operations of each new aircraft. At the same time, aircraft structures and wings have been getting smaller and thinner as mission requirements expand. Thus, internal physical space available for plumbing and components continues to decrease.

Shortly after World War II, as aircraft became more sophisticated and power-assist, flight-control functions became a requirement, hydraulic system operating pressures rose from the 1000 psi level to the 3000 psi level found on most aircraft today. Since then, 4000 psi systems have been developed for the U.S. Air Force XB-70 and B-1 bombers and a number of European aircraft including the tornado multirole combat aircraft and the Concorde supersonic transport. The V-22 Osprey incorporates a 5000 psi hydraulic system. The power levels of military aircraft hydraulic systems have continued to rise. This is primarily due to higher aerodynamic loading, combined with the increased hydraulic functions and operations of each new aircraft. At the same time, aircraft structures and wings have been getting smaller and thinner as mission requirements expand. Thus, internal physical space available for plumbing and components continues to decrease.

A 2-D CFD model was developed to describe the heat transfer, and reaction kinetics in a honeycomb structured ceramic diesel particulate trap. This model describes the steady state as well as the transient behavior of the flow and heat transfer during the trap regeneration processes. The trap temperature profile was determined by numerically solving the 2-D unsteady energy equation including the convective, heat conduction and viscous dissipation terms. The convective terms were based on a 2-D analytical flow field solution derived from the conservation of mass and momentum equations (Opris, 1997). The reaction kinetics were described using a discretized first order Arrhenius function. The 2-D term describing the reaction kinetics and particulate matter conservation of mass was added to the energy equation as a source term in order to represent the particulate matter oxidation. The filtration model describes the particulate matter accumulation in the trap.

To date the market for P/M stainless steel has not developed appreciably, and has centered largely on the development of austenitic 300 series stainless steels. Although these stainless steels are noted for their resistance to corrosion in many media, it has been difficult for P/M parts fabricators to produce parts that will sustain 1,000 hours of protection in a 5% salt solution. The problem starts with the water atomized powders and continues with the sintering practice exercised to produce the parts. Reasons for lack of corrosion resistance, based upon these considerations, will be discussed. In addition, the ferritic stainless steels are being considered seriously for fuel injectors. These emerging applications derive from the corrosive environment that may become a problem if and when alternative fuels are introduced. P/M ferritic stainless steels may also assume a position as a corrosion resistant magnetic material required in ABS systems which are currently emerging.

A technique for evaluating high temperature oxidation and corrosion tendencies of automotive crankcase lubricants is described. The technique utilizes a versatile bench apparatus which, with a minimum of modification, can be used for either evaluating thermal oxidation stability of gear lubricants or oxidation-corrosion tendencies of automotive crankcase lubricants. The apparatus is relatively compact and requires a minimal lubricant sample. Design of the apparatus permits close control of all operating parameters and provides satisfactory test data repeatability. Retainable copper-lead test bearings are used as the indicator in predicting a pass or fail of fully formulated crankcase lubricants as in the case of the CRC L-38-559 (Federal Test Method 3405) technique. Engine and bench test data are compared to illustrate the capabilities of this new bench technique.

A technique for determining induction system deposit (ISD) tendencies of a gasoline is described. The technique uses a bench apparatus, designed to simulate the valve and port area of an engine intake system, which provides deposit data correlative to real engines. The apparatus is compact, requires a minimal fuel sample, uses a retainable metal tube as the deposit collecting surface, and has good repeatability. Design of the equipment eliminates the possibility of deposit contamination by dirt, rust and lead precipitate, and both solvent-washed and unwashed data may be obtained. ASTM Gum, engine intake deposit weights, and ISD technique data are compared to illustrate the capabilities of this new technique.